CHANGES OF ACUTE TOXICITY AND FLUORESCENCE SPECTRUM PROPERTIES OF PHENOL WASTEWATER TREATED BY OZONE ADVANCED OXIDATION

WANG Shu-ting; WEI Jian-jian; MA Xue-rou; MA De-hua; LI Jian-sheng

doi:10.13205/j.hjgc.202111008

Volume 39 Issue 11

Jan. 2022

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WANG Shu-ting, WEI Jian-jian, MA Xue-rou, MA De-hua, LI Jian-sheng. CHANGES OF ACUTE TOXICITY AND FLUORESCENCE SPECTRUM PROPERTIES OF PHENOL WASTEWATER TREATED BY OZONE ADVANCED OXIDATION[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(11): 69-76. doi: 10.13205/j.hjgc.202111008

Citation:

WANG Shu-ting, WEI Jian-jian, MA Xue-rou, MA De-hua, LI Jian-sheng. CHANGES OF ACUTE TOXICITY AND FLUORESCENCE SPECTRUM PROPERTIES OF PHENOL WASTEWATER TREATED BY OZONE ADVANCED OXIDATION[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(11): 69-76. doi: 10.13205/j.hjgc.202111008

Citation:

WANG Shu-ting, WEI Jian-jian, MA Xue-rou, MA De-hua, LI Jian-sheng. CHANGES OF ACUTE TOXICITY AND FLUORESCENCE SPECTRUM PROPERTIES OF PHENOL WASTEWATER TREATED BY OZONE ADVANCED OXIDATION[J]. ENVIRONMENTAL ENGINEERING , 2021, 39(11): 69-76. doi: 10.13205/j.hjgc.202111008

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CHANGES OF ACUTE TOXICITY AND FLUORESCENCE SPECTRUM PROPERTIES OF PHENOL WASTEWATER TREATED BY OZONE ADVANCED OXIDATION

doi: 10.13205/j.hjgc.202111008

Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received Date: 2021-06-28
Available Online: 2022-01-26

Abstract

Abstract

In this study, the changes of biological toxicity during the ozonation of phenol, m-cresol, o-cresol and m-dihydroxybenzene were investigated, and the fluorescence spectra of highly toxic intermediates were revealed. It was found that the biological toxicity of four phenolic compounds firstly increased and then decreased after ozonation with the reaction time passed. The maximum biological toxicity of phenol, m-cresol, o-cresol and m-dihydroxybenzene was 16.7, 26.3, 34.8, 3.2 times of their initial toxicity, respectively. At the toxicity peaks, the toxic unit were removed by 95.2%, 94.5%, 87.3% and 44.4% respectively, after adding Na₂SO₃, and there was a significant correlation between the change of toxic unit and the recovery of fluorescence intensity peak at emission wavelength of 295~305 nm (P<0.05). It was speculated that the highly toxic intermediates formed during the ozonation of phenols were mainly oxidative carbonyl compounds. This study could provide new insight into the construction of rapid quantitative characterization of biological toxicity after ozonation based on the optical characteristics.
- ozone oxidation,
- phenolic compounds,
- acute biological toxicity,
- intermediate products,
- three-dimensional fluorescence spectra

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References(34)

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