Development of an online CO2 monitoring system for flue gas emission sources
-
摘要: 现行烟气污染源中二氧化碳浓度的监测高度依赖人工统计,存在误差大,实时性差等问题。针对以上问题,提出了一种基于双通道红外差分法的CO2监测方法,并研发了一套CO2浓度在线监测系统,基于Zemax光路仿真设计并制造了10 cm长直射型圆形气室,研发了基于Cortex-M3核微控制器与FreeRTOS实时操作系统的信号检测软硬件系统,实现了对烟气污染源中CO2浓度的在线监测。实验结果表明,在体积分数0%~20%的量程范围内,示值误差达到0.78%F.S.,24 h零点和量程漂移分别为-0.15%和-0.9%,系统响应时间低至27 s。该监测系统具有高精准度、强稳定性和快反应速度,可为烟气污染源在线监测提供可靠的数据支持。Abstract: Current methods for detecting CO2 concentration in flue gas pollution sources rely heavily on manual statistics, which leads to significant errors and poor real-time performance. To address these issues, this paper proposed a CO2 monitoring method based on dual-channel infrared differential spectroscopy, and developed an online CO2 concentration monitoring system. A 10-cm-long direct-type circular gas cell was designed and fabricated, guided by Zemax optical path simulation. A signal detection hardware and software system was developed, featuring a Cortex-M3 core microcontroller and the FreeRTOS real-time operating system, enabling online monitoring of CO2 concentrations in flue gas pollution sources. Experimental results demonstrated that within the volume fraction range of 0% to 20%, the indicated value error reached 0.78% of full scale. The 24-hour zero drift and span drift were -0.15% and -0.9%, respectively, and the system response time was as low as 27 seconds. This monitoring system offers high accuracy, strong stability, and fast response, providing reliable data support for online monitoring of flue gas pollution sources.
-
[1] WANG S,ZHOU B,QU J B,et al. Air pollution impact of thermal power industry in Shandong province under carbon peak and carbon neutrality scenario[J]. China Environmental Science,2024,44(11):5990-5998. 王圣,周斌,屈加豹,等. 双碳情景下山东省火电行业大气污染影响[J]. 中国环境科学,2024,44(11):5990-5998. [2] GE J C,HUANG J,LAI Y N,et al. Analysis of standard specifications for calculating carbon emission factors for global electric power grids[J]. Global Energy Interconnection,2024,7(6):662-674. 葛佳程,黄杰,赖业宁,等. 国内外电网碳排放因子计算标准规范分析[J]. 全球能源互联网,2024,7(6):662-674. [3] DAI X,PANG Y F,ZHU P F,et al. Research and application of dilution method CO2 online monitoring systems in thermal power enterprises[J]. Chinese Metrology,2024(7):105-109. 戴旭,庞祎帆,朱鹏飞,等. 火电企业关于稀释法CO2在线监测系统的研发应用[J]. 中国计量,2024(7):105-109. [4] QIU D Z,CHEN C,GUO L,et al. Characteristics of greenhouse gas emissions from municipal wastewater treatment plants in major urban groups of China based on emission factor method[J]. Environmental Engineering,2022,40(6):116-122. 邱德志,陈纯,郭丽,等. 基于排放因子法的中国主要城市群城镇污水厂温室气体排放特征[J]. 环境工程,2022,40(6):116-122. [5] ZHANG Y N,LIU C,ZHANG L,et al. Research on infrared CO2 gas sensor based on NDIR technology[J]. Instrument Technique and Sensor,2023(9):23-28. 张雅楠,刘灿,张磊,等. 基于NDIR技术的红外CO2气体传感器研究[J]. 仪表技术与传感器,2023(9):23-28. [6] SUN Q F,LIU T Y,YU X N,et al. Non-interference NDIR detection method for mixed gases based on differential elimination[J]. Sensors and Actuators B:Chemical,2023,390:133901. [7] SUN Q F,LIU T Y,HUANG M Z. High accuracy wide range CO2 detection method based on difference optical path NDIR[J]. Sensors and Actuators A:Physical,2023,363:114722. [8] ZHOU L,PANG X B,WU Z T. Development of a portable high precision carbon dioxide detector and elimination of humidity interference[J]. Environmental Engineering,2023,41(10):37-44. 周磊,庞小兵,吴振涛. 便携式高精度二氧化碳检测仪的研制及湿度干扰消除的研究[J]. 环境工程,2023,41(10):37-44. [9] ZHANG Y,CHEN F,LENG J X,et al. Carbon monoxide monitoring system based on gas filtering correlation[J]. Transducer and Microsystem Technologies,2018(10):116-119,124. 张宇,陈帆,冷健雄,等. 基于气体滤波相关的一氧化碳监测系统[J]. 传感器与微系统,2018(10):116-119. [10] FAISAL R. Intrusion steering by probing CO2 transient density changes using NDIR sensing array[J]. Sensors and Actuators A:Physical,2021,330:112863. [11] WANG F,FANG H M,ZENG L B. Drift correction method of gas sensor based on polynomial regression model[J]. Transducer and Microsystem Technologies,2018,37(11):28-30. 王飞,房汉鸣,曾丽蓓. 基于多项式回归模型的气体传感器漂移矫正方法[J]. 传感器与微系统,2018,37(11):28-30. [12] QIANG Z F,WANG X,ZHANG X T. Gaussian distribution of stable diffusion for gas concentration correction on non-dispersive infrared gas sensor[J]. Chinese Journal of Scientific Instrument,2023,44(2):138-145. 强振峰,王雪,张效天. 非色散红外气体传感器稳态扩散高斯分布浓度校正方法[J]. 仪器仪表学报,2023,44(2):138-145. -
点击查看大图
计量
- 文章访问数: 4
- HTML全文浏览量: 1
- PDF下载量: 0
- 被引次数: 0
登录
注册
E-alert
登录
注册
E-alert
下载: