An accurate identification method for hazardous characteristics of electrolytic manganese anode slime based on full process traceability

CHEN Lingbo; ZENG Guihua; QI Yan; ZHOU Hailan; DENG Yongchao; YANG Dan; YU Zhiyuan

doi:10.13205/j.hjgc.202507021

Volume 43 Issue 7

Jul. 2025

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2025 > 43(7): 193-201

CHEN Lingbo, ZENG Guihua, QI Yan, ZHOU Hailan, DENG Yongchao, YANG Dan, YU Zhiyuan. An accurate identification method for hazardous characteristics of electrolytic manganese anode slime based on full process traceability[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(7): 193-201. doi: 10.13205/j.hjgc.202507021

Citation:

CHEN Lingbo, ZENG Guihua, QI Yan, ZHOU Hailan, DENG Yongchao, YANG Dan, YU Zhiyuan. An accurate identification method for hazardous characteristics of electrolytic manganese anode slime based on full process traceability[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(7): 193-201. doi: 10.13205/j.hjgc.202507021

Citation:

CHEN Lingbo, ZENG Guihua, QI Yan, ZHOU Hailan, DENG Yongchao, YANG Dan, YU Zhiyuan. An accurate identification method for hazardous characteristics of electrolytic manganese anode slime based on full process traceability[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(7): 193-201. doi: 10.13205/j.hjgc.202507021

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An accurate identification method for hazardous characteristics of electrolytic manganese anode slime based on full process traceability

doi: 10.13205/j.hjgc.202507021

Key Laboratory of Water Pollution Control Technology, Hunan Research Academy of Environmental Sciences, Changsha 410004, China

Received Date: 2025-03-13
Accepted Date: 2025-05-28
Rev Recd Date: 2025-05-20

Available Online: 2025-09-11

Abstract

Abstract

A comprehensive identification methodology integrating "engineering traceability， morphological analysis， and dynamic testing" has been established to identify the hazardous characteristics of electrolytic manganese anode slime. The scientific and effective identification of solid waste properties of electrolytic manganese anode slime was obtained from both theoretical and experimental perspectives. The identification results showed that electrolytic manganese anode slime did not have any hazardous characteristics such as infectivity， corrosivity， ignitability， reactivity， acute toxicity， extraction toxicity， toxic substance content， etc. The conclusion can provide a reference for the determination of solid waste properties of electrolytic manganese anode slime. It can also be used as a basis for its environmental management and resource utilization. The identification method established in this paper is feasible and can provide a reference for the identification of hazardous characteristics of other solid waste.
- electrolytic manganese,
- anode slime,
- hazardous characteristics,
- identification method

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References(23)

References

[1]	JIANG W B,JAO Y Y,YE J,et al. Brief discussion on the influence of the technical specification for pollution control of manganese residue on the development of the industry[J]. China Environmental Protection Industry,2022(11):43-44.蒋文博,矫云阳,叶旌,等.浅谈《锰渣污染控制技术规范》对行业发展的影响[J].中国环保产业,2022(11):43-44.
[2]	ZHANG R,MA X,SHEN X,et al. Life cycle assessment of electrolytic manganese metal production[J]. Journal of Cleaner Production,2020,253:119951.
[3]	WANG P X. Study on step extraction of manganese,lead,selenium and tin from electrolytic manganese anode slime based on sulfur[D]. Zhengzhou:Zhengzhou University,2022.王鹏星.基于硫转化的电解经阳极泥中经铅锡硒分步提取研究[D].郑州:郑州大学,2022.
[4]	HE J H. Research on environmental pollution of electrolytic manganese production and related environmental policies in China[J]. Environment and Development,2020,32(5):65-66.何家欢.电解锰生产的环境污染及我国相关环境政策的研究[J].环境与发展,2020,32(5):65-66.
[5]	TANG G F,JlN Y,FANG Z Z,et al. Preparation of high purity Mn₃O₄ from electrolytic manganese anode slime[J]. Nonferrous Metals Engineering,2023,13(23):59-64.唐庚飞,金尧,方志珍,等.用电解锰阳极泥制备高纯Mn₃O₄[J].有色金属工程,2023,13(23):59-64.
[6]	ZHANG H,BI Y,CHEN X,et al. Treatment and characterization analysis of electrolytic manganese anode slime[J]. Procedia Environmental Sciences,2016,31:683-690.
[7]	ZHU R,LONG H,WANG Y,et al. Microwave-assisted recovery of lead from electrolytic manganese anode sludge using tartaric acid and NaOH[J]. Environmental Technology,2021:1-15.
[8]	TAO C,LI D,LIU Z,et al. Activation and purification of electrolytic-manganese anode slime and its application[J]. Battery Bimonthly,2011,41:121-124.
[9]	ZHENG Z E. Experimental research on reduction roasting-acid leaching electrolyte manganese anode slime[J]. Rare Metals and Cemented Carbides,2022,50(2):15-18.郑子恩.电解金属锰阳极泥还原焙烧-酸浸试验研究[J].稀有金属与硬质合金,2022,50(2):15-18.
[10]	WEI H K,YANG Y,LUO D,et al. A research on comprehensive recycling of electrolytic manganese anode slime[J]. China's Manganese Industry,2017,35(S1):55-58魏汉可,杨勇,罗豆,等.电解金属锰阳极泥的综合回收利用研究[J].中国锰业,2017,35(增刊1):55-58
[11]	ZHOU J. Recovery and utilization of lead in lead-containing waste residue from electrolytic manganese production[D]. Lanzhou:Lanzhou Jiaotong University,2022.周杰.电解锰生产含铅废渣中铅的回收与利用[D].兰州:兰州交通大学,2022.
[12]	LONG T F,JIN Y,TANG W L,et al. Separation of manganese and lead from electrolytic manganese anode slime by reduction roasting and acid leaching process[J]. Mining and Metallurgical Engineering,2023,43(6):128-138.龙腾发,金尧,唐文丽,等.基于还原焙烧-酸浸法的电解锰阳极泥中锰铅分离研究[J].矿冶工程,2023,43(6):128-138.
[13]	YAN J X,WANG H J. Discussion on identification of hazardous characteristics of solid waste,the existing problems and some related recommendations[J]. Industrial Safety and Environmental Protection,2021,47(11):81-84.闫纪宪,王红娟.浅析当前固体废物危险特性鉴别工作中的问题及建议[J].工业安全与环保,2021,47(11):81-84.
[14]	HUA B,BI Y F,LIAO J Y,et al. Preliminary study on the properties and Pb removal of electrolytic manganese anode slime[J]. Environmental Engineering,2013,31:457-460.华兵,毕亚凡,廖金阳,等.电解锰阳极泥特性及除铅初步研究[J].环境工程,2013,31:457-460.
[15]	SHAO J,MAO J Q,ZHANG Y Y. Analysis on the present situation and suggestions of hazardous waste identification in China[J]. Shandong Chemical Industry,2022,51:246-248.邵娟,茆吉庆,张洋阳.我国危险废物鉴别现状浅析及建议[J].山东化工,2022,51:246-248.
[16]	WANG S M,RAO A Q,TANG Y H. Study on hazardous waste identification of fluorine-containing sludge in glass etching production wastewater treatment[J]. Jiangxi Science,2024,42(3):567-573.汪帅马,饶安琪,唐勇辉.玻璃蚀刻含氟废水处理污泥危险废物鉴别研究[J].江西科学,2024,42(3):567-573.
[17]	HAO Y Q. Solid waste identification method of imported metal smelting materials[J]. Environmental Protection of Chemical Industry,2017,37(5):566-571.郝雅琼.金属冶炼进口物料的固体废物鉴别方法[J].化工环保,2017,37(5):566-571.
[18]	HUANG L Q. Research on preparation of manganate cathode materials for lithium batteries with electrolytic manganese anode slime[D]. Wuhan:Wuhan Institute of Technology,2014.黄良取.电解锰阳极泥制备锰酸锂电池正极材料的工艺研究[D].武汉:武汉工程大学,2014.
[19]	YANG T Y,XUE Y,LIU X M,et al. Solidification/stabilization and separation/extraction treatments of environmental hazardous components in electrolytic manganese residue:a review[J]. Process Safety and Environmental Protection,2022,157:509.
[20]	ZHANG H B. Research on migration behavior of lead in electrolytic manganese anode slime[D]. Wuhan:Wuhan Institute of Technology,2016.张宏波.电解锰阳极泥中铅的迁移行为研究[D].武汉:武汉工程大学,2016.
[21]	JIANG L H,DUAN N,WANG Y Y,et al. Analysis of selenium pollution in china and the control of electrolytic manganese metal industries[J]. Environmental Science&Technology,2011,34(S2):393-396.降林华,段宁,王允雨,等.我国硒污染分析与电解锰行业控制对策[J].环境科学与技术,2011,34(增刊2):393-396.
[22]	TAN Z Z,MEI G G,LI W J,et al. Metallurgy of Manganese[M]. Changsha:Central South University Press,2004.谭柱中,梅光贵,李维健,等.锰冶金学[M].长沙:中南大学出版社,2004.
[23]	LUO L,ZHOU H,CAI Q,et al. Selenium in electrolytic waste residue:determination of concentration and study of speciation[J]. Environmental Science&Technology,2016,39(4):58-62.罗乐,周皓,蔡庆,等.电解废渣中硒含量及赋存形态的研究[J].环境科学与技术,2016,39(4):58-62.