ADSORPTION PROPERTIES OF ORGANIC PHOSPHORUS IN WATER BY WATER TREATMENT RESIDUAL

QIU Fu-guo; LIU Yu-jun; ZHAO Shuang; FU Kun-ming; CAO Xiu-qin

doi:10.13205/j.hjgc.202101005

Volume 39 Issue 1

Apr. 2021

Turn off MathJax

Article Contents

Article Navigation > ENVIRONMENTAL ENGINEERING > 2021 > 39(1): 40-46

QIU Fu-guo, LIU Yu-jun, ZHAO Shuang, FU Kun-ming, CAO Xiu-qin. ADSORPTION PROPERTIES OF ORGANIC PHOSPHORUS IN WATER BY WATER TREATMENT RESIDUAL[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(1): 40-46. doi: 10.13205/j.hjgc.202101005

Citation:

QIU Fu-guo, LIU Yu-jun, ZHAO Shuang, FU Kun-ming, CAO Xiu-qin. ADSORPTION PROPERTIES OF ORGANIC PHOSPHORUS IN WATER BY WATER TREATMENT RESIDUAL[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(1): 40-46. doi: 10.13205/j.hjgc.202101005

Citation:

PDF( 1501 KB)

ADSORPTION PROPERTIES OF ORGANIC PHOSPHORUS IN WATER BY WATER TREATMENT RESIDUAL

doi: 10.13205/j.hjgc.202101005

Key Laboratory of Urban Stormwater System and Water Environment (Beijing University of Civil Engineering and Architecture), Ministry of Education, Beijing 100044, China

Received Date: 2019-11-06
Available Online: 2021-04-23

Abstract

Abstract

The adsorption kinetics, thermodynamics experiments and adsorption isothermal models of adsorption of adenosine monophosphate(AMP) on aluminum-based water treatment residual (Al-WTR) were studied by batch test. The effects of initial phosphorus concentration, temperature and particle size on the adsorption of AMP were analyzed. The experimental results showed that AMP uptake was favored under neutral and acidic conditions. The smaller the particle size, the larger the adsorption amount. The Al-WTR with size of 1.0~2.0 mm was most suitable for practical application. The pseudo-second-order kinetic model well fitted the adsorption process of Al-AMP on WTR, which indicated that the adsorption was mainly based on chemical adsorption. The Langmuir isotherm model described the adsorption equilibrium well, and the thermodynamic analysis manifested that the adsorption process was a spontaneous, endothermic and entropy-increasing process. The analysis of Fourier-transform infrared spectrum analysis (FTIR) showed that there was a loss of hydroxy groups associated with Al and an increase in Al-O-P bonds during the adsorption of AMP on Al-WTR. This phenomenon was enhanced by the increase of initial phosphorus concentration, indicating that the adsorption of Al-WTR on AMP mainly fulfilled through ligand exchange.
- WTR,
- organic phosphorus,
- adenosine monophosphate,
- adsorption,
- thermodynamics,
- pseudo-second order kinetic

FullText(HTML)

References(28)

References

YAN Q, JAMES B R, DAVIS A P. Lab-scale column studies for enhanced phosphorus sorption from synthetic urban stormwater using modified bioretention media[J].Journal of Environmental Engineering,2017,143(1):1-13.

ZHANG R Y, WU F C, LIU C Q, et al. Characteristics of organic phosphorus fractions in different trophic sediments of lakes from the middle and lower reaches of Yangtze River region and Southwestern Plateau, China[J]. Environmental Pollution, 2008, 152(2):366-372.

HUANG X L, ZHANG J Z. Spatial variation in sediment-water exchange of phosphorus in florida bay:amp as a model organic compound[J]. Environmental Science & Technology, 2010, 44(20):7790-7795.

YAN Q, DAVIS A P, JAMES B R. Enhanced organic phosphorus sorption from urban stormwater using modified bioretention media:batch studies[J]. Journal of Environmental Engineering, 2016, 142(4):04016001.

FENG W Y, ZHU Y R, WU F C, et al. Characterization of phosphorus forms in lake macrophytes and algae by solution 31P nuclear magnetic resonance spectroscopy[J]. Environmental Science and Pollution Research, 2016, 23(8):7288-7297.

RAZALI M, ZHAO Y Q, BRUEN M. Effectiveness of a drinking-water treatment sludge in removing different phosphorus species from aqueous solution[J]. Separation and Purification Technology, 2007, 55(3):300-306.

MAKRIS K C, SARKAR D, DATTA R. Aluminum-based drinking-water treatment residuals:a novel sorbent for perchlorate removal[J]. Environmental Pollution, 2006, 140(1):0-12.

MAKRIS K C, HARRIS W G, O'CONNO G A, et al. Phosphorus immobilization in micropores of drinking-water treatment residuals:implications for long-term stability[J]. Environmental Science & Technology, 2004, 38(24):6590-6596.

IPPOLITO J A, BARBARICK K A, ELLIOTT H A. Drinking water treatment residuals:a review of recent uses[J]. Journal of Environment Quality, 2011, 40(1):1-2.

DAYTON E A, BASTA N T. Use of drinking water treatment residuals as a potential best management practice to reduce phosphorus risk index scores[J]. Journal of Environmental Quality, 2005, 34(6):2112-2117.

仇付国,孙瑶,陈丽霞. 给水厂铝污泥特性分析及吸附氮磷性能试验[J].环境工程,2016,34(4):54-59.

MCGECHAN M B, LEWIS. Sorption of phosphorus by soil, Part 1:principles, equations and models[J]. Biosystems Engineering, 2002, 82(1):1-24.

ZHU C S, WANG L P, CHEN W B. Removal of Cu(Ⅱ) from aqueous solution by agricultural by-product:peanut hull[J]. Journal of Hazardous Materials, 2009, 168(2/3):739-746.

胡绳,刘云,董元华,等. 改性长石对磷的吸附热力学和动力学研究[J]. 环境工程学报, 2009, 3(11):2100-2104.

STEFANO C D, MILEA D, PETTIGNANO A, et al. Speciation of phytate ion in aqueous solution:alkali metal complex formation in different ionic media[J]. Analytical & Bioanalytical Chemistry, 2003, 376(7):1030-1040.

Coagulant Recovery:A Critical Assessment[M]. Washington:American Water Works Association, 1991.

SHANG C, HUANG P M, STEWART J W B. Kinetics of adsorption of organic and inorganic phosphates by short-range ordered precipitate of aluminum[J]. Canadian Journal of Soil Science, 1990, 70(3):461-470.

陈波浪,盛建东,蒋平安,等. 不同质地棉田土壤对磷吸附与解吸研究[J]. 土壤通报, 2010,41(2):303-307.

KUMAR K V, KUMARAN A. Removal of methylene blue by mango seed kernel powder[J]. Biochemical Engineering Journal, 2005, 27(1):83-93.

许光眉,施周,邓军. 石英砂负载氧化铁吸附除磷的热动力学研究[J].环境工程学报,2007,1(6):15-18.

KANG L S, HAN S W, JUNG C W. Synthesis and characterization of polymeric inorganic coagulants for water treatment[J]. Korean Journal of Chemical Engineering, 2001, 18(6):965-970.

MCINTYRE J F, FOLEY R T, BROWN B F. Infrared spectra of aluminum salt solutions[J]. Applied Spectroscopy, 1982, 36(36):128-136.

宁寻安,李凯,李润生. 聚合氯化铝的红外光谱研究[J].环境化学, 2008,27(2):263-264.

RIESGRAF D A, MAY M L. Infrared spectra of aluminum hydroxide chlorides[J]. Applied Spectroscopy, 1978, 32(4):362-366.

ZAJAC A, DYMIŃSKA L, LORENC J, et al. Syntheses, spectroscopic properties and molecular structure of silver phytate complexes-IR, UV-VIS studies and DFT calculations[J].Journal of Molecular Structure,2018:483-491.

WANG Y L, DU B Y, LIU J, et al. Surface analysis of cryofixation-vacuum-freeze-dried polyaluminum chloride-humic acid (PACl-HA) flocs[J]. Journal of Colloid & Interface Science, 2007, 316(2):457-466.

ZHAO D Y, SENGUPTA A K. Ligand separation with a copper(Ⅱ)-loaded polymeric ligand exchanger[J]. Industrial & Engineering Chemistry Research, 2000, 39(2):455-462.

GUAN X H, SHANG C, ZHU J, et al. ATR-FTIR investigation on the complexation of myo-inositol hexaphosphate with aluminum hydroxide[J]. Journal of Colloid and Interface Science, 2006, 293(2):296-302.

Relative Articles

Supplements(0)

Cited By

Proportional views