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膜接触反应器强化臭氧传质机制与印染废水处理应用研究进展

杨帆,  王振华,  戴高奇,  罗金明,  余德游

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文章导航 > 环境工程  > 2026 >  44(3): 30-45
杨帆, 王振华, 戴高奇, 罗金明, 余德游. 膜接触反应器强化臭氧传质机制与印染废水处理应用研究进展[J]. 环境工程, 2026, 44(3): 30-45. doi: 10.13205/j.hjgc.202603003
引用本文: 杨帆, 王振华, 戴高奇, 罗金明, 余德游. 膜接触反应器强化臭氧传质机制与印染废水处理应用研究进展[J]. 环境工程, 2026, 44(3): 30-45. doi: 10.13205/j.hjgc.202603003
shu
YANG Fan, WANG Zhenhua, DAI Gaoqi, LUO Jinming, YU Deyou. Progress on ozone mass transfer enhancement mechanisms in membrane contactor reactors and their applications in textile dyeing and finishing wastewater treatment[J]. ENVIRONMENTAL ENGINEERING , 2026, 44(3): 30-45. doi: 10.13205/j.hjgc.202603003
Citation: YANG Fan, WANG Zhenhua, DAI Gaoqi, LUO Jinming, YU Deyou. Progress on ozone mass transfer enhancement mechanisms in membrane contactor reactors and their applications in textile dyeing and finishing wastewater treatment[J]. ENVIRONMENTAL ENGINEERING , 2026, 44(3): 30-45. doi: 10.13205/j.hjgc.202603003
shu

膜接触反应器强化臭氧传质机制与印染废水处理应用研究进展

doi: 10.13205/j.hjgc.202603003

  • 1. 浙江理工大学 生物基纤维材料全国重点实验室，杭州 310018;

  • 2. 上海交通大学 环境科学与工程学院，上海 200240;

  • 3. 浙江理工大学 生态染整技术教育部工程研究中心，杭州 310018

基金项目: 

国家自然科学基金项目（22476183，22106141）；浙江省重点研发计划（2026C02A1004）

详细信息
    作者简介:

    杨帆（2000—），女，硕士研究生，主要研究方向为膜接触臭氧反应器在印染废水处理中的应用。2023220202120@mails.zstu.edu.cn

    通讯作者:

    罗金明（1989—），男，研究员，主要从事关键金属及新污染物去除与资源化相关的环境功能材料的设计/开发与基础/应用研究。jinmng.luo@sjtu.edu.cn；罗金明（1989—），男，研究员，主要从事关键金属及新污染物去除与资源化相关的环境功能材料的设计/开发与基础/应用研究。jinmng.luo@sjtu.edu.cn

Progress on ozone mass transfer enhancement mechanisms in membrane contactor reactors and their applications in textile dyeing and finishing wastewater treatment

  • 1. State Key Laboratory of Bio-based Fiber Materials，Zhejiang Sci-Tech University，Hangzhou 310018，China;

  • 2. School of Environmental Science and Engineering，Shanghai Jiao Tong University，Shanghai 200240，China;

  • 3. Engineering Research Center of Ecological Dyeing and Finishing Technology （Ministry of Education），Zhejiang Sci-Tech University，Hangzhou 310018，China

    摘要
  • 摘要: 臭氧氧化技术作为印染废水深度处理的有效手段，其规模化应用受限于臭氧传质效率低的核心瓶颈。膜接触反应器（membrane contactor reactor，MCR）通过构筑微尺度气液界面，可显著强化臭氧传质过程，兼具传质效率高与无二次污染等优势，但膜污染、材料成本及运行稳定性等问题制约了其工程化推广。系统综述了MCR强化臭氧传质机制的研究进展，介绍了气液界面传质原理与中空纤维膜反应器构型设计规律，解析了膜材料特性（疏水性PTFE/PVDF选择）、工艺参数（气液流速、跨膜压差、pH值）及传质模型对臭氧体积传质系数的调控规律，评述了MCR在印染废水处理中对染料高效脱除、有机物矿化及色度控制的应用效能。研究表明：优化后的MCR系统臭氧体积传质系数比传统鼓泡塔工艺高5~10倍，大幅强化了污染物降解动力学，但膜污染引发的通量衰减、溴酸盐副产物生成及成本效益平衡仍需突破。最后，提出未来研究需重点关注抗污染-耐腐蚀-低成本协同的多功能复合膜材料的理性设计、超重力场/电催化等多技术耦合的界面反应机制解析、基于过程模型的智能参数调控体系构建、中试规模的技术经济性与环境风险综合评价方法等方向，为MCR-臭氧工艺的工程应用提供理论依据与技术参考。
    Abstract: Ozonation is an effective advanced treatment technology for textile dyeing and finishing wastewater； however， its large-scale application is primarily constrained by its intrinsically low ozone mass transfer efficiency. Membrane contactor reactors （MCRs） can significantly enhance ozone mass transfer by constructing microscale gas-liquid interfaces， offering advantages such as high mass transfer efficiency and the absence of secondary pollution. Nevertheless， issues including membrane fouling， high material costs， and poor operational stability still limit their engineering-scale implementation. This study systematically reviewed recent advances in the mechanisms of ozone mass transfer enhancement in MCRs. The principles of gas-liquid interfacial mass transfer and the design characteristics of hollow fiber membrane contactor configurations were introduced. The regulatory effects of membrane material properties （e.g.， the selection of hydrophobic PTFE/PVDF）， operating parameters （gas-liquid flow rates， transmembrane pressure， and pH）， and mass transfer models on the volumetric ozone mass transfer coefficient were critically analyzed. Furthermore， the application efficiency of MCRs in textile dyeing and finishing wastewater treatment was evaluated， with particular emphasis on efficient dye removal， organic matter mineralization， and decolorization. Research demonstrated that optimized MCR systems could increase the volumetric ozone mass transfer coefficient by 5~10 times compared with conventional bubble column processes， thereby substantially enhancing the kinetics of pollutant degradation. However， challenges such as membrane fouling-induced flux decline， bromate by-product formation， and cost-benefit optimization remained to be addressed. Finally， future research directions were proposed， focusing on the rational design of multifunctional composite membranes integrating antifouling properties， corrosion resistance， and low cost； the elucidation of interfacial reaction mechanisms through coupling with intensified fields such as high-gravity and electrocatalytic processes； the development of intelligent parameter regulation systems based on process modeling； and comprehensive techno-economic and environmental risk assessments at the pilot scale. These efforts will provide theoretical support and technical guidance for the engineering application of MCR-ozone processes.
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  • 收稿日期:  2025-12-10
  • 网络出版日期:  2026-04-11
  • 刊出日期:  2026-03-01

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