ADSORPTION OF PROPRANOLOL ON MONTMORILLONITE SATURATED WITH DIFFERENT METAL CATIONS

JING Xiu-yan; WANG Wen-ji; DONG Qiang-fei; QIAO Le-le; DENG Yue-hua

doi:10.13205/j.hjgc.202205010

Volume 40 Issue 5

Jul. 2022

Turn off MathJax

Article Contents

Article Navigation > ENVIRONMENTAL ENGINEERING > 2022 > 40(5): 67-74

JING Xiu-yan, WANG Wen-ji, DONG Qiang-fei, QIAO Le-le, DENG Yue-hua. ADSORPTION OF PROPRANOLOL ON MONTMORILLONITE SATURATED WITH DIFFERENT METAL CATIONS[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 67-74. doi: 10.13205/j.hjgc.202205010

Citation:

JING Xiu-yan, WANG Wen-ji, DONG Qiang-fei, QIAO Le-le, DENG Yue-hua. ADSORPTION OF PROPRANOLOL ON MONTMORILLONITE SATURATED WITH DIFFERENT METAL CATIONS[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 67-74. doi: 10.13205/j.hjgc.202205010

Citation:

PDF( 2231 KB)

ADSORPTION OF PROPRANOLOL ON MONTMORILLONITE SATURATED WITH DIFFERENT METAL CATIONS

doi: 10.13205/j.hjgc.202205010

College of Geology and Environment, Xi'an University of Science and Technology, Xi'an 710054, China

Received Date: 2021-09-02
Available Online: 2022-07-02

Abstract

Abstract

In this paper, the montmorillonite was saturated with five metal cations by the impregnation method to obtain iron-based montmorillonite(Fe-MT), copper-based montmorillonite(Cu-MT), potassium-based montmorillonite(K-MT), sodium-based montmorillonite(Na-MT), and calcium-based montmorillonite(Ca-MT). The adsorption behavior, main influencing factors, and adsorption mechanism of propranolol on these montmorillonites saturated with five interlayer metal cations were studied. The results showed that the five metal cations saturated montmorillonite had high adsorption capacity for propranolol, in the sequence of Fe-MT>Cu-MT>K-MT>Na-MT>Ca-MT. The increase of adsorption capacity at pH of 3~9 was due to the weakening of the competitiveness of adsorption sites of H⁺ and propranolol on montmorillonite saturated with metal cations. The decrease of adsorption capacity at pH of 9~11 resulted from propranolol mainly existed in molecular state and the decrease of electrostatic attraction. The presence of K⁺, Na⁺, and Ca²⁺ could inhibit the absorption of propranolol. The addition of humic acid could promote the adsorption of propranolol, but its effect decreased with the increase of humic acid concentration, and even adsorption inhibition occured. Langmuir isothermal adsorption model and the pseudo-second-order kinetic equation could better describe the adsorption process of propranolol. This study was expected to provide a theoretical basis for a comprehensive understanding of the migration and transformation of propranolol in soil environment.
- propranolol,
- metal saturation,
- montmorillonite,
- adsorption

FullText(HTML)

References(28)

References

[1]	MAROTHU V K,GORREPATI M,IDRIS N F,et al.Photocatalysis of β-blockers:an overview[J].Arabian Journal of Chemistry,2014,198(7).
[2]	GAO Q,FANG J N,GAO N Y,et al.Kinetic and mechanistic investigations of the degradation of propranolol in heat activated persulfate process[J].RSC Advances,2018,8(72):41163-41171.
[3]	FONO L J,SEDLAK D L.Use of the chiral pharmaceutical propranolol to identify sewage discharges into surface waters[J].Environmental Science and Technology,2005,39(23):9244-9252.
[4]	WICK A,FINK G,JOSS A,et al.Fate of beta blockers and psycho-active drugs in conventional wastewater treatment[J].Water Research,2009,43(4):1060-1074.
[5]	DEBLONDE T,COSSU-LEGUILLE C,HARTEMANN P.Emerging pollutants in wastewater:a review of the literature[J].International Journal of Hygiene and Environmental Health,2011,214(6):442-448.
[6]	MASZKOWSKA J,STOLTE S,KUMIRSKA J,et al.Beta-blockers in the environment:Part Ⅰ.Mobility and hydrolysis study[J].Science of the Total Environment,2014,493:1112-1121.
[7]	LIU J C,DAN X X,LU G H,et al.Investigation of pharmaceutically active compounds in an urban receiving water:occurrence,fate and environmental risk assessment[J].Ecotoxicology and Environmental Safety,2018,154:214-220.
[8]	FRAYSSE B,MONS R,GARRIC J.Development of a zebrafish 4-day embryo-larval bioassay to assess toxicity of chemicals[J].Ecotoxicology& Environmental Safety,2006,63(2):253-267.
[9]	MADUREIRA T V,ROCHA M J,CRUZEIRO C,et al.The toxicity potential of pharmaceuticals found in the Douro River estuary (Portugal):assessing impacts on gonadal maturation with a histopathological and stereological study of zebrafish ovary and testis after sub-acute exposures[J].Aquatic Toxicology,2011,105(3/4):292-299.
[10]	彭应心.β受体阻滞剂的临床疗效与理化性质有关[J].中华高血压杂志,2012(1):23-25.
[11]	王刚,甘志伟.环境中的β-阻断剂及其在污水处理中的工艺研究[J].四川农业科技,2018(6):78-80.
[12]	DING J N,LU G H,LI S,et al.Biological fate and effects of propranolol in an experimental aquatic food chain[J].Science of the Total Environment,2015,532:31-39.
[13]	ALDER A C,SCHAFFNER C,MAJEWSKY M,et al.Fate of betablocker human pharmaceuticals in surface water:comparison of measured and simulated concentrations in the Glatt Valley Watershed.Switzerland[J].Water Research,2010,44(3):936-948.
[14]	HAUCH A,TUQAN A M.Oxidation of bisoprolol in heated persulfate/H₂O systems:kinetics and products[J].Chemical Engineering Journal,2012,183:162-171.
[15]	TAY K S,ISMAIL N S B.Degradation of β-blockers in water by sulfate radical-based oxidation:kinetics,mechanism and ecotoxicity assessment[J].International Journal of Environmental Science& Technology,2016,13(10):2495-2504.
[16]	KIBBEY T C G,PARUCHURI R,SABATINI D A,et al.Adsorption of beta blockers to environmental surfaces[J].Environmental Science& Technology,2007,41(15):5349-56.
[17]	XU J Y,SUN H W,ZHANG Y W,et al.Occurrence and enantiomer profiles of β-blockers in wastewater and a receiving water body and adjacent soil in Tianjin,China[J].Science of the Total Environment,2019,650(Pt1):1122-1130.
[18]	CARTER L J,HARRIS E,WILLIAMS M,et al.Fate and uptake of pharmaceuticals in soil-plant systems[J].Journal of Agricultural& Food Chemistry,2014,62(4):816-825.
[19]	许佳瑶,孙红文,汪磊.β-受体阻断剂在黏土上的吸附行为[J].环境化学,2013,32(11):2109-2114.
[20]	MARÍA D M O,MARTÍN J,MEDINA-CARRASCO S,et al.Adsorption of propranolol onto montmorillonite:kinetic,isotherm and pH studies[J].Applied Clay Science,2019,173:107-114.
[21]	DENG Y H,LI Y N,NIE W J,et al.Fast removal of propranolol from water by attapulgite/graphene oxide magnetic ternary composites[J].Materials,2019,12(6):924.
[22]	邓月华,王文姬,贺艳,等.普萘洛尔在太湖沉积物上的吸附特征[J].环境化学,2021,40(1):263-271.
[23]	PENG N,WANG K F,LIU G G,et al.Role of complexation in propranolol sorption to clay minerals in the presence of fulvic and humic acid[J].Advanced Materials Research,2014,926/927/928/929/930:222-225.
[24]	AGGARWAL V,HUI L,BOYD S A,et al.Enhanced sorption of trichloroethene by smectite clay exchanged with Cs⁺[J].Environmental Science& Technology,2006,40(3):894-899.
[25]	MAURER M,ESCHER B I,RICHLE P,et al.Elimination of β-blockers in sewage treatment plants[J].Water Research,2007,41(7):1614-1622.
[26]	SHENG X,QIN C,YANG B,et al.Metal cation saturation on montmorillonites facilitates the adsorption of DNA via cation bridging[J].Chemosphere,2019,235:670-678.
[27]	HARO N K,DEL V P,MARCILIO N R,et al.Removal of atenolol by adsorption-Study of kinetics and equilibrium[J].Journal of Cleaner Production,2017,154:214-219.
[28]	刘楠.复合改性蒙脱土对水溶液中Cr (Ⅵ)的吸附研究[D].西安:西北大学,2017.