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Volume 40 Issue 7
Sep.  2022
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Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2022  >  40(7): 159-164,185
DU Xiaoli, CHI Zhongwen, YIN Zijie, ZHAO Meng. ATTENUATION ON CONTROL EFFECT OF HEAVY METALS IN RUNOFF BY PERMEABLE BRICK DURING THE WHOLE PROCESS OF BLOCKAGE[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(7): 1-8. doi: DOI:10.13205/j.hjgc.202207001
Citation: HOU Pin, ZHANG Yu, PENG Lian, ZHAO Junhui, BU Qingwei, WANG Jianbing, BEN Weiwei, QIANG Zhimin. A DETECTION METHOD FOR TRACE BENZO (a) PYRENE IN COKING WASTEWATER BY SOLID-PHASE EXTRACTION AND GC-MS ANALYSIS[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(7): 159-164,185. doi: DOI:10.13205/j.hjgc.202207023
shu

A DETECTION METHOD FOR TRACE BENZO (a) PYRENE IN COKING WASTEWATER BY SOLID-PHASE EXTRACTION AND GC-MS ANALYSIS

doi: DOI:10.13205/j.hjgc.202207023

  • 1. School of Chemical & Environmental Engineering, China University of Mining and Technology-Beijing, Beijing 100083, China;

  • 2. Key Laboratory of Drinking Water Science and Technology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China

  • Received Date: 2021-03-16
    Available Online: 2022-09-02
    Abstract
  • Based on solid phase extraction (SPE) and gas chromatography/mass spectrometry (GC-MS),the study herein established a quantitative analysis method for trace benzo (a) pyrene (BaP) in coking wastewater.The BaP-containing water samples were enriched and purified by SPE after being modified by methanol,then eluted by dichloromethane,concentrated by nitrogen blowing,and quantified by GC-MS after constant volume of dichloromethane or acetonitrile.The results showed that,after the optimization of sample pretreatment and under the analysis conditions,the linear correlation coefficient (R2) of BaP standard curve was greater than 0.99,the recovery rate was in the range of 79.6%~85.5%,the detection limit and quantitative limit were 4.33 ng/L and 14.45 ng/L,respectively.This method was then applied to the determination of BaP in the secondary effluent of a coking plant in Inner Mongolia.The recoveries of spiked BaP samples were in the range of 83.3%~89.3%,indicating that this method presented high sensitivity and good selectivity.It is suitable for the quantitative determination of trace BaP in coking wastewater.
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