黄河中游流域地表水中酚类污染来源、分布特征及其生态风险

谢咏昌; 刘权震; 徐雄; 林利华; 杜川; 王东红; 林明利

doi:10.13205/j.hjgc.202512002

黄河中游流域地表水中酚类污染来源、分布特征及其生态风险

doi: 10.13205/j.hjgc.202512002

谢咏昌^1,2,
刘权震¹,
徐雄¹,
林利华¹,
杜川^1,2,
王东红^1,2, ,,
林明利³

1. 中国科学院生态环境研究中心工业废水无害化与资源化国家工程研究中心, 北京 100085;
2. 中国科学院大学, 北京 100049;
3. 中国城市规划设计研究院, 北京 100875

基金项目:

国家重点研发计划（2021YFC3200802-02）；国家自然科学基金项目（22406193）

详细信息

作者简介:
谢咏昌（1997—），男，博士研究生，主要研究方向为水体中有机污染物筛查。ycxie_st@rcees.ac.cn

通讯作者:
王东红（1968—），女，研究员，主要研究方向为水环境中风险污染物的识别及其转化机制。dhwang@rcees.ac.cn

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出版历程
- 收稿日期: 2025-01-15
- 录用日期: 2025-03-02
- 修回日期: 2025-02-20
- 网络出版日期: 2026-01-09

Source， distribution characteristics and ecological risk assessment of phenolic compounds in surface water of middle reach of the Yellow River Basin

1. National Engineering Research Center of Industrial Wastewater Detoxication and Resource Recovery, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;
2. University of Chinese Academy of Sciences, Beijing 100049, China;
3. China Academy of Urban Planning and Design, Beijing 100875, China

摘要

摘要: 通过分析黄河中游煤化工工业园区13种酚类化合物的排放特征，研究工业排水对黄河干流中酚类污染物的贡献及影响。结果表明：黄河中游5个工业园区排污口和18个河流断面（包括支流如汾河的断面采样点）分别检出6种和7种酚类化合物，其总浓度分别为115.66~38462.44，44.13~2568.32 ng/L。排污口和河流断面的主要酚类污染物均为苯酚、邻甲苯酚和对甲苯酚。酚类在工业园区排污口的排放总浓度普遍高于其上游和下游断面，且排污口相近的河流断面中酚类污染物种类及浓度占比相似，表明工业园区污水排放是黄河干流中酚类污染的重要来源之一。采用风险商的方法评估酚类污染的生态风险，结果表明苯酚、邻甲苯酚和对甲苯酚在大部分采样点中存在中、低生态风险，而汾河中下游河流的采样点普遍存在潜在生态风险，因此这些酚类污染物和汾河中下游流域需重点关注。研究可为黄河中游流域酚类污染治理提供理论支撑和科学依据。
- 酚类化合物 /
- 黄河流域 /
- 地表水 /
- 生态风险 /
- 来源 /
- 煤化工
Abstract: This study presented an analysis of the emission characteristics of 13 phenolic compounds within coal chemical industry parks situated in the middle reach of the Yellow River Basin. The contribution and impact of industrial wastewater on the prevalence of phenolic pollutants in the mainstream of the Yellow River were investigated. A total of 6 and 7 phenolic pollutants were identified in 5 industrial wastewater discharge outlets and 18 river cross-section sampling sites （including the tributary sampling sites such as the Fen River）， with the total concentration range from 115.66 to 38462.44 ng/L， and 44.13 to 2568.32 ng/L， respectively. Phenol， o-cresol， and p-cresol were the most dominant pollutants at these sampling sites. The total concentration of phenols discharged at the industrial wastewater discharge outlets was generally higher than that at the upstream and downstream sections. Sampling sites within the same industrial area exhibited similar types and concentration proportions of pollutants， suggesting that emissions from industrial areas were one of the main sources of phenolic pollution in the surface water of the Yellow River Basin. The ecological risk quotient method was employed to assess the risk of these phenolic pollutions， and the results indicated that phenol， p-cresol， 2-chlorophenol， and 2-nitrophenol posed potential ecological risks in the majority of sampling sites， while ecological risks were prevalent in the sampling points of the middle and lower reaches of the Fen River. Therefore， these phenolic pollutants and the middle and lower reaches of the Fen River basin require focused attention. This study can provide theoretical support and a scientific basis for phenol pollution control in the middle reach of the Yellow River Basin.
- phenolic compound /
- the Yellow River Basin /
- surface water /
- ecological risk /
- source /
- coal chemical industry

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