铁基非均相芬顿氧化技术宽pH降解有机污染物的研究进展

徐李聪; 陶然; 吴明华; 罗金明; 余德游

doi:10.13205/j.hjgc.202508001

铁基非均相芬顿氧化技术宽pH降解有机污染物的研究进展

doi: 10.13205/j.hjgc.202508001

徐李聪^1,3,
陶然^1,3,
吴明华^1,3,
罗金明²,
余德游^1,3, ,

1. 浙江理工大学生物基纤维材料全国重点实验室, 杭州 310018;
2. 上海交通大学环境科学与工程学院, 上海 200240;
3. 浙江理工大学纺织生态染整教育部工程研究中心, 杭州 310018

基金项目:

国家自然科学基金面上项目“水分子竞争吸附调控催化臭氧形成活性氧物种规律与机制研究”（22476183）

详细信息

作者简介:
徐李聪（1995—），男，博士研究生在读，主要研究方向为印染废水污染控制。xlc158383521327@163.com

通讯作者:
余德游（1992—），男，副教授，主要研究方向为纺织印染绿色制造。yudeyou92@zstu.edu.cn

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出版历程
- 收稿日期: 2025-06-26
- 录用日期: 2025-08-20
- 修回日期: 2025-08-19

Research progress on degradation of organic pollutants by iron-based heterogeneous Fenton process over a wide pH range

XU Licong^1,3,
TAO Ran^1,3,
WU Minghua^1,3,
LUO Jinming²,
YU Deyou^{1,3
, ,}

1. State Key Laboratory of Bio-based Fiber Materials, Zhejiang Sci-Tech University, Hangzhou 310018, China;
2. School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China;
3. Engineering Research Center for Eco-Dyeing and Finishing of Textiles(Ministry of Education), Zhejiang Sci-Tech University, Hangzhou 310018, China

摘要

摘要: 非均相芬顿氧化作为一种典型的高级氧化技术，主要通过活化H₂O₂产生具有强氧化性的羟基自由基等活性氧物种降解有机污染物，广泛应用于工业废水和生活污水的深度处理。铁基非均相芬顿催化剂作为当前的研究热点，虽具有环境友好、成本低廉等优点，但仍然存在催化效率低、pH适用范围窄等局限。近年来，相关学者在拓宽铁基非均相芬顿催化剂pH适用范围、提高催化活性方面作了大量研究，有效改善了芬顿氧化技术的不足。系统介绍了非均相芬顿氧化的基本原理和拓宽pH适用范围的强化机制，综述了近几年国内外通过引入物理外场、化学助剂辅助诱导和催化剂内部结构调控等策略在拓宽pH适用范围的最新进展，提出了当前研究亟待解决的科学问题和未来发展方向，可为开发具有宽pH适用范围的高芬顿活性的非均相铁基催化剂提供参考。
- 非均相芬顿 /
- 铁基催化剂 /
- 宽pH适用性 /
- Fe（Ⅲ）/Fe（Ⅱ）循环 /
- 废水处理
Abstract: Heterogeneous Fenton oxidation， a representative advanced oxidation technology， primarily degrades organic pollutants by activating H₂O₂ to generate highly oxidative reactive oxygen species， such as hydroxyl radicals. This method has been widely applied in the advanced treatment of industrial and domestic wastewater. Iron-based heterogeneous Fenton catalysts have gathered significant research interest， due to their eco-friendliness and low cost. However， challenges such as low catalytic efficiency and a narrow applicable pH range remain. In recent years， substantial efforts have been made to broaden the pH range and enhance the catalytic activity of iron-based heterogeneous Fenton catalysts， effectively addressing some limitations of the Fenton oxidation process. This review systematically introduces the fundamental principles of heterogeneous Fenton oxidation and the mechanisms for extending its pH applicability. It also summarizes recent advances， both domestically and internationally， in strategies such as the introduction of external physical fields， chemical auxiliary agents， and internal structural regulation of catalysts to broaden the pH range. Additionally， it highlights critical scientific issues that need to address and discusses future research directions， providing valuable insights for developing high-activity iron-based heterogeneous Fenton catalysts with a wide pH applicability.
- heterogeneous Fenton catalysis /
- iron-based catalyst /
- wide pH applicability /
- Fe(Ⅲ)/Fe(Ⅱ) cycle /
- wastewater treatment

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