SSTUDY ON CATALYTIC PYROLYSIS CHARACTERISTICS OF ANTIBIOTIC RESIDUE

CHANG Xiao-nan; LI Zai-xing; LI Yi-fei; ZHENG Zi-xuan

doi:10.13205/j.hjgc.202205003

Volume 40 Issue 5

Jul. 2022

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CHANG Xiao-nan, LI Zai-xing, LI Yi-fei, ZHENG Zi-xuan. SSTUDY ON CATALYTIC PYROLYSIS CHARACTERISTICS OF ANTIBIOTIC RESIDUE[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 18-24,30. doi: 10.13205/j.hjgc.202205003

Citation:

CHANG Xiao-nan, LI Zai-xing, LI Yi-fei, ZHENG Zi-xuan. SSTUDY ON CATALYTIC PYROLYSIS CHARACTERISTICS OF ANTIBIOTIC RESIDUE[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 18-24,30. doi: 10.13205/j.hjgc.202205003

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SSTUDY ON CATALYTIC PYROLYSIS CHARACTERISTICS OF ANTIBIOTIC RESIDUE

doi: 10.13205/j.hjgc.202205003

1. School of Environmental Science and Engineering, Hebei University of Science and Technology, Shijiazhuang 050000, China;
2. School of Energy and Environmental Engineering, University of Science and Technology Beijing, Beijing 100083, China

Received Date: 2020-08-10
Available Online: 2022-07-02

Abstract

Abstract

In order to convert biomass into high-quality liquid fuel, penicillin residue was selected as catalytic pyrolysis material and pyrolysis experiments were carried out at temperatures of 400℃, 500℃, 600℃ and 700℃. To maximize the yield of biomass oil, the optimal pyrolysis temperature was explored. On this basis, CoO/HZSM-5 and NiO/HZSM-5 were selected as catalysts for catalytic pyrolysis of penicillin residue to explore their catalytic effect on the quality improvement of bio-oil. The results showed that the yield of biomass oil obtained by pyrolysis of penicillin residue at 500℃ reached the peak without catalyst. At the same temperature, the yield of biomass oil decreased when catalyst CoO/HZSM-5 and NiO/HZSM-5 were added, but the content of hydrocarbons in the bio-oil increased by 8.66 and 7.41 percentage points, reaching 25.34% and 24.09%, respectively; the contents of oxygen-containing substances including alcohols, esters, and aldehydes decreased by 9.68 and 12.49 percentage points, respectively, to 31.74% and 30.34%; the contents of nitrogen-containing heterocyclic substances decreased by 5.96 and 12.49 percentage points, respectively, to 32.51% and 35.07%. The catalytic pyrolysis of three amino acids and the intermediate product DKP was studied to further explain the catalytic pyrolysis mechanism of penicillin residue.For the purpose of maximizing the rate, the optimal pyrolysis temperature was also explored.
- penicillin residue,
- amino acid,
- catalytic pyrolysis,
- HZSM-5,
- GC-MS

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References(42)

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