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Volume 43 Issue 10
Oct.  2025
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Article Contents
WANG Kaiyue, YANG Zhijie, LIU Wuyan, LIU Jianguo, LI Yu, ZHANG Shuai. Preparation and mechanisms of nutrient morphological transformation of coal gangue-cattle manure-sheep manure composite eco-friendly fertilizer[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(10): 65-75. doi: 10.13205/j.hjgc.202510008
Citation: WANG Kaiyue, YANG Zhijie, LIU Wuyan, LIU Jianguo, LI Yu, ZHANG Shuai. Preparation and mechanisms of nutrient morphological transformation of coal gangue-cattle manure-sheep manure composite eco-friendly fertilizer[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(10): 65-75. doi: 10.13205/j.hjgc.202510008

Preparation and mechanisms of nutrient morphological transformation of coal gangue-cattle manure-sheep manure composite eco-friendly fertilizer

doi: 10.13205/j.hjgc.202510008
  • Received Date: 2025-03-07
  • Accepted Date: 2025-04-30
  • Rev Recd Date: 2025-04-01
  • Available Online: 2025-12-03
  • Publish Date: 2025-10-01
  • To investigate the changes in maturity and nutrient transformation mechanism of coal gangue, cow manure, and sheep manure synergistic composting, and to maximize the utilization efficiency of coal gangue, this study set up four sets of mixed composting treatments with coal gangue content of 60% (D1), 50% (D2), 40% (D3), 30% (D4). During the composting process, changes in the temperature, pH, conductivity, nitrogen, phosphorus, potassium, humus, C/N, seed germination index, as well as characterization methods such as scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), etc., were involved, to reveal their patterns and effects. The results showed that the addition of coal gangue can effectively reduce the salt content of ecological fertilizers. The conductivity of the final products of D1, D2, D3, and D4 were 1.02, 1.12, 1.20, and 1.35 mS/cm, respectively. The pH values of the four treatments were within the range of 7.5 to 8.1, which met the requirements of China’s national organic fertilizer standard. The effective phosphorus and potassium of groups D3 and D4 were increased by more than 60% and 50%, respectively. When the content of coal gangue was 40% (D3 group), the F/A ratio reached 2.5, indicating the strongest degree of composting humification. The germination index (GI) was as high as 104.2%, and it could meet the GI index requirement earlier, indicating that the toxicity to plants was effectively reduced. The SEM-XRD-FTIR results also showed that after composting, the honeycomb structure in the D3 pile became more pronounced, and some crystals had decreased crystallinity. The aromatization degree of the pile was higher, showing better slow-release performance. In summary, the synergistic composting of coal gangue, cow manure, and sheep manure in a mass ratio of 4:3:3 can significantly improve the maturity and nutrient conversion efficiency of compost. This study provides a theoretical basis and application value for preparation technology of high value-added ecological fertilizers.
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