纳米功能化陶瓷膜在饮用水处理中的研究进展与挑战

孙志强; 谭伊让; 李昊文; 田禹; 马军; 隋潇

doi:10.13205/j.hjgc.202509002

纳米功能化陶瓷膜在饮用水处理中的研究进展与挑战

doi: 10.13205/j.hjgc.202509002

孙志强¹,
谭伊让²,
李昊文²,
田禹¹,
马军¹,
隋潇^1,2, ,

1. 哈尔滨工业大学城市水资源和水环境国家重点实验室, 哈尔滨 150090;
2. 哈尔滨工业大学(威海) 海洋科学与技术学院, 山东威海 264209

基金项目:

国家自然科学基金面上项目“体相氧空位耦合膜限域催化臭氧高选择性净水增效机制研究”（52470003）；国家自然科学基金青年科学基金项目（C类）“可调变碳点‘双控’二维COFs纳滤膜构建及其强化PFAS广谱性分离机制”（22506033）

详细信息

作者简介:
孙志强（1991—），男，教授，主要研究方向为水质深度处理理论与技术。sunhit@hit.edu.cn

通讯作者:
隋潇（1990—），女，副教授，主要研究方向为膜法水处理技术。suixiao@hit.edu.cn

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出版历程
- 收稿日期: 2025-09-09
- 网络出版日期: 2025-11-05
- 刊出日期: 2025-09-01

Research progress and challenges of nano-functionalized ceramic membranes in drinking water treatment

SUN Zhiqiang¹,
TAN Yirang²,
LI Haowen²,
TIAN Yu¹,
MA Jun¹,
SUI Xiao^{1,2
, ,}

1. State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China;
2. School of Marine Science and Technology, Harbin Institute of Technology, Weihai 264209, China

摘要

摘要: 饮用水安全是保障人类健康和社会发展的基石。随着水质标准的不断提高，具有高分离效率和长寿命优势的陶瓷膜在水处理领域展现出巨大潜力。纳米功能化陶瓷膜技术是提升饮用水水质与处理效率的前沿方向。系统综述了纳米材料改性陶瓷膜在饮用水处理中的前沿进展。概述了陶瓷膜的材料、结构及其过滤机理，详细阐述了纳米改性陶瓷膜的不同改性体系，分析了其在饮用水处理技术中的性能效果，如显著提升膜通量、增强污染物去除能力与抗污染性能。最后，探讨了该技术迈向规模化应用所面临的挑战：纳米材料分散性差、纳米材料浸出风险和膜污染问题，并对其未来发展路径进行了展望。文章聚焦于该技术从实验室迈向规模化应用进程中面临的技术瓶颈，系统梳理了不同纳米改性体系及其性能效果，旨在为推动纳米功能化陶瓷膜技术的深入研究与未来的产业化应用提供理论参考。
- 陶瓷膜 /
- 纳米材料 /
- 膜改性 /
- 功能化 /
- 饮用水处理
Abstract: Drinking water safety is fundamental to safeguarding human health and social development. With continuously improving national water quality standards， ceramic membranes—characterized by high separation efficiency and long service life—have demonstrated significant potential in the field of water treatment. Nano-functionalized ceramic membrane technology represents a cutting-edge approach to enhancing the quality and separation performance efficiency of drinking water. This paper provides a systematic review of recent advances in nanomaterial-modified ceramic membranes for drinking water treatment. First， an overview of the materials， structure， and separation mechanisms of ceramic membranes is provided. Subsequently， various modification strategies using nanomaterials are elaborated， with an analysis of their performance in drinking water treatment processes， including significantly improved membrane flux， enhanced contaminant removal， and fouling resistance. Finally， the challenges hindering the large-scale application of this technology are discussed， such as poor nanomaterial dispersion， potential nanomaterial leaching， membrane fouling issues， and then perspectives on future development pathways are proposed. This paper not only systematically reviews various modification systems and their performance but also focuses specifically on the technical bottlenecks encountered during the transition from laboratory research to large-scale implementation. It can offer insights for promoting in-depth research and future industrial applications of nano-functionalized ceramic membrane technology.
- ceramic membrane /
- nanomaterial /
- membrane modification /
- functionalization /
- drinking water treatment

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参考文献(64)

[1]	CHENG Z Q，PENG X H，CHEN Z W，et al. Exploration on the construction path of high-quality drinking water under the background of the new national standard[J]. China Water & Wastewater，2024，40（18）:8-14. 程志强，彭秀华，陈志伟，等. 新国标背景下高品质饮用水建设路径探索[J]. 中国给水排水，2024，40（18）:8-14.
[2]	ZENG C，ZHANG T Y，HE H，et al. Analysis on key issues and development paths for municipal drinking water quality improvement[J]. Energy Environmental Protection，2025，39（1）:1-10. 曾超，张天阳，何欢，等. 市政饮用水品质提升关键问题与发展路径分析[J]. 能源环境保护，2025，39（1）:1-10.
[3]	DONG B Z，XIAO J，HUA J L，et al. Thoughts on high-quality drinking water and practice in Suzhou[J]. Water & Wastewater Engineering，2021，57（8）:19-27. 董秉直，肖健，华建良，等. 高品质饮用水的思考以及苏州实践[J]. 给水排水，2021，57（8）:19-27.
[4]	LI C，SUN W，LU Z，et al. Ceramic nanocomposite membranes and membrane fouling:a review[J]. Water Research，2020，175:115674.
[5]	DONG Y，WU H，YANG F，et al. Cost and efficiency perspectives of ceramic membranes for water treatment[J]. Water Research，2022，220[ 2025-09-04].
[6]	ZHU H，PAN Y，SUN X，et al. Recycle of ceramic substrate of PDMS/ceramic composite membranes towards alcohol-permselective pervaporation[J]. Journal of Membrane Science，2021，640:119835.
[7]	LIN Z，LIU L，ZHANG C，et al. Emerging conductive ceramic membranes for water purification and membrane fouling mitigation[J]. Chemical Engineering Journal，2024，493:152474.
[8]	OMAR N M A，OTHMAN M H D，TAI Z S，et al. Overcoming challenges in water purification by nanocomposite ceramic membranes:A review of limitations and technical solutions[J]. Journal of Water Process Engineering，2024，57:104613.
[9]	KIM J，van der BRUGGEN B. The use of nanoparticles in polymeric and ceramic membrane structures:Review of manufacturing procedures and performance improvement for water treatment[J]. Environmental Pollution，2010，158（7）:2335-2349.
[10]	WU Y Z，SHAREEF U，XU J P，et al. Carbon quantum dots doped thin-film nanocomposite（TFN）membrane on macroporous ceramic hollow fiber support via one-step interfacial polymerization[J]. Separation and Purification Technology，2021，266:118572.
[11]	WU Y Z，LI H X，XU Z L，et al. Ceramic hollow fiber NF membrane incorporating UiO-66 for the chlorinated hydrocarbons removal[J]. Chemical Engineering Journal，2022，435:134789.
[12]	WU M，SUN Y，JI T，et al. Fabrication of water-stable MOF-808 membrane for efficient salt/dye separation[J]. Journal of Membrane Science，2023，686:122023.
[13]	PANG L，WU M，CHAI Z，et al. Preparation and dye separation performance of ZIF-67/mesoporous silica ceramic nanofiltration membrane by liquid phase epitaxy（LPE）growth method[J]. Separation and Purification Technology，2023，322:124339.
[14]	SUN S，YAO H，FU W，et al. Reactive Photo-Fenton ceramic membranes:synthesis，characterization and antifouling performance[J]. Water Research，2018，144:690-698.
[15]	FAN Y，ZHOU Y，FENG Y，et al. Fabrication of reactive flat-sheet ceramic membranes for oxidative degradation of ofloxacin by peroxymonosulfate[J]. Journal of Membrane Science，2020，611:118302.
[16]	WANG Y，MA B，ULBRICHT M，et al. Progress in alumina ceramic membranes for water purification:Status and prospects[J]. Water Research，2022，226:119173.
[17]	MALZBENDER J. Mechanical aspects of ceramic membrane materials[J]. Ceramics International，2016，42（7）:7899-7911.
[18]	YAO Y，LI G，GRAY K A，et al. Single-walled carbon nanotube-facilitated dispersion of particulate TiO₂ on ZrO₂ ceramic membrane filters[J]. Langmuir，2008，24（14）:7072-7075.
[19]	YANG R，YANG Y，WANG Y，et al. MgO-Al₂O₃-SiO₂-ZrO₂ system ceramic glass as sintering aids to fabricate Al₂O₃ceramic membrane with high acid corrosion resistance[J]. Separation and Purification Technology，2023，323:124231.
[20]	JING P，LIU M，WANG P，et al. Flexible nonwoven ZrO₂ceramic membrane as an electrochemically stable and flame-resistant separator for high-power rechargeable batteries[J]. Chemical Engineering Journal，2020，388:124259.
[21]	SOLAIMAN J M，RAJAMOHAN N，YUSUF M，et al. Nanocomposite ceramic membranes as novel tools for remediation of textile dye waste water:a review of current applications，machine learning based modeling and future perspectives[J]. Journal of Environmental Chemical Engineering，2024，12（2）:112353.
[22]	LIANG Y，WANG Y，QIAN J，et al. Effects of low-melting-point sintering aid MoO₃on the performance of SiC ceramic membrane supports and the underlying mechanisms[J]. Journal of Alloys and Compounds，2025，1027:180675.
[23]	HUANG L，QIN H，HU T，et al. Fabrication of high permeability SiC ceramic membrane with gradient pore structure by one-step freeze-casting process[J]. Ceramics International，2021，47（12）:17597-17605.
[24]	YUE X，ZHANG T，YANG D，et al. Fabrication of flexible ceramic membranes derived from hard Si₃N₄and soft MnO₂ nanowires[J]. Ceramics International，2020，46（6）:8478-8482.
[25]	LIU Y，ZHANG L，ZHANG R，et al. Thermal insulating and fire-retardant Si₃N₄ nanowire membranes resistant to high temperatures up to 1300 ℃[J]. Journal of Materials Science & Technology，2023，155:82-88.
[26]	CHOUGUI A，BELOUATEK A，RABILLER-Baudry M. Synthesis and characterization of new ultrafiltration ceramic membranes for water treatment[J]. Journal of Water Process Engineering，2019，30:100620.
[27]	JARVIS P，CARRA I，JAFARI M，et al. Ceramic vs polymeric membrane implementation for potable water treatment[J]. Water Research，2022，215:118269.
[28]	GRAY S，DONG Y，WINNUBST L，et al. Special issue:ceramic membrane for water treatment[J]. Water Research，2023，240:120095.
[29]	HUBADILLAH S K，JAMALLUDIN M R，DZARFAN Othman M H，et al. Recent progress on low-cost ceramic membrane for water and wastewater treatment[J]. Ceramics International，2022，48（17）:24157-24191.
[30]	SAMADI A，GAO L，KONG L，et al. Waste-derived low-cost ceramic membranes for water treatment:opportunities，challenges and future directions[J]. Resources，Conservation and Recycling，2022，185:106497.
[31]	AZADI F，KARIMI-JASHNI A，ZERAFAT M M，et al. Fabrication，optimization，and performance of a novel double-skinned Al₂O₃，TiO₂ ceramic nanocomposite membrane for forward osmosis application[J]. Environmental Technology & Innovation，2021，22:101423.
[32]	PRESUMIDO P H，SANTOS L F，NEUPARTH T，et al. A novel ceramic tubular membrane coated with a continuous graphene-TiO₂ nanocomposite thin-film for CECs mitigation[J]. Chemical Engineering Journal，2022，430:132639.
[33]	LE M H，KIM K J，JEONG S，et al. Effect of charged nano-particles on ceramic microfiltration membrane fouling[J]. Journal of Industrial and Engineering Chemistry，2019，72:125-132.
[34]	DLAMINI D S，MAMBA B B，LI J. The role of nanoparticles in the performance of nano-enabled composite membranes-a critical scientific perspective[J]. Science of the Total Environment，2019，656:723-731.
[35]	GUO Y，XU B，QI F. A novel ceramic membrane coated with MnO₂-Co₃O₄ nanoparticles catalytic ozonation for benzophenone-3 degradation in aqueous solution:Fabrication，characterization and performance[J]. Chemical Engineering Journal，2016，287:381-389.
[36]	MIAO K，LIU S，LI H，et al. Efficient construction and transfer mechanism of high-flux ceramic membranes for membrane distillation[J]. Journal of Membrane Science，2025，734:124445.
[37]	TAO S，XU Y D，GU J Q，et al. Preparation of high-efficiency ceramic planar membrane and its application for water desalination[J]. Journal of Advanced Ceramics，2018，7（2）:117-123.
[38]	WU J，XUE S，BRIDGES D，et al. Fe-based ceramic nanocomposite membranes fabricated via e-spinning and vacuum filtration for Cd²⁺ ions removal[J]. Chemosphere，2019，230:527-535.
[39]	LI H，FU M，WANG S Q，et al. Stable Zr-based metal-organic framework nanoporous membrane for efficient desalination of hypersaline water[J]. Environmental Science and Technology，2021，55（21）:14917-14927.
[40]	WANG C，SUN H，WANG N，et al. Robust ZIF-8 and its derivative composite membrane for antibiotic desalination with high performance[J]. Separation and Purification Technology，2023，307:122857.
[41]	WANG X，LYU Q，TONG T，et al. Robust ultrathin nanoporous MOF membrane with intra-crystalline defects for fast water transport[J]. Nature Communications 2022 13:1，2022，13（1）:1-11.
[42]	WANG T，YUN Y，WANG M，et al. Superhydrophobic ceramic hollow fiber membrane planted by ZnO nanorod-array for high-salinity water desalination[J]. Journal of the Taiwan Institute of Chemical Engineers，2019，105:17-27.
[43]	MENG X，LIU Z，DENG C，et al. Microporous nano-MgO/diatomite ceramic membrane with high positive surface charge for tetracycline removal[J]. Journal of Hazardous Materials，2016，320:495-503.
[44]	DONG Y，MA L，TANG C Y，et al. Stable superhydrophobic ceramic-based carbon nanotube composite desalination membranes[J]. Nano Letters，2018，18（9）:5514-5521.
[45]	ZHANG S，DU Y，JIANG H，et al. Controlled synthesis of TiO₂ nanorod arrays immobilized on ceramic membranes with enhanced photocatalytic performance[J]. Ceramics International，2017，43（9）:7261-7270.
[46]	ALIAS N H，JAAFAR J，SAMITSU S，et al. Photocatalytic nanofiber-coated alumina hollow fiber membranes for highly efficient oilfield produced water treatment[J]. Chemical Engineering Journal，2019，360:1437-1446.
[47]	PLAKAS K V.，MANTZA A，SKLARI S D，et al. Heterogeneous Fenton-like oxidation of pharmaceutical diclofenac by a catalytic iron-oxide ceramic microfiltration membrane[J]. Chemical Engineering Journal，2019，373:700-708.
[48]	WANG Y，HUI S，ZHAN S，et al. Activation of peroxymonosulfate by novel Pt/Al₂O₃ membranes via a nonradical mechanism for efficient degradation of electron-rich aromatic pollutants[J]. Chemical Engineering Journal，2020，381:122563.
[49]	LEE Y，CHA M，SO Y，et al. Functionalized boron nitride ceramic nanofiltration membranes for semiconductor wastewater treatment[J]. Separation and Purification Technology，2022，300:121945.
[50]	CHOUDHURY P，MONDAL P，MAJUMDAR S，et al. Preparation of ceramic ultrafiltration membrane using green synthesized CuO nanoparticles for chromium（Ⅵ）removal and optimization by response surface methodology[J]. Journal of Cleaner Production，2018，203:511-520.
[51]	YAN Q，QIU M，CHEN X，et al. Ultrasound assisted synthesis of size-controlled aqueous colloids for the fabrication of nanoporous zirconia membrane[J]. Frontiers in Chemistry，2019，7（May）:435453.
[52]	ZHANG N，DONG H，WANG Y，et al. Sacrificial GO-BD interlayer for high performance ceramic ultrafiltration membrane[J]. Materials Today Communications，2024，38:107730.
[53]	WANG X，ZHAI L，WANG Y，et al. Improving water-treatment performance of zirconium metal-organic framework membranes by postsynthetic defect healing[J]. ACS Applied Materials and Interfaces，2017，9（43）:37848-37855.
[54]	LIU Y，LIU S，ZHANG W H，et al. MoS₂/MoO₃ heterostructure ceramic membrane for nanofiltration[J]. Journal of Membrane Science，2025，727:124098.
[55]	LI P，LI Y X，WU Y Z，et al. Thin-film nanocomposite NF membrane with GO on macroporous hollow fiber ceramic substrate for efficient heavy metals removal[J]. Environmental Research，2021，197:111040.
[56]	WANG S，TIAN J，WANG Q，et al. Low-temperature sintered high-strength CuO doped ceramic hollow fiber membrane:Preparation，characterization and catalytic activity[J]. Journal of Membrane Science，2019，570/571:333-342.
[57]	LIU Y，ZHU W，GUAN K，et al. Preparation of high permeable alumina ceramic membrane with good separation performance via UV curing technique[J]. RSC Advances，2018，8（24）:13567-13577.
[58]	GONG B，CHEN W，QIAN C，et al. Contribution of proteins to ceramic membrane fouling at the early stage of membrane filtration[J]. Separation and Purification Technology，2023，312:123450.
[59]	CAI C，SUN W，HE S，et al. Ceramic membrane fouling mechanisms and control for water treatment[J]. Frontiers of Environmental Science and Engineering，2023，17（10）:1-15.
[60]	LEFATSHE K，DUBE P，SEBUSO D，et al. Optical dispersion analysis of template assisted 1D-ZnO nanorods for optoelectronic applications[J]. Ceramics International，2021，47（6）:7407-7415.
[61]	MARLOW W H. Van der WAALS Energies in the Formation and Interaction of Nanoparticle Aggregates[J]. Gas Phase Nanoparticle Synthesis，2004:1-27.
[62]	HIREMATH A，MURTHY A A，THIPPERUDRAPPA S，et al. Nanoparticles Filled Polymer Nanocomposites:A Technological Review[J]. Cogent Engineering，2021，8（1），1956319.
[63]	LI Q，JIA R，SHAO J，et al. Photocatalytic degradation of amoxicillin via TiO₂ nanoparticle coupling with a novel submerged porous ceramic membrane reactor[J]. Journal of Cleaner Production，2019，209:755-761.
[64]	CHANG S，AHMAD R，KWON D，et al. Hybrid ceramic membrane reactor combined with fluidized adsorbents and scouring agents for hazardous metal-plating wastewater treatment[J]. Journal of Hazardous Materials，2020，388:121777.