ADSORPTION AND TRANSFORMATION OF CHLOROPYRIDINE: RESEARCH ADVANCES AND CHALLENGES

SUN Su-yun; LI Bao-lei; KONG De-yong; HOU Ya-nan; MA Jin-feng; GUO Jian-bo; SONG Yuan-yuan

doi:10.13205/j.hjgc.202205032

Volume 40 Issue 5

Jul. 2022

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2022 > 40(5): 227-236

SUN Su-yun, LI Bao-lei, KONG De-yong, HOU Ya-nan, MA Jin-feng, GUO Jian-bo, SONG Yuan-yuan. ADSORPTION AND TRANSFORMATION OF CHLOROPYRIDINE: RESEARCH ADVANCES AND CHALLENGES[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 227-236. doi: 10.13205/j.hjgc.202205032

Citation:

SUN Su-yun, LI Bao-lei, KONG De-yong, HOU Ya-nan, MA Jin-feng, GUO Jian-bo, SONG Yuan-yuan. ADSORPTION AND TRANSFORMATION OF CHLOROPYRIDINE: RESEARCH ADVANCES AND CHALLENGES[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 227-236. doi: 10.13205/j.hjgc.202205032

Citation:

SUN Su-yun, LI Bao-lei, KONG De-yong, HOU Ya-nan, MA Jin-feng, GUO Jian-bo, SONG Yuan-yuan. ADSORPTION AND TRANSFORMATION OF CHLOROPYRIDINE: RESEARCH ADVANCES AND CHALLENGES[J]. ENVIRONMENTAL ENGINEERING , 2022, 40(5): 227-236. doi: 10.13205/j.hjgc.202205032

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ADSORPTION AND TRANSFORMATION OF CHLOROPYRIDINE: RESEARCH ADVANCES AND CHALLENGES

doi: 10.13205/j.hjgc.202205032

1. Tianjin Key Laboratory of Aquatic Science and Technology, School of Environmental and Municipal Engineering, Tianjin Chengjian University, Tianjin 300384, China;
2. National Technology Innovation Center of Synthetic Biology, Tianjin Institute of Industrial Biotechnology, Chinese Academy of Science, Tianjin 300308, China;
3. Shenyang Academy Environmental Sciences, Shenyang 110167, China

Received Date: 2021-07-19
Available Online: 2022-07-02

Abstract

Abstract

The mass production of chloropyridine herbicides and their wide application in agricultural production and daily life causes them to be continuously detected in wastewater, drinking water, and other environments, and possesses potential hazards to the ecological environment and human health. How to effectively remove chloropyridine contaminants becomes a focus in the field of water pollution control. In terms of compound structure, the breaking of the C-Cl bond is critical to the degradation of chloropyridine compounds. This work provides an overview of research advances in the removal of chloropyridine contaminants and challenges. Related strategies including adsorption, advanced oxidation methods, catalytic hydrogenation and coupling technologies, etc., have demonstrated an excellent pollutant detoxification effect. The mechanisms, process parameters, and major challenges of pollutants removal are discussed in detail. The adsorption method faces problems such as difficulty in degrading pollutants, developing new adsorbent materials, and adsorbent regeneration. Advanced oxidation technology has a high pollutant mineralization rate, but its disadvantages are low oxidation efficiency and high operating cost. The catalytic hydrogenation degraded pollutants directionally, but the degradation is still incomplete. Biological treatment technology is economical and effective, but the removal rate of pollutants still needs to be improved. The studies indicate that due to the refractory characteristics of chloropyridine contaminants, it is efficient to remove the pollutants with independent treatment technology. The combination of multiple treatment methods is a feasible strategy for the efficient removal of pollutants. Researches on the transformation technologies and mechanisms of chloropyridine in the environment have important theoretical and practical guiding value for the efficient detoxification and degradation of risk pollutants.
- chloropyridine contaminants,
- adsorption,
- advanced oxidation,
- catalytic hydrogenation,
- biological treatment

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References(55)

References

[1]	MATSUSHITAL T,MORIMOTO A,KURIYAMA T,et al.Removals of pesticides and pesticide transformation products during drinking water treatment processes and their impact on mutagen formation potential after chlorination[J].Water Research,2018,138(1):67-76.
[2]	ALEXANDRINO D A M,MUCHA A P,ALMEIDA C M R,et al.Microbial degradation of two highly persistent fluorinated fungicides-epoxiconazole and fludioxonil[J].Journal of Hazardous Materials,2020,394:122545.
[3]	ZHANG H Y,YUAN X Z,XIONG T,et al.Bioremediation of co-contaminated soil with heavy metals and pesticides:influence factors,mechanisms and evaluation methods[J].Chemical Engineering Journal,2020,398:125657.
[4]	FIORENZA R,DI MAURO A,CANTARELLA M,et al.Preferential removal of pesticides from water by molecular imprinting on TiO₂ photocatalysts[J].Chemical Engineering Journal,2020,379:122309.
[5]	YANG X R,DING X,ZHOU L,et al.New insights into clopyralid degradation by sulfate radical:pyridine ring cleavage pathways[J].Water Research,2020,171:115378.
[6]	GARCIA-MUNOZ P,DACHTLER W,ALTMAYER B,et al.Reaction pathways,kinetics and toxicity assessment during the photocatalytic degradation of glyphosate and myclobutanil pesticides:influence of the aqueous matrix[J].Chemical Engineering Journal,2020,384:123315.
[7]	SEMITSOGLOU-TSIAPOU S,TEMPLETON M R,GRAHAM N J,et al.Low pressure UV/H₂O₂ treatment for the degradation of the pesticides metaldehyde,clopyralid and mecoprop-Kinetics and reaction product formation[J].Water Research,2016,91(1):285-294.
[8]	SOJIC D V,ANDERLUH V B,ORCIC D Z,et al.Photodegradation of clopyralid in TiO₂ suspensions:identification of intermediates and reaction pathways[J].Journal of Hazardous Materials,2009,168(1):94-101.
[9]	MACIEL G M,SOUZA C G M D,ARAUJO C A V D,et al.Biosorption of herbicide picloram from aqueous solutions by live and heat-treated biomasses of Ganoderma lucidum(Curtis) P.Karst and Trametes sp.[J].Chemical Engineering Journal,2013,215/216(9):331-338.
[10]	LI H Y,QIU Y Z,YAO T,et al.Evaluation of seven chemical pesticides by mixed microbial culture (PCS-1):degradation ability,microbial community,and Medicago sativa phytotoxicity[J].Journal of Hazardous Materials,2020,389:121834.
[11]	王建龙.废水中工业强度氯吡啉的生物处理生物降解与处理毒性[J].四川师范大学学报,2020,43(2):143-173.
[12]	HASAN Z,JHUNG S H.Removal of hazardous organics from water using metal-organic frameworks (MOFs):plausible mechanisms for selective adsorptions[J].Journal of Hazardous Materials,2015,283(9):329-339.
[13]	de SMEDT C,SPANOGHE P,BISWAS S,et al.Comparison of different solid adsorbents for the removal of mobile pesticides from aqueous solutions[J].Adsorpt,2015,21(3):243-254.
[14]	ZHANG H Q,JIA Y Y,KHANALS K,et al.Understanding the role of extracellular polymeric substances on ciprofloxacin adsorption in aerobic sludge,anaerobic sludge,and sulfate-reducing bacteria sludge systems[J].Environmental Science& Technology,2018,52(11):6476-6486.
[15]	李文刚,孙耀胜,么强,等.新型有机污染物污染现状及其深度处理工艺研究进展[J].环境工程,2021,39(8):77-87.
[16]	MARCO-BROWN J L,ARECO M M,TORRES SANCHEZ R M,et al.Adsorption of picloram herbicide on montmorillonite:kinetic and equilibrium studies[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,2014,449(2):121-128.
[17]	MARCO-BROWN J L,BARBOSA-LEMA C M,TORRES SANCHEZ R M,et al.Adsorption of picloram herbicide on iron oxidepillared montmorillonite[J].Applied Clay Science,2012,58(1):25-33.
[18]	KHAN S,HE X,KHAN J A,et al.Kinetics and mechanism of sulfate radical-and hydroxyl radical-induced degradation of highly chlorinated pesticide lindane in UV/peroxymonosulfate system[J].Chemical Engineering Journal,2017,318(5):135-142.
[19]	孙怡,于利亮,黄浩斌,等.高级氧化技术处理难降解有机废水的研发趋势及实用化进展[J].化工学报,2017,68(5):1743.
[20]	SKOUTELIS C,ANTTONOPOULOU M,KONSTANTINOU I,et al.Photodegradation of 2-chloropyridine in aqueous solution:reaction pathways and genotoxicity of intermediate products[J].Journal of Hazardous Materials,2017,321(9):753-763.
[21]	TIZAOUI C,MEZUGHI K,BICKLEY R.Heterogeneous photocatalytic removal of the herbicide clopyralid and its comparison with UV/H₂O₂ and ozone oxidation techniques[J].Desalination,2011,273(1):197-204.
[22]	WESTPHAL K,SALIGER R,JAGER D,et al.Degradation of clopyralid by the fenton reaction[J].Industrial& Engineering Chemistry Research,2013,52(39):13924-13929.
[23]	XU G,BU T T,WU M H,et al.Electron beam induced degradation of clopyralid in aqueous solutions[J].Journal of Radioanalytical and Nuclear Chemistry,2011,288(3):759-764.
[24]	ORELLANA-GARACIA F,ALVAREZ M A,LOPEZ-RAMON V,et al.Photodegradation of herbicides with different chemical natures in aqueous solution by ultraviolet radiation:effects of operational variables and solution chemistry[J].Chemical Engineering Journal,2014,255(6):307-315.
[25]	PEREZ-LUCAS G,ALISTE M,VELA N,et al.Decline of fluroxypyr and triclopyr residues from pure,drinking and leaching water by photo-assisted peroxonation[J].Process Safety and Environmental Protection,2020,137(2):358-365.
[26]	WU M H,YANG X Y,XU G,et al.UV-Based oxidation processes for removal of clopyralid:optimal conditions,efficiency,and by-products[J].Environmental Engineering Science,2015,32(12):998-1006.
[27]	BERBERIDOU C,KYZAS G Z,PASPALTSIS I,et al.Photocatalytic disinfection and purification of water employing reduced graphene oxide/TiO₂ composites[J].Journal of Chemical Technology& Biotechnology,2019,94(12):3905-3914.
[28]	MACIAS-SANCHEZ J J,HINOJOSA-REYES L,CABALLERO-QUINTERO A,et al.Synthesis of nitrogen-doped ZnO by sol-gel method:characterization and its application on visible photocatalytic degradation of 2,4-D and picloram herbicides[J].Photochemical& Photobiological Sciences,2015,14(3):536-542.
[29]	RASHEED P,HAQ S,WASEEM M,et al.Green synthesis of vanadium oxide-zirconium oxide nanocomposite for the degradation of methyl orange and picloram[J].Materials Research Express,2020,7(2):025011.
[30]	ABRANMOVIC B F,ANDERLUH V B,TOPALOV A S,et al.Titanium dioxide mediated photocatalytic degradation of 3-amino-2-chloropyridine[J].Applied Catalysis B:Environment,2004,48(3):213-221.
[31]	OZCAN A,SAHIN Y,KOPARAL A S,et al.Degradation of picloram by the electro-Fenton process[J].Journal of Hazardous Materials,2008,153(1/2):718-727.
[32]	WANG J L,CHEN H.Catalytic ozonation for water and wastewater treatment:recent advances and perspective[J].Science of teh Total Environment,2020,704:135249.
[33]	KANAKARAJU D,GLASS B D,OELGEMOLLER M.Advanced oxidation process-mediated removal of pharmaceuticals from water:a review[J].Journal of Environmental Management,2018,219(4):189-207.
[34]	WANG Y,LI H Y,YI P,et al.Degradation of clofibric acid by UV,O₃ and UV/O₃ processes:performance comparison and degradation pathways[J].Journal of Hazardous Materials,2019,379:120771.
[35]	ORTEGA-LIEBANA M C,SANCHEZ-LOPEZ E,HIDALGO-CARRILLO J,et al.A comparative study of photocatalytic degradation of 3-chloropyridine under UV and solar light by homogeneous (photo-Fenton) and heterogeneous (TiO₂) photocatalysis[J].Applied Catalysis B:Environment,2012,127(8):316-322.
[36]	PHOON B L,ONG C C,MOHAMED SAHEED M S,et al.Conventional and emerging technologies for removal of antibiotics from wastewater[J].Journal of Hazardous Materials,2020,400:122961.
[37]	CARBONERAS CONTREAS M B,FOURCADE F,ASSADI A,et al.Electro Fenton removal of clopyralid in soil washing effluents[J].Chemosphere,2019,237:124447.
[38]	SIEDLECKA E M,OFIARSKA A,BORZYSZKOWSKA A F,et al.Cytostatic drug removal using electrochemical oxidation with BDD electrode:degradation pathway and toxicity[J].Water Research,2018,144:235-245.
[39]	KARAÇAL A,MUNOZ-MORALES M,KALKAN S,et al.A comparison of the electrolysis of soil washing wastes with active and non-active electrodes[J].Chemosphere,2019,225:19-26.
[40]	TEEVS L,VORLOP K D,PRUßE U.Model study on the aqueous-phase hydrodechlorination of clopyralid on noble metal catalysts[J].Catalysis Communications,2011,14(1):96-100.
[41]	PENG H,GUO J B,LI H B,et al.Granulation and response of anaerobic granular sludge to allicin stress while treating allicin-containing wastewater[J].Biochemical Engineering Journal,2021,169:107971.
[42]	罗开华.生化法处理吡啶羧酸类废水的研究[D].湘潭:湘潭大学,2019.
[43]	TU J,GUO J B,LU C C,et al.Effect and mechanism of cyclodextrins on nitrate reduction and bio-activity by S.oneidensis.MR-1[J].Bioresource Technology,2020,317:124002.
[44]	ZHANG C,WANG S H,LV Z W,et al.NanoFe₃O₄ accelerates anoxic biodegradation of 3,5,6-trichloro-2-pyridinol[J].Chemosphere,2019,235(6):185-193.
[45]	SOLIS R R,JAVIER RIVAS F,GIMENO O,et al.Photocatalytic ozonation of pyridine-based herbicides by N-doped titania[J].Journal of Chemical Technology& Biotechnology,2016,91(7):1998-2008.
[46]	REDDY SP V,KIM K H.A review of photochemical approaches for the treatment of a wide range of pesticides[J].Journal of Hazardous Materials,2015,285(11):325-335.
[47]	RAJAH Z,GUIZA M,SOLIS R R,et al.Clopyralid degradation using solar-photocatalytic/ozone process with olive stone activated carbon[J].Journal of Environmental Chemical Engineering,2019,7(1):102900.
[48]	RAJAH Z,GUIZA M,SOLIS R R,et al.Catalytic and photocatalytic ozonation with activated carbon as technologies in the removal of aqueous micropollutants[J].Journal of Photochemistry and Photobiology A:Chem,2019,382:111961.
[49]	BERBERIDOU C,KISIOU V,KARAHANIDOU S,et al.Photocatalytic degradation of the herbicide clopyralid:kinetics,degradation pathways and ecotoxicity evaluation[J].Journal of Chemical Technolgoy& Biotechnology,2016,91:2510.
[50]	MUNOZ-MORALES M,SAEZ C,CANIZARES P,et al.Improvement of electrochemical oxidation efficiency through combination with adsorption processes[J].Journal of Environmental Management,2020,262:110364.
[51]	MARTIN de VIDALES M J,CASTRO M P,SAEZ C,et al.Radiation-assisted electrochemical processes in semi-pilot scale for the removal of clopyralid from soil washing wastes[J].Separation and Purification Technology,2019,208(4):100-109.
[52]	RASCHITOR A,LLANOS J,RODRIGO M A,et al.Is it worth using the coupled electrodialysis/electro-oxidation system for the removal of pesticides?Process modelling and role of the pollutant[J].Chemosphere,2020,246:125781.
[53]	BARBOSA FERREIRA M,SOUZA F L,MUNOZ-MORALES M,et al.Clopyralid degradation by AOPs enhanced with zero valent iron[J].Journal of Hazardous Materials,2020,392:122282.
[54]	CARBONERAS M B,CANIZARES P,RODRIGO M A,et al.Improving biodegradability of soil washing effluents using anodic oxidation[J].Bioresource Technology,2018,252(12):1-6.
[55]	SEDLAZECK K P,VOLLPRECHT D,MULLER P,et al.Decomposition of dissolved organic contaminants by combining a boron-doped diamond electrode,zero-valent iron and ultraviolet radiation[J].Chemosphere,2019,217(11):897-904.