树脂增强电吸附水处理技术研究进展

熊奇坤; 王欣奕; 刘炜荣; 唐英才; 马丽新; 刘宝震; 包环宇

doi:10.13205/j.hjgc.202606008

树脂增强电吸附水处理技术研究进展

doi: 10.13205/j.hjgc.202606008

1. 中规院(北京)规划设计有限公司, 北京 100044;
2. 兰州交通大学环境与市政工程学院, 兰州 730070;
3. 海南大学环境科学与工程学院, 海口 570228;
4. 清华大学环境学院, 北京 100084;
5. 山东建筑大学市政与环境工程学院, 济南 250101

基金项目:

国家自然科学基金青年科学基金项目“磁性流动电极电吸附去除小分子有机物的磁场调控原理及电磁协同机制”（52400043）

详细信息

作者简介:
熊奇坤(1994-),男,工程师,主要研究方向为城市内涝、海绵城市和市政工程等研究。634459468@qq.com

通讯作者:
唐英才(1996-),男,副研究员,主要研究方向为环境污染物吸附去除技术及其理论前沿研究。tangyingcai@hainanu.edu.cn

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出版历程
- 收稿日期: 2025-02-05
- 录用日期: 2025-03-01
- 修回日期: 2025-02-25
- 网络出版日期: 2026-07-06

Research advances in resin-enhanced electrosorption for water treatment

1. CAUPD Beijing Planning Design Consultants Ltd, Beijing 100044, China;
2. School of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China;
3. School of Environmental Science and Engineering, Hainan University, Haikou 570228, China;
4. School of Environment, Tsinghua University, Beijing 100084, China;
5. College of Environmental and Municipal Engineering, Shandong Jianzhu University, Ji'nan 250101, China

摘要

摘要: 树脂增强电吸附水处理技术通过协同效应显著提高了离子吸附效率和选择性，成为水处理领域的研究热点。该技术通过多维度调控电极-溶液界面行为，为解决动力学迟滞和选择性不足等瓶颈提供了创新方案。通过简单集成技术，可使脱盐效率突破92.3%；树脂涂层复合电极可有效消除共离子效应，使得总盐吸附容量提升42%；树脂衍生多孔碳电极具备可调孔隙结构，其吸附容量为市售活性炭的3~5倍；通过增强溶液对流和电对流效应，树脂填充策略实现了（670±20） mg/（L·h）的高脱盐速率。不同结合形式可根据特定水质特征，实现吸附性能的定向优化。未来的研究可进一步开发具有电/磁响应特性的树脂材料，构建树脂-电极多尺度结构设计理论，建立跨尺度模型，融合电化学、流体动力学与界面科学的全方位分析，特别是需要深入研究电/磁场调控下树脂基流动电极的动态变化规律，以及树脂表面催化位点的精准构建。文章旨在推动该技术在水处理领域的广泛应用与高效实践，为未来开发高效、选择性和稳定性的电吸附技术提供理论支持和科学依据。
- 电吸附 /
- 树脂 /
- 外场调控 /
- 磁性材料 /
- 水处理技术
Abstract: Resin-enhanced electrosorption for water treatment significantly improves ion adsorption efficiency and selectivity through synergistic effects， making it a research hotspot in the water treatment field. This technology provides an innovative solution to the bottlenecks of kinetic lag and insufficient selectivity by modulating electrode-solution interface behavior in multiple dimensions. Current technological advances include the following： a simple integration method enables desalination efficiency to exceed 92.3%； resin-coated composite electrodes eliminate the co-ion effect and achieve a 42% increase in total salt adsorption capacity； resin-derived porous carbon electrodes with tunable pore structures possess three to five times the adsorption capacity of commercially available activated carbon； and by enhancing solution convection and electrophoretic convection， the resin-filling strategy achieves a high desalination rate of （670 ± 20） mg/（L·h）. Studies have demonstrated that different material combinations can achieve targeted optimization of adsorption performance based on specific water quality characteristics. Future research directions may focus on： developing intelligent resin materials with electromagnetic responsiveness； constructing a multi-scale structural design theory for resin-electrode systems； and establishing a cross-scale model integrating electrochemistry， fluid dynamics， and interface science for comprehensive analysis. In particular， in-depth studies are needed on the dynamic behavior of resin-based flow electrodes under electric/magnetic field regulation， as well as the precise construction of catalytic sites on the resin surface. This review aims to promote the widespread application and efficient practice of this technology in water treatment， providing a theoretical foundation and scientific basis for the future development of high-efficiency， selective， and stable electrosorption technologies.
- electrosorption /
- resin /
- external field regulation /
- magnetic material /
- water treatment technology

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参考文献(74)

[1]	LIU R，ZHANG Q Q，YAO S G，et al. Multi-physies simulation and comparative analysis of CDI/MCDI desalination process[J]. Ship Science and Technology，2022，44（23）：54-59. 刘锐，张琪琪，姚寿广，等. CDI/MCDI法海水淡化过程多物理场模拟及对比分析[J]. 舰船科学技术，2022，44（23）：54-59.
[2]	BALES C，KINSELA A S，MILLER C，et al. Removal of trace uranium from groundwaters using membrane capacitive deionization desalination for potable supply in remote communities：Bench，pilot，and field scale investigations[J]. Environmental Science& Technology，2023，57（30）：11345-11355.
[3]	LUO D K，TONG P P，LI Z H，et al. Achieving high-quality effluent and low-carbon emission through coupling fluidized pellet bed and capacitive deionization[J]. Energy Environmental Protection，2025，39（1）：173-180. 罗定坤，仝培培，李志华，等. 耦合流化床和电容去离子实现污水处理高效达标与低碳化运行[J]. 能源环境保护，2025，39（1）：173-180.
[4]	TAN C，LI B，WANG A，et al. The application of capacitive deionization technology based on activated carbon electrode to produce pure water[J]. Chemistry and Industry of Forest Products，2023，43（1）：72-78. 檀畅，李蓓，王傲，等. 基于活性炭电极的电容去离子技术制备纯水应用研究[J]. 林产化学与工业，2023，43（1）：72-78.
[5]	MA L. Experimental study on the application of capacitivedeionization technology in desalination of circulatingcooling sewage in power plants[D]. Beijing：North China Electric Power University，2021. 马岚. 电容去离子技术用于电厂循环冷却排污水脱盐实验研究[D]. 北京：华北电力大学，2021.
[6]	WU H，PANG Y W，CHENG H G，et al. Carbon-based electrode materials and capacitive deionization technology for seawater desalination[J]. Chemistry，2022，85（8）：898-908. 吴浩，庞义炜，成怀刚，等. 海水淡化用碳基电极材料及电容去离子技术研究进展[J]. 化学通报，2022，85（8）：898-908.
[7]	ZHAO B H，LIU X N，HU Y Y，et al. Comparison and development trend of traditional electroadsorption and flow electrode capacitive deion technology[J]. Chemical Industry and Engineering Progress，2025，44（7）：4101-4116. 赵保华，刘晓娜，胡彦云，等. 传统电吸附与流动电极电容去离子技术对比和技术发展趋势[J]. 化工进展，2025，44（7）：4101-4116.
[8]	HE S M，XIONG W，GAO X L，et al. Research progress and prospects of capacitive deionization technology in water treatment[J]. Chemical Industry and Engineering Progress，2025，44（11）：6660-6673. 贺舒敏，熊伟，高小龙，等. 电容去离子技术在水处理中的研究进展[J]. 化工进展，2025，44（11）：6660-6673.
[9]	LI X L，LI H X. Energy consumption of seawater reverse osmosis system[J]. Industrial Water Treatment，2002（10）：56-57. 李秀莉，李宏秀. 海水反渗透淡化系统的能耗[J]. 工业水处理，2002（10）：56-57.
[10]	SU H C，LI F S，XU G R，et al. Hybrid membrane inter-stage design for RO seawater desalination system[J]. Water Purification Technology，2024，43（1）：132-139. 苏慧超，李逢时，徐国荣，等. 反渗透海水淡化系统混合膜设计[J]. 净水技术，2024，43（1）：132-139.
[11]	SONG J M，WANG C P，WANG S H，et al. Specific energy consumption analysis of reverse osmosis desalination system with energy recovery combination processes[J]. Industrial Water Treatment，2024，44（5）：212-217. 宋结民，汪程鹏，王生辉，等. 不同能量回收组合工艺下海水淡化系统比能耗分析[J]. 工业水处理，2024，44（5）：212-217.
[12]	HUANG Z. Application of electro-adsorption and R/O technology to reuse treatment of municipal sewage[J]. Large Scale Nitrogenous Fertilizer Industry，2012，35（4）：256-258. 黄政. 电吸附技术与反渗透技术在市政污水回用处理中的应用[J]. 大氮肥，2012，35（4）：256-258.
[13]	LIU T，SERRANO J，ELLIOTT J，et al. Exceptional capacitive deionization rate and capacity by block copolymer-based porous carbon fibers[J]. Science Advances，2020，6（16）：eaaz906.
[14]	CHEN Y，ZHANG Z，DENG W，et al. Mechanistic insight into the electrochemical absorption adsorption behaviour of Cd²⁺ and Na⁺ on MnO₂ in a deionization supercapacitor[J]. Desalination，2022，521：115384.
[15]	MA J，XIONG Y，DAI X，et al. Zinc spinel ferrite nanoparticles as a pseudocapacitive electrode with ultrahigh desalination capacity and long-term stability[J]. Environmental Science& Technology Letters，2020，7（2）：118-125.
[16]	FLEISCHMANN S，MITCHELL J B，WANG R，et al. Pseudocapacitance：From fundamental understanding to high power energy storage materials[J]. Chemical Reviews，2020，120（14）：6738-6782.
[17]	XING S Y，YU F，MA J. Research progress in design and application of transition metal electrode for capacitive deionization[J]. Chinese Journal of Applied Chemistry，2023，40（9）：1215-1232. 邢思阳，于飞，马杰. 电容去离子过渡金属基电极设计及应用研究进展[J]. 应用化学，2023，40（9）：1215-1232.
[18]	YIN B Y，HAO L，WEI T，et al. Revealing bulk reaction kinetics of battery-like electrode for pseudocapacitor with ultra-high rate performance[J]. Chemical Engineering Journal，2022，450（Part2）：138224.
[19]	ZHANG Y Y. Construction of novel electrodes for capacitive deionization and their desalination performance[D]. Lanzhou：Lanzhou University of Technology，2023. 张玉蓉. 电容去离子新型电极的构建及其脱盐性能研究[D]. 兰州：兰州理工大学，2023.
[20]	KUMAR S，ALDAQQA N M，ALHSEINAT E，et al. Electrode materials for desalination of water via capacitive deionization[J]. Angewandte Chemie International Edition，2023，62（35）：e202302180.
[21]	MENG F Y，DING Z B，XU X T，et al. Metal organic framework-derived nitrogen-doped porous carbon sustained Prussian blue analogues for efficient and fast hybrid capacitive deionization[J]. Separation and Purification Technology，2023，317：123899.
[22]	TANG Y C. Study on the efficiency and mechanism of reducing secondary effluent pollutants by the combined process of magnetic resin and ozone[D]. Harbin：Harbin Institute of Technology，2022. 唐英才. 磁性树脂和臭氧组合工艺削减二级出水污染物的效能及机理研究[D]. 哈尔滨：哈尔滨工业大学，2022.
[23]	YANG L. Study on the efficiency and mechanism of MIEX^{^®} enhanced coagulation to reduce pollutants in secondary effluent[D]. Harbin：Harbin Institute of Technology，2023. 杨亮. MIEX^{^®}强化混凝削减二级出水污染物效能及机理研究[D]. 哈尔滨：哈尔滨工业大学，2023.
[24]	WANG Z J，GONG H，ZHANG Y，et al. Nitrogen recovery from low-strength wastewater by combined membrane capacitive deionization（MCDI）and ion exchange（IE）process[J]. Chemical Engineering Journal，2017，316：1-6.
[25]	ZHANG M C，WANG C M，ZHU Z Y，et al. Preparation of reclaimed water using the magnetic resin adsorption coupled with capacitive deionization technology[J]. Environmental Science and Technology，2017，30（5）：10-13. 张满成，王长明，朱增银，等. 磁性树脂耦合电吸附的再生水制备工艺研究[J]. 环境科技，2017，30（5）：10-13.
[26]	ZUO K C，KIM J，JAIN A，et al. Novel composite electrodes for selective removal of sulfate by the capacitive deionization process[J]. Environmental Science& Technology，2018，52（16）：9486-9494.
[27]	KIM J，JAIN A，ZUO K C，et al. Removal of calcium ions from water by selective electrosorption using target-ion specific nanocomposite electrode[J]. Water Research，2019，160：445-453.
[28]	DUAN J H. Separation and purification of vanadium using capacitive deionization with resin/active carbon composite electrode[D]. Wuhan：Wuhan University of Technology，2018. 段继华. 基于树脂/活性炭复合电极的电容去离子技术分离富集钒研究[D]. 武汉：武汉理工大学，2018.
[29]	ZHOU J Y，ZHANG Y M，BAO S X，et al. Preparation and selective adsorption property of the ion-exchange resin/carbon composite electrode[J]. Industrial Safety and Environmental Protection，2016，42（12）：51-54. 周嘉郁，张一敏，包申旭. 离子交换树脂/活性炭复合电极制备及选择性吸附性能研究[J]. 工业安全与环保，2016，42（12）：51-54.
[30]	KIM Y，CHOI J. Selective removal of nitrate ion using a novel composite carbon electrode in capacitive deionization[J]. Water Research，2012，46（18）：6033-6039.
[31]	KIM D I，GONZALES R R，DORJI P，et al. Efficient recovery of nitrate from municipal wastewater via MCDI using anion-exchange polymer coated electrode embedded with nitrate selective resin[J]. Desalination，2020，484：114425.
[32]	YEO J H，CHOI J H. Enhancement of nitrate removal from a solution of mixed nitrate，chloride and sulfate ions using a nitrate-selective carbon electrode[J]. Desalination，2013，320：10-16.
[33]	GAN L，WU Y F，SONG H O，et al. Selective removal of nitrate ion using a novel activated carbon composite carbon electrode in capacitive deionization[J]. Separation and Purifcation Technology，2019，212：728-736.
[34]	MA W T. Porous carbon spheres derived from melamine and phenolic resin and their capacitance deionization performance[D]. Tianjin：Tianjin University of Technology，2021. 马文婷. 密胺和酚醛树脂衍生多孔碳球及其电容去离子性能[D]. 天津：天津理工大学，2021.
[35]	WU S，YAN P，YANG W，et al. ZnCl₂ enabled synthesis of activated carbons from ion-exchange resin for efficient removal of Cu²⁺ ions from water via capacitive deionization[J]. Chemosphere，2021，264：128557.
[36]	CHEN Y，YUE M，HUANG Z，et al. Electrospun carbon nanofiber networks from phenolic resin for capacitive deionization[J]. Chemical Engineering Journal，2014，252：30-37.
[37]	XIAO Y. Production of high purity water by membrane-free electrodeionization（MFEDI）[D]. Hangzhou：Zhejiang University，2013. 肖艳. 无膜电去离子（MFEDI）技术制备高纯水研究[D]. 杭州：浙江大学，2013.
[38]	LIAO S. Purification of primary RO effluent by membrane-free electrodeionization[D]. Hangzhou：Zhejiang University，2021. 廖帅. MFEDI技术用于处理一级反渗透出水研究[D]. 杭州：浙江大学，2021.
[39]	SOYSÜREN G，YETGIN A G，ARAR Ö，et al. Removal of manganese（II）from aqueous solution by ionic liquid impregnated polymeric sorbent and electrodeionization（EDI）techniques[J]. Process Safety and Environmental Protection，2022，158：189-198.
[40]	ZHAO C，ZHANG L，GE R，ET AL. Treatment of low-level Cu（II）wastewater and regeneration through a novel capacitive deionization-electrodeionization（CDI-EDI）technology[J]. Chemosphere，2019，217：763-772.
[41]	ZHANG A L. Study on the treatment of heavy metal wastewater containing salt by CDI-EDI combined process[D]. Baoding：Hebei University，2017. 张爱琳. CDI-EDI组合工艺处理含盐重金属废水的研究[D]. 保定：河北大学，2017.
[42]	LIANG P，YUAN L L，YANG X F，et al. Coupling ion-exchangers with inexpensive activated carbon fiber electrodes to enhance the performance of capacitive deionization cells for domestic wastewater desalination[J]. Water Research，2013，47（7），2523-2530.
[43]	TANG K X，ZHOU K. Water desalination by flow-electrode capacitive deionization in overlimiting current regimes[J]. Environmental Science& Technology，2020，54：5853-5863.
[44]	XU L Q，PENG S，WU K，et al. Precise manipulation of the charge percolation networks of flow-electrode capacitive deionization using a pulsed magnetic field[J]. Water Research，2022，222：118963.
[45]	XU L Q，TANG L，PENG S，et al. Magnetic array for efficient and stable Flow-electrode capacitive deionization[J]. Chemical Engineering Journal，2022，446（Part4）：137415.
[46]	MA J J，GAO T，HE Y F，et al. Enhanced charge efficiency and electrode separation utilizing magnetic carbon in flow electrode capacitive deionization[J]. ACS ES&T Engineering，2021，1（3）：340-347.
[47]	SRIMUK P，SU X，YOON J，et al. Charge-transfer materials for electrochemical water desalination，ion separation and the recovery of elements[J]. Nature Reviews Materials，2020，5（7）：517-538.
[48]	唐英才，巫寅虎，胡洪营，等. 一种基于磁性流动电极的电吸附装置及其应用：CN202410476042.6[P]. 2024-06-04. TANG Y C，WU Y H，HU H Y，et al. An electroadsorption device based on a magnetic flow electrode and its application：CN202410476042.6[P]. 2024-06-04.
[49]	WANG C Y，XUE S Y，XU Y B，et al. Novel electrocatalytic capacitive deionization with catalytic electrodes for selective phosphonate degradation：Performance and mechanism[J]. Water Research，2024，256：121614.
[50]	CHEN R，DENG X，WANG C，et al. A newly designed graphite-polyaniline composite current collector to enhance the performance of flow electrode capacitive deionization[J]. Chemical Engineering Journal，2022，435：134845.
[51]	BERGGREN M，MALLIARAS G G. How conducting polymer electrodes operate[J]. Science，2019，364（6437）：233-234.
[52]	LUO S，ELOUARZAKI K，XU Z J. Electrochemistry in magnetic fields[J]. Angewandte Chemie International Edition，2022，61（27）：e202203564.
[53]	ZHANG L，ZENG Z，WANG D，et al. Magnetic field-induced capacitance change in aqueous carbon-based supercapacitors[J]. Cell Reports Physical Science，2021，2（6）：100455.
[54]	BAI X，WANG J，HAO H，et al. Magnetic field-enhanced performance of superparamagnetic LiMn₂O₄-based composite slurry electrode for semisolid flow battery[J]. Small Methods，2023，7（9）：2300548.
[55]	ZHANG X，ZHOU H，ZHANG H. How does temperature affect the charge transfer process in flow electrode capacitive deionization？[J]. Environmental Science& Technology，2024，58（33）：14886-14894
[56]	HEO J，AHN H，WON J，et al. Electro-inductive effect：Electrodes as functional groups with tunable electronic properties[J]. Science，2020，370（6513）：214-219.
[57]	HAN Y，ZHAO J，GUO X，et al. Removal of methanol from water by capacitive deionization system combined with functional nanoporous graphene membrane[J]. Chemosphere，2023，311：137011.
[58]	DENG W，CHEN Y，WANG Z，et al. Regulation，quantification and application of the effect of functional groups on anion selectivity in capacitive deionization[J]. Water Research，2022，222：118927.
[59]	REN J，ZHU Z，QIU Y，et al. Magnetic field assisted adsorption of pollutants from an aqueous solution：A review[J]. Journal of Hazardous Materials，2021，408：124846.
[60]	LIU Z，LU T，CHEN Q. An sp-hybridized all-carboatomic ring，cyclo[18]carbon：Electronic structure，electronic spectrum，and optical nonlinearity[J]. Carbon，2020，165：461-467.
[61]	ZENG J，XIE W，GUO Y，et al. Magnetic field facilitated electrocatalytic degradation of tetracycline in wastewater by magnetic porous carbonized phthalonitrile resin[J]. Applied Catalysis B：Environmental，2024，340：123225.
[62]	WU Z F. Research on desalination efficiency of saline industrial wastewater based on magneto-electric coupled capacitive deionization system[D]. Baoding：Hebei University，2024. 吴泽丰. 基于磁电耦合电容去离子体系的含盐工业废水脱盐效能研究[D]. 保定：河北大学，2024.
[63]	WU Y，GAO S J，WANG T Y，et al. Research progress of electro-driven selective membrane separation technology[J]. Environmental Engineering，2021，39（7）：30-37. 吴悠，高舒嘉，王天玉，等. 电驱动选择性膜分离技术研究进展[J]. 环境工程，2021，39（7）：30-37.
[64]	JI M，BAO J G，ZHU X W，et al. Enhanced chromate（Ⅵ）removal characteristics and mechanism using graphene oxide immobilized nanoscale zero-valent iron coupled with a weak magnetic field（GO-nFe⁰/WMF）[J]. Environmental Science，2020，41（7）：3326-3336. 计盟，鲍建国，朱晓伟，等. 弱磁场强化氧化石墨烯负载纳米零价铁（GO-nFe⁰/WMF）对水中Cr（Ⅵ）的去除特性及机制[J]. 环境科学，2020，41（7）：3326-3336.
[65]	CHI J B，XING Y，CANG D Q，et al. Analysis on micro-behavior of electromagnetic induction in the technology of magnetic water treatment[J]. Environmental Engineering，2009，27（4）：20-24. 迟金宝，邢奕，苍大强，等. 磁场水处理技术中微观电磁感应行为分析[J]. 环境工程，2009，27（4）：20-24.
[66]	MA F F，KANG H B，ZHAO H，et al. Study adsorption mechanism of phosphate on layered double hydroxide loaded biochar and DFT[J]. Environmental Science，2025，46（7）：4360-4369. 马锋锋，康宏兵，赵浩，等. 层状双氢氧化物负载生物炭对磷的吸附机制及DFT[J]. 环境科学，2025，46（7）：4360-4369.
[67]	SU Z X，LIU S H，GUAN Y F，et al. Cadmium and arsenic interactions during co-adsorption onto goethite[J]. Environmental Science，2023，44（7）：3970-3977. 苏子贤，刘赛红，管玉峰，等. 镉砷在针铁矿界面共吸附的相互作用机制[J]. 环境科学，2023，44（7）：3970-3977.
[68]	SHI Z，ZHANG C，YANG L F，et al. Study on pollution characteristics of capacitive deionizing electrode[J]. Environmental Engineering，2018，36（12）：113-118. 施周，张超，杨灵芳，等. 电容去离子电极的污染特性研究[J]. 环境工程，2018，36（12）：113-118.
[69]	HUANG J X. Advanced thallium removal through capacitive deionization with titanium-carbon electrodes[D]. Guangzhou：Guangzhou University，2024. 黄涓溪. 基于钛炭复合电极的电容去离子深度除铊研究[D]. 广州：广州大学，2024.
[70]	CAO S，CHEN T，ZHENG S，et al. High-performance capacitive deionization and killing microorganism in surface-water by ZIF-9 derived carbon composites[J]. Small Methods，2021，5（12）：2101070.
[71]	XIAO X B. Comparison of effects of antibiotics removed by typical hospital wastewater treatment processes in Haikou and research on antibiotics adsorption simulation experiment[D]. Haikou：Hainan University，2014. 肖湘波. 海口市医疗废水典型处理工艺单元对抗生素的去除效果比较和抗生素吸附模拟实验研究[D]. 海口：海南大学，2014.
[72]	ZHAO X，YANG J，PENG J，et al. An extended S-heterocyclic organic compound with enhanced redox active sites for efficient and stable ammonium ion removal via capacitive deionization[J]. Desalination，2024，592：118120.
[73]	YANG W，WANG F，QUE Q，et al. Urban stormwater discharge contributes more micropollutants to surface water in humid regions of China：Comparison with treated wastewater[J]. Water Research，2025，268：122712.
[74]	ZHOU X C，ZHANG C L，DING G Y，et al. Research progress on occurrence and removal technology of emerging contaminants in urban stormwater runoff[J]. Water Purification Technology，2024，43（10）：40-47. 周秀彩，张朝利，丁国莹，等. 城市雨水径流中新污染物的赋存与去除技术研究进展[J]. 净水技术，2024，43（10）：40-47.