Ru基催化剂催化氧化含氯挥发性有机物研究进展

朱新宝; 杨雯皓; 赵东越; 宋海涛

doi:10.13205/j.hjgc.202608018

Ru基催化剂催化氧化含氯挥发性有机物研究进展

doi: 10.13205/j.hjgc.202608018

中石化石油化工科学研究院有限公司, 北京 100083

基金项目:

国家自然科学基金项目（22306210）

详细信息

作者简介:
朱新宝（2000—），男，硕士，主要研究方向为大气污染物控制。zhuxinbao.ripp@sinopec.com

通讯作者:
宋海涛（1978—），男，研究员，主要研究方向为石油炼制及工业烟气污染物治理催化剂研发与应用。songht.ripp@sinopec.com

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出版历程
- 收稿日期: 2025-03-13

Research progress on Ru-based catalysts for catalytic oxidation of chlorinated volatile organic compounds

Sinopec Research Institute of Petroleum Processing Co. Ltd., Beijing 100083, China

摘要

摘要: 含氯挥发性有机物（chlorinated volatile organic compounds，CVOCs）具有易挥发、难降解、毒性强的特点，严重危胁大气环境和人类健康。催化氧化法是目前CVOCs减排领域高效、安全且经济的主流方法之一，其关键在于设计、开发高性能催化剂。在CVOCs催化氧化中，Cl物种对催化剂的毒化作用严重限制了催化剂性能，而Ru基催化剂因其具有优异的CVOCs催化氧化活性和抗氯性能，近年来被广泛研究。综述了Ru基催化剂在CVOCs催化氧化领域的最新研究进展，通过系统文献分析，阐明了Ru基催化剂催化氧化CVOCs的机理；并从活性组分设计与调控、载体设计与调控、表面修饰与改性的角度，概述Ru基催化剂的设计与结构调控策略；最后总结了Ru基催化剂的新型制备方法和反应组分对催化性能的影响，进一步展望了该领域未来的发展方向，以期为后续设计、开发适用于复杂工况的高性能Ru基催化剂提供借鉴。
- Ru基催化剂 /
- 含氯挥发性有机物 /
- 催化氧化 /
- 结构调控 /
- 反应机理
Abstract: Chlorinated volatile organic compounds （CVOCs） are volatile， difficult to degrade， and highly toxic， posing serious threats to the atmospheric environment and human health. Catalytic oxidation is currently one of the mainstream methods for CVOCs abatement， owing to its high efficiency， safety， and economic feasibility， and its key aspect lies in the design and development of high-performance catalysts. In the catalytic oxidation of CVOCs， the poisoning effect of chlorine species on catalysts severely restricts catalytic performance. Ru-based catalysts， which exhibit excellent catalytic oxidation activity toward CVOCs and favorable chlorine-resistant performance， have been widely studied in recent years. This paper reviews the latest research progress on Ru-based catalysts for the catalytic oxidation of CVOCs. The mechanism of catalytic oxidation of CVOCs by Ru-based catalysts is elucidated through a systematic analysis of the relevant literature. Furthermore， the strategies for the design and structural regulation of Ru-based catalysts are outlined from the perspectives of active components， supports， and surface modification. Finally， novel preparation methods for Ru-based catalysts and the influence of reaction components on catalytic performance are summarized. Future research directions in this field are also prospected， aiming to provide a reference for the subsequent design and development of high-performance Ru-based catalysts suitable for complex operating conditions.
- Ru-based catalysts /
- chlorinated volatile organic compounds /
- catalytic oxidation /
- structural regulation /
- reaction mechanism

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参考文献(92)

[1]	CAO X L，SPARLING M，DABEKA R. Occurrence of 13 volatile organic compounds in foods from the Canadian total diet study[J]. Food Additives& Contaminants：Part A，2016，33（2）：373-382.
[2]	JIA H Q，XING Y，ZHANG L G，et al. Progress of catalytic oxidation of typical chlorinated volatile organic compounds（CVOCs）：a review[J]. Science of the Total Environment，2023，865：161063.
[3]	LUO H Y，ZHANG T T. Migration and transformation of chlorine species for transition metal oxide in catalytic combustion of chlorinated volatile organic compounds[J]. Chemical Industry and Engineering Progress，2018，37（S1）：102-107. 罗邯予，张婷婷. 含氯废气催化燃烧过程中氯物种的迁移与转化[J]. 化工进展，2018，37（增刊1）：102-107.
[4]	YANG Q，XU H，ZHAO Y R，et al. Research progress of noble metal（Pt，Pd，and Ru）-based catalysts for catalytic degradation of chlorine-containing volatile organic compounds[J]. Energy Environmental Protection，2023，37（3）：75-87. 杨沁，徐晗，赵亚若，等. 贵金属（Pt、Pd和Ru）基催化剂在含氯挥发性有机物催化降解中的研究进展[J]. 能源环境保护，2023，37（3）：75-87.
[5]	RAN L. Low-temperature catalytic combustion of chlorinated volatile organic compounds over ruthenium-based catalysts[D]. Shanghai：East China University of Science and Technology，2013. 冉乐. 钌基催化剂上含氯挥发性有机化合物的低温催化燃烧[D]. 上海：华东理工大学，2013.
[6]	LÜ X L，JIANG M Z，CHEN J，et al. Unveiling the lead resistance mechanism and interface regulation strategy of Ru-based catalyst during chlorinated VOCs oxidation[J]. Applied Catalysis B：Environmental，2022，315：121592.
[7]	ZHANG X，DAI L Y，LIU Y X，et al. 3DOM CeO₂-supported RuᵧM（M=Au，Pd，Pt）alloy nanoparticles with improved catalytic activity and chlorine-tolerance in trichloroethylene oxidation[J]. Catalysis Science& Technology，2020，10（11）：3755-3770.
[8]	CAO S，FEI X Q，WEN Y X，et al. Bimodal mesoporous TiO₂ supported Pt，Pd and Ru catalysts and their catalytic performance and deactivation mechanism for catalytic combustion of Dichloromethane（CH₂Cl₂）[J]. Applied Catalysis A：General，2018，550：20-27.
[9]	HUANG Y，TIAN M J，JIANG Z Y，et al. Inserting Cr₂O₃dramatically promotes RuO₂/TiO₂ catalyst for low-temperature 1，2-dichloroethane deep destruction：catalytic performance and synergy mechanism[J]. Applied Catalysis B：Environmental，2022，304：121002.
[10]	PEI J J，PENG B，LIN H，et al. Single-Atom Ru on Al₂O₃ for highly active and selective 1，2-dichloroethane catalytic degradation[J]. ACS Applied Materials& Interfaces，2021，13（45）：53683-53690.
[11]	HUO H M，GUO J，ZANG W L，et al. Research progress in the process mechanism of catalytic oxidation of chlorine-containing volatile organic compounds and the deactivation and regeneration of catalysts[J]. Environmental Pollution& Control，2023，45（12）：1710-1715. 霍浩淼，国洁，臧文丽，等. 催化氧化含氯挥发性有机物过程机制及催化剂失活和再生的研究进展[J]. 环境污染与防治，2023，45（12）：1710-1715.
[12]	YANG W H，ZHAO D Y，SONG H T，et al. Design and structure regulation of VOCs catalytic oxidation catalysts[J]. Progress in Chemistry，2024，36（1）：27-47. 杨雯皓，赵东越，宋海涛，等. VOCs 氧化催化剂设计与结构调控[J]. 化学进展，2024，36（1）：27-47.
[13]	MENG X Y，WANG Q R，WANG W，et al. Synergistic mechanism of hetero-interfacial oxygen vacancies on catalytic oxidation of 1，2-dichloroethane over Ru-modified monolayer-dispersed WO_x/CeO₂ catalysts：differences in distribution of active sites[J]. Applied Catalysis B：Environment and Energy，2024，344：123664.
[14]	ZHANG X，DAI L Y，LIU Y X，et al. Effect of support nature on catalytic activity of the bimetallic RuCo nanoparticles for the oxidative removal of 1，2-dichloroethane[J]. Applied Catalysis B：Environmental，2021，285：119804.
[15]	LI L，ZHANG J J，XU H，et al. A systematical comparison of catalytic behavior of NM/γ-Al₂O₃（NM = Ru，Rh，Pt，Pd，Au，Ir）on 1，2-dichloroethane oxidation：distributions of by-products and reaction mechanism[J]. Applied Sciences，2023，13（1）：36.
[16]	YU X H，DAI L Y，PENG Y，et al. High selectivity to HCl for the catalytic removal of 1，2-dichloroethane over RuP/3DOM WOₓ：insights into the effects of P-doping and H₂O introduction[J]. Environmental Science& Technology，2021，55（21）：14906-14916.
[17]	PENG B，HU Z，ZHANG K F，et al. Synergies of redox ability and acidity over RuMn/ZSM-5 for catalytic elimination of 1，2-dichloroethane[J]. Separation and Purification Technology，2024，333：125973.
[18]	LIANG W J，ZHU Y X，REN S D，et al. Enhanced catalytic elimination of chlorobenzene over Ru/TiO₂ modified with SnO₂—synergistic performance of oxidation and acidity[J]. Chemical Physics，2023，566：111787.
[19]	DUAN X X，ZHAO T，NIU B，et al. Simultaneously constructing active sites and regulating Mn-O strength of Ru-substituted perovskite for efficient oxidation and hydrolysis oxidation of chlorobenzene[J]. Advanced Science，2023，10（3）：2205054.
[20]	LIANG W J，ZHU Y X，REN S D，et al. Catalytic combustion of chlorobenzene at low temperature over Ru-Ce/TiO₂：high activity and high selectivity[J]. Applied Catalysis A：General，2021，623：118257.
[21]	LIU X L，CHEN L，ZHU T Y，et al. Catalytic oxidation of chlorobenzene over noble metals（Pd，Pt，Ru，Rh）and the distributions of polychlorinated by-products[J]. Journal of Hazardous Materials，2019，363：90-98.
[22]	PENG R S，LI S J，SUN X B，et al. Size effect of Pt nanoparticles on the catalytic oxidation of toluene over Pt/CeO₂ catalysts[J]. Applied Catalysis B：Environmental，2018，220：462-470.
[23]	CHEN C Y，CHEN F，ZHANG L，et al. Importance of platinum particle size for complete oxidation of toluene over Pt/ZSM-5 catalysts[J]. Chemical Communications，2015，51（27）：5936-5938.
[24]	YANG D Y，FU S Y，HUANG S S，et al. The preparation of hierarchical Pt/ZSM-5 catalysts and their performance for toluene catalytic combustion[J]. Microporous and Mesoporous Materials，2020，296：109802.
[25]	DELGADO J A，CLAVER C，CASTILLÓN S，et al. Fischer-Tropsch synthesis catalysed by small TiO₂ supported cobalt nanoparticles prepared by sodium borohydride reduction[J]. Applied Catalysis A：General，2016，513：39-46.
[26]	GAO G Q，LIAO Y，LI W W，et al. Active surface RuO_x species originating from size-driving self-dispersion process for toluene catalytic combustion[J]. Chemical Engineering Journal，2022，441：136127.
[27]	YANG Y，ZHENG Z，KONG M Y，et al. The study on the active site regulated RuO_x/Sn_0.2Ti_0.8O₂ catalysts with different Ru precursors for the catalytic oxidation of dichloromethane[J]. Catalysts，2021，11（11）：1306.
[28]	CHEN X，JIA Z L，WANG M X，et al. Correlation between chlorobenzene oxidation and active oxygen species induced by the dispersity of RuO_x[J]. China Environmental Science，2025，45（4）：1820-1832. 陈曦，贾子良，王梦雪，等. RuO_x分散性导致的活性氧异化与氯苯氧化相关性[J]. 中国环境科学，2025，45（4）：1820-1832.
[29]	BU J，LIU J L，CHEN X Y，et al. Ru/SBA-15 catalysts for partial hydrogenation of benzene to cyclohexene：tuning the Ru crystallite size by Ba[J]. Catalysis Communications，2008，9（15）：2612-2615.
[30]	CARBALLO J M G，YANG J，HOLMEN A，et al. Catalytic effects of ruthenium particle size on the fischer-tropsch synthesis[J]. Journal of Catalysis，2011，284（1）：102-108.
[31]	FERNÁNDEZ C，PEZZOTTA C，GAIGNEAUX E M，et al. Disclosing the synergistic mechanism in the catalytic activity of different-sized Ru nanoparticles for ammonia synthesis at mild reaction conditions[J]. Catalysis Today，2015，251：88-95.
[32]	LI L L，JIANG Y F，ZHANG T H，et al. Size sensitivity of supported Ru catalysts for ammonia synthesis：from nanoparticles to subnanometric clusters and atomic clusters[J]. Chem，2022，8（3）：749-768.
[33]	GUO Z R，LI L X，GUO Y，et al. Size effect of Ru particles on the self-reforming-driven hydrogenolysis of a lignin model compound[J]. Catalysis Science& Technology，2022，12（16）：5143-5151.
[34]	ZHENG Y F，HAN R，WANG Y C，et al. High-temperature shock-resistant zeolite-confined Ru subnanometric species boosts highly catalytic oxidation of dichloromethane[J]. Applied Catalysis B：Environment and Energy，2024，355：124195.
[35]	YANG X F，WANG A Q，QIAO B T，et al. Single-atom catalysts：a new frontier in heterogeneous catalysis[J]. Accounts of Chemical Research，2013，46（8）：1740-1748.
[36]	WANG Y，LIU Z，WEI Y，et al. Significant inhibition of secondary pollution in the catalytic oxidation of chloroaromatics over a bifunctional Ru₁/CeO₂ single-atom catalyst[J]. Journal of Materials Chemistry A，2024，12（5）：2949-2958.
[37]	WU L K，DENG J G，LIU Y X，et al. Enhanced removal efficiency of multicomponent VOCs over the Sn-doped Silicalite-1-supported Ru single-atom catalysts by constructing tightly coupled redox and acidic sites[J]. Applied Catalysis B：Environment and Energy，2024，351：123910.
[38]	GAO R Y，TIAN X R，DING X L，et al. Regulating catalytic stability of PtSnM/CeO₂（M=Mn，W，Nb）catalysts via the closely coupled multi-active sites to promote multicomponent VOCs oxidation[J]. Chemical Engineering Journal，2023，471：144456.
[39]	GOULAS K A，SREEKUMAR S，SONG Y，et al. Synergistic effects in bimetallic palladium-copper catalysts improve selectivity in oxygenate coupling reactions[J]. Journal of the American Chemical Society，2016，138（21）：6805-6812.
[40]	KIM D，RESASCO J，YU Y，et al. Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold-copper bimetallic nanoparticles[J]. Nature Communications，2014，5（1）：4948.
[41]	SU Y T，QIAN H H，WU Z B，et al. Ceria-supported bimetallic RuPt alloy for enhanced chlorine-tolerance catalysis[J]. ACS ES&T Engineering，2025.
[42]	WANG Y，CHEN Y，ZHANG L，et al. Total catalytic oxidation of chlorinated aromatics over bimetallic Pt-Ru supported on hierarchical HZSM-5 zeolite[J]. Microporous and Mesoporous Materials，2020，308：110538.
[43]	ZHENG Y F，HAN R，YANG Z X，et al. Engineering subnanometric electronic interaction between Ru and Mn in zeolite boosts catalytic oxidation of dichloromethane[J]. Environmental Science& Technology，2025，59（4）：2276-2284.
[44]	LIU Y X，DONG T T，DENG J G，et al. Ternary metal catalyst with excellent chlorine resistance and high-efficiency catalytic oxidation performance for mixed VOCs：China，CN114345335B[P]. 2022-04-05. 刘雨溪，董甜甜，邓积光，等. 一种具有优异抗氯性及高效催化氧化混合VOCs的三元金属催化剂：CN114345335B[P]. 2022-04-05.
[45]	YOON S，JO J，JEON B，et al. Revealing charge transfer at the interface of spinel oxide and ceria during CO oxidation[J]. ACS Catalysis，2021，11（3）：1516-1527.
[46]	LONG Y P，MENG Q J，CHEN M L，et al. Selective Ru adsorption on SnO₂/CeO₂ mixed oxides for efficient destruction of multicomponent volatile organic compounds：from laboratory to practical possibility[J]. Environmental Science& Technology，2022，56（13）：9762-9772.
[47]	SADAKANE M，HORIUCHI T，KATO N，et al. Facile preparation of three-dimensionally ordered macroporous alumina，iron oxide，chromium oxide，manganese oxide，and their mixed-metal oxides with high porosity[J]. Chemistry of Materials，2007，19（23）：5779-5785.
[48]	YU X H，DAI L Y，DENG J G，et al. Catalytic performance and intermediates identification of trichloroethylene deep oxidation over Ru/3DOM SnO₂ catalysts[J]. Journal of Catalysis，2021，400：310-324.
[49]	YANG S，ZHAO H，DONG F，et al. Highly efficient catalytic combustion of o-dichlorobenzene over lattice-distorted Ru/OMS-2：the rapidly replenishing effect of surface adsorbed oxygen on lattice oxygen[J]. Molecular Catalysis，2019，470：127-137.
[50]	SUN T，ZHOU X Y，LI X Y，et al. Chlorine poisoning-resistant atomically dispersed Ru for low-temperature o-dichlorobenzene oxidation[J]. Applied Catalysis B：Environment and Energy，2025，366：125035.
[51]	HUANG H，DAI Q G，WANG X Y. Morphology effect of Ru/CeO₂ catalysts for the catalytic combustion of chlorobenzene[J]. Applied Catalysis B：Environmental，2014，158/159：96-105.
[52]	XIE B C，WANG Z P，ZHANG X，et al. Morphology effect of cerium dioxide on the catalytic performance of Ru/CeO₂ catalyst for the oxidation of different CVOCs[J]. Separation and Purification Technology，2024，345：127428.
[53]	POLO-GARZON F，BAO Z H，ZHANG X Y，et al. Surface reconstructions of metal oxides and the consequences on catalytic chemistry[J]. ACS Catalysis，2019，9（6）：5692-5707.
[54]	ZHANG H，WANG W M，ZHAO H X，et al. Facet-dependent interfacial charge transfer in Fe（Ⅲ）-grafted TiO₂ nanostructures activated by visible light[J]. ACS Catalysis，2018，8（10）：9399-9407.
[55]	YAN L，DU J J，JING C Y. How TiO₂ facets determine arsenic adsorption and photooxidation：spectroscopic and DFT studies[J]. Catalysis Science& Technology，2016，6（7）：2419-2426.
[56]	LIU G，YANG H G，WANG X M，et al. Visible light responsive nitrogen doped anatase TiO₂ sheets with dominant｛001｝ facets derived from TiN[J]. Journal of the American Chemical Society，2009，131（36）：12868-12869.
[57]	SUN B H，LI Q Q，SU G J，et al. Insights into chlorobenzene catalytic oxidation over noble metal loading｛001｝-TiO₂：the role of NaBH₄ and subnanometer Ru undergoing stable Ru⁰⇆Ru⁴⁺ circulation[J]. Environmental Science& Technology，2022，56（22）：16292-16302.
[58]	LI J，QIAN L，YAN Y F，et al. Catalytic oxidation of dichloromethane co-promoted by RuO₂ and V₂O₅ supported on nano-CeO₂[J]. Molecular Catalysis，2023，550：113565.
[59]	HAO W C，WANG Z W，XIE S H，et al. Catalytic performance of Nb₂O₅ modified Ru/CeO₂ for dichloromethane oxidation[J]. Progress in Natural Science：Materials International，2023，33（4）：486-494.
[60]	WANG Y，WANG P，LU X F，et al. Construction of mesoporous Ru@ZSM-5 catalyst for dichloromethane degradation：synergy between acidic sites and redox centres[J]. Fuel，2023，346：128337.
[61]	LI W Q，HU D，YIN K，et al. Hierarchical Ru-Ce/H-ZSM-5 catalysts for the catalytic oxidation of chlorobenzene：structure-activity relationship and chlorine poisoning resistance[J]. Surfaces and Interfaces，2022，34：102320.
[62]	XIE Y J，WANG S M，JIN P，et al. Hierarchical ZSM-5 zeolite supported RuO_x catalysts via organic mesoporous porogens for catalytic oxidation of vinyl chloride[J]. Surfaces and Interfaces，2024，45：103885.
[63]	WANG C，TIAN C C，GUO Y L，et al. Ruthenium oxides supported on heterostructured CoPO-MCF materials for catalytic oxidation of vinyl chloride emissions[J]. Journal of Hazardous Materials，2018，342：290-296.
[64]	YING Q J，WANG X Q，LIU Y，et al. Rational design of a novel core-shell Cu-ZSM-5@Ru/S-1 tandem catalyst for the catalytic combustion of dichloromethane[J]. ACS ES&T Engineering，2023，3（7）：1013-1021.
[65]	FEI Z Y，WANG Z C，LI D F，et al. Silica-confined Ru highly dispersed on ZrO₂ with enhanced activity and thermal stability in dichloroethane combustion[J]. Nanoscale，2021，13（24）：10765-10770.
[66]	LIU B，LI C M，ZHANG G Q，et al. Oxygen vacancy promoting dimethyl carbonate synthesis from CO₂ and methanol over Zr-doped CeO₂ nanorods[J]. ACS Catalysis，2018，8（11）：10446-10456.
[67]	GUTIÉRREZ-ORTIZ J，DE RIVAS B，LÓPEZ-FONSECA R，et al. Catalytic purification of waste gases containing VOC mixtures with Ce/Zr solid solutions[J]. Applied Catalysis B：Environmental，2006，65（3）：191-200.
[68]	XIE B C，WEI Z J，DING M，et al. Enhanced Ru-O-Ce interaction by solid solution structure of Ru-Ce_xZr_1-xO₂ catalysts for efficient catalytic combustion of vinyl chloride[J]. Applied Catalysis B：Environment and Energy，2024，350：123926.
[69]	ZHAO J，XI W J，TU C，et al. Catalytic oxidation of chlorinated VOCs over Ru/Ti_xSn_1-x catalysts[J]. Applied Catalysis B：Environmental，2020，263：118237.
[70]	WANG Y，DU C，LIU Z，et al. Highly active and durable chlorobenzene oxidation catalyst via porous atomic layer coating of Ru on Pt/Al₂O₃[J]. Applied Catalysis B：Environmental，2023，330：122648.
[71]	YING Q J，LIU Y，WANG N Y，et al. The superior performance of dichloromethane oxidation over Ru doped sulfated TiO₂catalysts：synergistic effects of Ru dispersion and acidity[J]. Applied Surface Science，2020，515：145971.
[72]	XIA H Q，LIU L L，NIU Q，et al. Exceptionally stable CePO₄ and RuO₂ contributing to catalytic oxidation of 1，2-dichloroethane on Co₃O₄ catalysts：complete inhibition of chlorinated byproducts[J]. Fuel，2023，351：129005.
[73]	DAI Q G，WU J Y，DENG W，et al. Comparative studies of P/CeO₂ and Ru/CeO₂ catalysts for catalytic combustion of dichloromethane：from effects of H₂O to distribution of chlorinated by-products[J]. Applied Catalysis B：Environmental，2019，249：9-18.
[74]	ZHANG N N，GUO Y L，GUO Y，et al. Synchronously constructing the optimal redox-acidity of sulfate and RuO_x Co-modified CeO₂ for catalytic combustion of chlorinated VOCs[J]. Chemical Engineering Journal，2023，454：140391.
[75]	DAI Q G，SHEN K，DENG W，et al. HCl-tolerant H_xPO₄/RuO_x-CeO₂ catalysts for extremely efficient catalytic elimination of chlorinated VOCs[J]. Environmental Science& Technology，2021，55（6）：4007-4016.
[76]	SU Y T，CAO K X，LU Y H，et al. Surface-phosphorylated ceria for chlorine-tolerance catalysis[J]. Environmental Science& Technology，2024，58（2）：1369-1377.
[77]	CHEN J W，MENG Q J，BI F，et al. Characteristics of catalytic destruction of dichloromethane and ethyl acetate mixture over H_xPO₄-RuO_x/CeO₂ catalyst[J]. Journal of Environmental Sciences，2025，148：336-349.
[78]	GU Z Y，YAN Y，LUO X Q，et al. Pilot study of novel ruthenium-cerium-based composite catalyst for efficient catalytic degradation of chlorinated volatile organic compounds[J]. Environmental Pollution& Control，2025，47（4）：114-119. 顾震宇，颜洋，罗学清，等. 新型钌铈基复合催化剂高效催化降解含氯挥发性有机物的中试研究[J]. 环境污染与防治，2025，47（4）：114-119.
[79]	CAO K X，MENG Q J，LUO X Q，et al. Synergistic roles of Ru，CeO₂，and HZSM-5 in a ternary-active center catalyst for catalytic destruction of dichloromethane[J]. Separation and Purification Technology，2024，339：126446.
[80]	WANG C，LIU N，ZHANG C H，et al. Ruthenium/cobalt binary oxides supported on hollow alumina microspheres as highly efficient catalyst for vinyl chloride oxidation[J]. Applied Surface Science，2019，497：143776.
[81]	CAI P P，LI H T，HAN Y Q，et al. The efficient and stable catalytic combustion of chlorobenzene utilizing a cordierite honeycomb ceramic RuCeO₂ catalyst：transitioning from laboratory innovation to practical application[J]. Fuel，2024，375：132605.
[82]	DENG W，JIA Z Y，GAO B，et al. Effect of preparation method on the performance of porous RuO _x/Co₃O₄ catalysts for 1，2-dichloroethane oxidation[J]. Applied Catalysis A：General，2021，624：118300.
[83]	ZHU X B，HE X Y，GUO L H，et al. Hydrophobic modification of ZSM-5-encapsulated uniform Pt nanoparticles for catalytic oxidation of volatile organic compounds[J]. ACS Applied Nano Materials，2022，5（3）：3374-3385.
[84]	SHEN K，DING Q，FAN H，et al. Biotemplate preparation of Ru/CeO₂ catalysts for the catalytic combustion of vinyl chloride[J]. Catalysis Communications，2023，184：106801.
[85]	ZHOU F Y，XIN Q，FU Y J，et al. Efficient catalytic oxidation of chlorinated volatile organic compounds over RuO₂-WO_x/SnO₂ catalysts：insight into the Cl poisoning mechanism of acid sites[J]. Chemical Engineering Journal，2023，464：142471.
[86]	WANG S M，ZHANG H L，WANG M J，et al. Micro-meso hierarchical ZSM-5 zeolite supported RuO_x nanoparticles for activity enhancement of catalytic vinyl chloride oxidation[J]. Applied Surface Science，2022，606：154906.
[87]	PITKÄHO S，MATEJOVA L，OJALA S，et al. Oxidation of perchloroethylene-activity and selectivity of Pt，Pd，Rh，and V₂O₅ catalysts supported on Al₂O₃，Al₂O₃-TiO₂ and Al₂O₃-CeO₂[J]. Applied Catalysis B：Environmental，2012，113-114：150-159.
[88]	DAI Q G，WANG X Y，LU G Z. Low-temperature catalytic combustion of trichloroethylene over cerium oxide and catalyst deactivation[J]. Applied Catalysis B：Environmental，2008，81（3）：192-202.
[89]	BERTINCHAMPS F，ATTIANESE A，MESTDAGH M M，et al. Catalysts for chlorinated VOCs abatement：multiple effects of water on the activity of VOx based catalysts for the combustion of chlorobenzene[J]. Catalysis Today，2006，112（1）：165-168.
[90]	ZHENG Z，YANG Y，LI H，et al. Effect of multi-pollutant on the catalytic oxidation of dichloromethane over RuO₂-WO₃/Sn_0.2Ti_0.8O₂ catalyst[J]. Fuel，2020，278：118207.
[91]	YU X H，DENG J G，LIU Y X，et al. Enhanced water resistance and catalytic performance of Ru/TiO₂ by regulating Brønsted acid and oxygen vacancy for the oxidative removal of 1，2-dichloroethane and toluene[J]. Environmental Science& Technology，2022，56（16）：11739-11749.
[92]	BAO P F，ZHOU X N，HAN W L，et al. Research progress of VOCs catalytic combustion monolithic catalyst and coating materials[J]. Journal of Molecular Catalysis（Chinese& English），2024，38（3）：254-262. 包鹏飞，周小纳，韩维亮，等. VOCs 催化燃烧整体式催化剂及涂层材料研究进展[J]. 分子催化（中英文），2024，38（3）：254-262.