Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 39 Issue 3
Jul.  2021
Turn off MathJax
Article Contents
Abstract
References
Article Navigation >  ENVIRONMENTAL ENGINEERING  > 2021  >  39(3): 7-13
ZHU Tong, YANG Shi-peng, TAN Wei-qiang, WANG Kai-jun. DEGRADATION OF 2,4,6-TRICHLOROPHENOL BY UV/O3/TiO2 COUPLING PROCESS[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(3): 7-13. doi: 10.13205/j.hjgc.202103002
Citation: ZHU Tong, YANG Shi-peng, TAN Wei-qiang, WANG Kai-jun. DEGRADATION OF 2,4,6-TRICHLOROPHENOL BY UV/O3/TiO2 COUPLING PROCESS[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(3): 7-13. doi: 10.13205/j.hjgc.202103002
shu

DEGRADATION OF 2,4,6-TRICHLOROPHENOL BY UV/O3/TiO2 COUPLING PROCESS

doi: 10.13205/j.hjgc.202103002

  • 1. School of Environmental and Municipal Engineering, Qingdao University of Technology, Qingdao 266033, China;

  • 2. School of Environment, Tsinghua University, Beijing 100084, China

  • Received Date: 2020-06-16
    Available Online: 2021-07-19
    Abstract
  • This paper broke the technical bottleneck of low ozone utilization of advanced oxidation technology based on ozone, through constructing a reaction system of UV/O3/TiO2 coupling process. The reaction mechanism of UV/O3/TiO2 coupling process was analyzed by ESR and fluorescence probe method, and it was clear that the self recycling of oxygen produced by ozone chain reaction in the reaction system was the main reason to improve ozone utilization. Taking 2,4,6-trichlorophenol as the target pollutant, through the analysis of initial concentration, contact time, pH, catalyst dosage and other factors, the degradation effect of UV/O3 and UV/TiO2 processes was compared, which highlighted the technical advantages of UV/O3/TiO2 coupling process. The results showed that the mineralization rate of 2,4,6-trichlorophenol solution by UV/TiO2 and UV/O3 was 12.65% and 51.54% in the same condition, and the reaction rate constant was 0.0058 min-1 and 0.1956 min-1 respectively. The mineralization rate of 2,4,6-trichlorophenol by UV/O3/TiO2 was 82.97% and the reaction rate constant was 0.2893 min-1. The utilization ratio of ozone was increased by 11.7% in the coupling process with good adaptability in the wide range of pH=3~11. The result could provide data support for theoretical research conclusion.
    • FullText(HTML)
    • References(30)
  • [1]
    LIU B, CHEN B, ZHANG B Y, et al. Photocatalytic degradation of polycyclic aromatic hydrocarbons in offshore produced water:effects of water matrix[J]. Journal of Environmental Engineering, 2016, 142(11):04016054.
    [2]
    LIU B, CHEN B, LEE K, et al. Removal of naphthalene from offshore produced water through immobilized nano-TiO2 aided photo-oxidation[J]. Water Quality Research Journal of Canada, 2016, 51(3):246-255.
    [3]
    李贞燕, 陈冰. 纳米二氧化钛光催化氧化油田采出水中萘和芴的影响因素分析[J]. 环境工程学报, 2015, 9(5):2106-2112.
    [4]
    李贞燕, 陈冰. 油田采出水中萘和芴的紫外光催化和·OH氧化降解过程影响因素与条件优化分析[J]. 环境工程, 2015, 33(10):31-34.
    [5]
    LIU B, CHEN B, ZHANG B Y. Oily wastewater treatment by nano-TiO2-induced photocatalysis:seeking more efficient and feasible solutions[J]. IEEE Nanotechnology Magazine, 2017, 11(3):4-15.
    [6]
    GOMES J F, BEDNARCZYK K, GMUREK M, et al. Noble metal-TiO2, supported catalysts for the catalytic ozonation of parabens mixtures[J]. Process Safety & Environmental Protection, 2017, 111:148-159.
    [7]
    MARTINS R C, QUINTA-FERREIRA R M. Screening of ceria-based and commercial ceramic catalysts for catalytic ozonation of simulated olive mill wastewaters[J]. Industrial & Engineering Chemistry Research, 2009, 48(3):1196-1202.
    [8]
    CENTI G, PERATHONER S. Advanced Oxidation Processes in Water Treatment[M]. Handbook of Advanced Methods and Processes in Oxidation Catalysis:from Laboratory to Industry, 2014:251-290.
    [9]
    OFIARSKA A, PIECZYŃSKA A, FISZKA B A, et al. Pt-TiO2-assisted photocatalytic degradation of the cytostatic drugs ifosfamide and cyclophosphamide under artificial sunlight[J]. Chemical Engineering Journal, 2016, 285:417-427.
    [10]
    VELEGRAKI T, HAPESHI E, FATTAKASSINOS D, et al. Solar-induced heterogeneous photocatalytic degradation of methyl-paraben[J]. Applied Catalysis B:Environmental, 2015,178:2-11.
    [11]
    LIN Y, FERRONATO C, DENG N, et al. Study of benzylparaben photocatalytic degradation by TiO2[J]. Applied Catalysis B Environmental, 2011, 104(3/4):353-360.
    [12]
    HUANG H, LI W. Destruction of toluene by ozone-enhanced photocatalysis:performance and mechanism[J]. Applied Catalysis B:Environmental, 2011, 102(3/4):449-453.
    [13]
    CHONG M N, JIN B, CHOW C W K, et al. Recent developments in photocatalytic water treatment technology:A review[J]. Water Research, 2010, 44(10):2997-3027.
    [14]
    SALIMI M, ESRAFILI A, GHOLAMI M, et al. Contaminants of emerging concern:a review of new approach in AOP technologies[J]. Environmental Monitoring and Assessment, 2017, 189(8):414.
    [15]
    余丽琴, 赵高峰, 冯敏, 等. 典型氯酚类化合物对水生生物的毒性研究进展[J].生态毒理学报,2013,8(5):658-670.
    [16]
    贺强礼, 关向杰, 黄水娥, 等. 典型酚类废水的微生物处理研究现状及其进展[J]. 环境工程, 2014,32(3):6-9.
    [17]
    宋瀚文, 王东红, 徐雄, 等. 我国24个典型饮用水源地中14种酚类化合物浓度分布特征[J]. 环境科学学报, 2014, 34(2):355-362.
    [18]
    赵德明,李敏,张建庭,等.微波强化臭氧氧化降解苯酚水溶液[J]. 化工学报,2009,60(12):3137-3141.
    [19]
    YAN G L, CHEN J, HUA Z Z. Roles of H2O2 and OH radical in bactericidal action of immobilized TiO2 thin-film reactor:an ESR study[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2009, 207(2/3):153-159.
    [20]
    GOMES J F, LEAL I, BEDNARCZYK K, et al. Photocatalytic ozonation using doped TiO2 catalysts for the removal of parabens in water[J]. Science of the Total Environment, 2017, 609:329-340.
    [21]
    MEHRJOUEI M, MVLLER S, MÖLLER D. A review on photocatalytic ozonation used for the treatment of water and wastewater[J]. Chemical Engineering Journal, 2015, 263:209-219.
    [22]
    MERENYI G, LIND J, NAUMO V S, et al. Reaction of ozone with hydrogen peroxide (peroxone process):a revision of current mechanistic concepts based on thermokinetic and quantum-chemical considerations[J]. Environmental Science & Technology, 2010, 44(9):3505-3507.
    [23]
    MOREIRA N F F, ORGE C A, RIBEIRO A R, et al. Fast mineralization and detoxification of amoxicillin and diclofenac by photocatalytic ozonation and application to an urban wastewater[J]. Water Research, 2015, 87:87-96.
    [24]
    李志健, 马兰, 景立明, 等. 2,4,6-三氯苯酚臭氧氧化特性研究[J]. 纸和造纸, 2015, 34(11):69-73.
    [25]
    CHONG M N, JIN B, CHOW C W K, et al. Recent developments in photocatalytic water treatment technology:a review[J]. Water Research, 2010, 44(10):2997-3027.
    [26]
    王欣, 王金翠, 殷晓梅, 等. 乙酰甲胺磷UV-TiO2/类Fenton光催化降解过程的响应面法优化[J]. 应用化工, 2013, 42(1):33-40.
    [27]
    AGUSTINA T E, ANG H M, VAREEK V K. A review of synergistic effect of photocatalysis and ozonation on wastewater treatment[J]. Journal of Photochemistry and Photobiology C:Photochemistry Reviews, 2005, 6(4):264-273.
    [28]
    刘茜, 唐飏, 李越, 等. 可见光下F-TiO2催化剂对2,4,6-三氯苯酚光催化活性研究[J].化学研究与应用,2017,29(6):761-767.
    [29]
    殷晓梅, 王欣, 王金翠, 等. 纳米TiO2-UV光催化降解乙酰甲胺磷影响因素的研究[J]. 应用化工, 2012, 41(9):1508-1512.
    [30]
    王旭东, 唐婧, 王磊, 等. 纳米TiO2光催化-超滤法处理模拟二级出水[J]. 环境工程学报, 2016,10(4):1615-1620.
    • Relative Articles

  • Relative Articles

    [1]LI Ru, LI Xiaokang, FENG Yan, WANG Xueyan, XING Qianyun. DEGRADATION OF XYLENE BY DBD PLASMA IN COLLABORATION WITH Mn-TiO2/γ-Al2O3 CATALYST[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(4): 157-166. doi: 10.13205/j.hjgc.202404019
    [2]ZHANG Yuqing, SUN Pengkun, TONG Hua. WIDE WINDOW DENITRIFICATION OF V2O5/MICROPOROUS TiO2 UNDER SYNERGISTIC EFFECT OF DIELECTRIC BARRIER DISCHARGE PLASMA[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(6): 82-93. doi: 10.13205/j.hjgc.202406010
    [3]CAO Qiang, LI Yuran, WANG Bin, WANG Jiancheng, ZHU Tingyu. DEACTIVATION MECHANISM OF γ-Al2O3 BASED CATALYSTS FOR THE CATALYTIC HYDROLYSIS OF CARBONYL SULFIDE IN PRESENCE OF HCl[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(12): 182-189. doi: 10.13205/j.hjgc.202312022
    [4]SUN Yueyin, HUANG Qiong, ZHOU Jie, YU Xiaomeng, ZHU Jie, GU Mingyang, XU Lirui, YANG Bo, TAO Tao. PREPARATION OF VISIBLE LIGHT CATALYST AND PERFORMANCE ANALYSIS OF FORMALDEHYDE DEGRADATION OVER SILVER-BISMUTH MODIFIED TiO2 NANOMATERIAL[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(2): 146-155. doi: 10.13205/j.hjgc.202302020
    [5]LIANG Bin, FENG Shi-min, ZHANG Yong-ming. ACCELERATION OF 2,4,6-TRICHLOROPHENOL BIODEGRADATION THROUGH AEROBIC AND ANAEROBIC CONDITION ALTERNATION[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(11): 83-88. doi: 10.13205/j.hjgc.202111010
    [6]HU Shen-da, SU Wei, XING Yi, ZHANG Zhen-wei, ZHOU Jing, WANG Jian, XIA Jing-liang. PILOT-SCALE TEST ON REMOVAL OF NOx AND SO2 FROM SINTERING FLUE GAS BY OZONE OXIDATION COMBINED WITH MAGNESIUM WET ABSORPTION[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 102-106. doi: 10.13205/j.hjgc.202005018
    [7]LIU Nan-nan, LUO Shang-lian, SUN Hong-yu, QIU Chun-sheng, WANG Dong, CHI Jie, SUN Li-ping, NIE Ying-jin. CHARACTERISTICS OF Pt DOPED TiO2 AND TNTs PHOTOCATALYST AND COMPARISON OF THEIR PHOTOCATALYTIC PROPERTIES[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(2): 63-69. doi: 10.13205/j.hjgc.202002008
    [8]LIU Chang-dong, YU Shuang-jiang, MIAO Xue, SHAN Liang, LIU Jun, PENG Yue, CHEN Jian-jun, LI Jun-hua. EFFECTS OF CHELATING AGENTS OF VANADIUM SALT ON PHYSICOCHEMICAL PROPERTIES AND CATALYTIC PERFORMANCES OF V2O5/TiO2 SCR CATALYST[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(8): 174-179,81. doi: 10.13205/j.hjgc.202008029
    [9]LIU Hai-yan, LI Dong, MIAO Xue, ZHU Yuan-yuan, LIU Xiao-feng, LV Ying, LI Jie, WU Ping-xia, PENG Yue, CHEN Jian-jun, LI Jun-hua. EFFECT OF PREPARATION METHODS OF CuO-WO3/TiO2 CATALYSTS ON NH3-SCR DENITRATION ACTIVITY[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 89-95. doi: 10.13205/j.hjgc.202005016
    [10]CHEN Jun-wei, LI Li-li, FANG Zhi-huang, YE Ling-fen, ZHENG Jia-hui, WANG Fei-feng. DEGRADATION OF HUMIC ACID IN WATER BY ULTRAVIOLET PHOTOCATALYSIS OF TiO2/GO COMPOSITE NANOMATERIALS[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(8): 89-95. doi: 10.13205/j.hjgc.202008015
    [11]WU Yan-xia, LIANG Hai-long, CHEN Xin, CHEN Chen, WANG Xian-zhong, CHEN Yu-feng, DAI Chang-you, HU Li-ming. EFFECT OF ZrO2 DOPING ON DENITRIFICATION PERFORMANCE OF V2O5-MoO3/TiO2 CATALYSTS[J]. ENVIRONMENTAL ENGINEERING , 2020, 38(5): 107-112,119. doi: 10.13205/j.hjgc.202005019
    [14]Li Duosong, Zhao Qiang, Wang Xianglian. EFFECT OF UV/H2O2 ON OXIDATION PERFORMANCE OF AS( Ⅲ) IN SOIL[J]. ENVIRONMENTAL ENGINEERING , 2015, 33(5): 166-169. doi: 10.13205/j.hjgc.201505036
    • Supplements(0)
    • Cited By

  • Cited by

    Periodical cited type(3)

    1. 赵剑秋，王铮，杨世鹏，常风民，彭思伟，王凯军. UV/O_3/PS耦合工艺在含酚废水处理中的应用. 环境工程学报. 2023(01): 71-81 .
    2. 王颖，刘勇，常艳文. 一种双金属吸附材料制备及降解二氯苯酚的效果. 合成材料老化与应用. 2023(02): 82-85 .
    3. 尹前，王毅博，陈志豪，麻琦. 臭氧高级氧化技术处理印染废水的性能对比. 西安工程大学学报. 2022(03): 83-92 .

    Other cited types(1)

  • Created with Highcharts 5.0.7Amount of accessChart context menuAbstract Views, HTML Views, PDF Downloads StatisticsAbstract ViewsHTML ViewsPDF Downloads2024-052024-062024-072024-082024-092024-102024-112024-122025-012025-022025-032025-0402.557.51012.515
    Created with Highcharts 5.0.7Chart context menuAccess Class DistributionFULLTEXT: 14.9 %FULLTEXT: 14.9 %META: 82.3 %META: 82.3 %PDF: 2.7 %PDF: 2.7 %FULLTEXTMETAPDF
    Created with Highcharts 5.0.7Chart context menuAccess Area Distribution其他: 9.0 %其他: 9.0 %China: 3.8 %China: 3.8 %[]: 0.3 %[]: 0.3 %上海: 0.5 %上海: 0.5 %临汾: 0.3 %临汾: 0.3 %北京: 2.4 %北京: 2.4 %十堰: 1.4 %十堰: 1.4 %南京: 1.4 %南京: 1.4 %南充: 0.3 %南充: 0.3 %南昌: 0.3 %南昌: 0.3 %厦门: 0.3 %厦门: 0.3 %台州: 0.8 %台州: 0.8 %合肥: 0.8 %合肥: 0.8 %天津: 1.6 %天津: 1.6 %安庆: 0.3 %安庆: 0.3 %常州: 0.5 %常州: 0.5 %常德: 0.3 %常德: 0.3 %广州: 1.1 %广州: 1.1 %张家口: 0.5 %张家口: 0.5 %成都: 0.8 %成都: 0.8 %扬州: 0.5 %扬州: 0.5 %昆明: 0.3 %昆明: 0.3 %晋城: 0.5 %晋城: 0.5 %朝阳: 0.3 %朝阳: 0.3 %杭州: 1.1 %杭州: 1.1 %武汉: 2.2 %武汉: 2.2 %济南: 0.3 %济南: 0.3 %济源: 0.5 %济源: 0.5 %温州: 0.3 %温州: 0.3 %漯河: 0.8 %漯河: 0.8 %潍坊: 0.5 %潍坊: 0.5 %盐城: 0.5 %盐城: 0.5 %芒廷维尤: 21.2 %芒廷维尤: 21.2 %苏州: 0.5 %苏州: 0.5 %萍乡: 0.3 %萍乡: 0.3 %衢州: 0.5 %衢州: 0.5 %西宁: 35.6 %西宁: 35.6 %西安: 0.5 %西安: 0.5 %贵阳: 0.3 %贵阳: 0.3 %运城: 2.4 %运城: 2.4 %遵义: 0.3 %遵义: 0.3 %邯郸: 0.3 %邯郸: 0.3 %郑州: 1.1 %郑州: 1.1 %重庆: 0.3 %重庆: 0.3 %长沙: 1.4 %长沙: 1.4 %长治: 0.3 %长治: 0.3 %阳泉: 0.5 %阳泉: 0.5 %其他China[]上海临汾北京十堰南京南充南昌厦门台州合肥天津安庆常州常德广州张家口成都扬州昆明晋城朝阳杭州武汉济南济源温州漯河潍坊盐城芒廷维尤苏州萍乡衢州西宁西安贵阳运城遵义邯郸郑州重庆长沙长治阳泉

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article views (302) PDF downloads(13) Cited by(4)
    Proportional views
    Related

    Journal Online

    Authors' Center

    Links

    Copyright © 《工业建筑》杂志社有限公司 京ICP备11033253号-1

    Supported by: Beijing Renhe Information Technology Co. Ltd     百度统计

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return