MAGNETIC BIOCHAR AEROGEL FROM WASTE CORRUGATED PAPER FOR ADSORPTION OF METHYLENE BLUE FROM WATER: PREPAREATRION AND PERFORMANCE

LI Zhili; WANG Haitao; HUO Hanxin; ZHAO Jin; ZHANG Yizhong; WANG Xunliang; GUO Jian; JIANG Tianxiang; MA Yuhui

doi:10.13205/j.hjgc.202412025

Volume 42 Issue 12

Dec. 2024

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2024 > 42(12): 210-217

LI Zhili, WANG Haitao, HUO Hanxin, ZHAO Jin, ZHANG Yizhong, WANG Xunliang, GUO Jian, JIANG Tianxiang, MA Yuhui. MAGNETIC BIOCHAR AEROGEL FROM WASTE CORRUGATED PAPER FOR ADSORPTION OF METHYLENE BLUE FROM WATER: PREPAREATRION AND PERFORMANCE[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 210-217. doi: 10.13205/j.hjgc.202412025

Citation:

LI Zhili, WANG Haitao, HUO Hanxin, ZHAO Jin, ZHANG Yizhong, WANG Xunliang, GUO Jian, JIANG Tianxiang, MA Yuhui. MAGNETIC BIOCHAR AEROGEL FROM WASTE CORRUGATED PAPER FOR ADSORPTION OF METHYLENE BLUE FROM WATER: PREPAREATRION AND PERFORMANCE[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 210-217. doi: 10.13205/j.hjgc.202412025

Citation:

LI Zhili, WANG Haitao, HUO Hanxin, ZHAO Jin, ZHANG Yizhong, WANG Xunliang, GUO Jian, JIANG Tianxiang, MA Yuhui. MAGNETIC BIOCHAR AEROGEL FROM WASTE CORRUGATED PAPER FOR ADSORPTION OF METHYLENE BLUE FROM WATER: PREPAREATRION AND PERFORMANCE[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(12): 210-217. doi: 10.13205/j.hjgc.202412025

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MAGNETIC BIOCHAR AEROGEL FROM WASTE CORRUGATED PAPER FOR ADSORPTION OF METHYLENE BLUE FROM WATER: PREPAREATRION AND PERFORMANCE

doi: 10.13205/j.hjgc.202412025

1. School of Environmental Science and Engineering, Tiangong University, Tianjin 300387, China;
2. The Institute of Seawater Desalination and Multipurpose Utilization, Ministry of Natural Resources of the People's Republic of China, Tianjin 300192, China;
3. Technical Centre for Soil, Agriculture and Rural Ecology and Environment, Ministry of Ecology and Environment of the People's Republic of China, Beijing 100012, China;
4. Shandong Sihai Water Treatment Equipment Co., Ltd., Weifang 262500, China;
5. Tianjin Haiyue Water Treatment High-Tech Co., Ltd., Tianjin 300192, China

Received Date: 2023-12-26
Available Online: 2025-01-18

Abstract

Abstract

A novel magnetic biochar aerogel (BCA_Fe-600) was prepared from waste corrugated paper via crushing followed by impregnation with FeCl₃/ethanol solution and carbonization. The materials’ morphology, elemental composition, crystal structure, surface area, surface functional groups, mechanical property, magnetic property, hydrophilicity, and Zeta potential were analyzed and compared. The adsorption isotherm of BCA_Fe-600 for methylene blue was studied, and BCA_Fe-600 was used as a magnetic separable and floatable adsorbent for the purification of the simulated methylene blue polluted natural water. The results showed that the hydrophilic BCA_Fe-600 was composed of criss-crossed ribbon-like carbon fibers, and the main chemical constituents of BCA_Fe-600 were amorphous carbon, maghemite, and calcite. The presence of FeCl₃ benefited the evolution of porous structure and the mechanical strength of BCA_Fe-600, and maghemite derived from FeCl₃ gave magnetism to BCA_Fe-600, possessing a BET surface area of 205 m²/g and a saturated magnetization value of 7.62 emu/g. The Langmuir model was applicable for fitting the adsorption isotherm data for methylene blue with a maximum adsorption capacity of 35.6 mg/g, and the adsorption kinetics of methylene blue on the floatable BCA_Fe-600 complied with pseudo-second-order kinetics model.
- waste corrugated paper,
- magnetic biochar aerogel,
- methylene blue,
- adsorption isotherm,
- adsorption kinetics

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References(25)

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