PERFORMANCE OF Bi<sub>2</sub>WO<sub>6</sub>@MXenes-NS ACTIVATED PERMONOSULFATE IN DEGRADING BISPHENOL A

XU Zhenyang; FANG Qinglu; GU Wenwen; LI Zhiying; ZHANG Yimei; WANG Fei

doi:10.13205/j.hjgc.202304002

Volume 41 Issue 4

Apr. 2023

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XU Zhenyang, FANG Qinglu, GU Wenwen, LI Zhiying, ZHANG Yimei, WANG Fei. PERFORMANCE OF Bi2WO6@MXenes-NS ACTIVATED PERMONOSULFATE IN DEGRADING BISPHENOL A[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(4): 10-17,62. doi: 10.13205/j.hjgc.202304002

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XU Zhenyang, FANG Qinglu, GU Wenwen, LI Zhiying, ZHANG Yimei, WANG Fei. PERFORMANCE OF Bi₂WO₆@MXenes-NS ACTIVATED PERMONOSULFATE IN DEGRADING BISPHENOL A[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(4): 10-17,62. doi: 10.13205/j.hjgc.202304002

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PERFORMANCE OF Bi₂WO₆@MXenes-NS ACTIVATED PERMONOSULFATE IN DEGRADING BISPHENOL A

doi: 10.13205/j.hjgc.202304002

1. College of Environmental Science and Engineering, North China Electric Power University, Beijing 100096, China;
2. Suzhou Research Institute of North China Electric Power University, Suzhou 215000, China;
3. College of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China

Received Date: 2021-10-14
Available Online: 2023-05-26
Publish Date: 2023-04-01

Abstract

Abstract

In order to solve the problem of removing endocrine disruptors in water environment, Bi₂WO₆@MXenes-NS(BM-NS) composite catalyst was synthesized by hydrothermal method, and bisphenol A (BPA) was degraded by activation of permonosulfate (PMS). The morphology and crystal structure of the catalyst were characterized by SEM, TEM and XRD. The effects of different catalyst systems, PMS concentrations, solution pH and coexisting ions on the degradation of BPA were investigated. The results showed that when the concentration of MXenes-NS was 0.5%, the concentration of catalyst was 1 g/L, the concentration of PMS was 0.3 g/L, and the solution pH was 3.03, BM-NS/PMS system had a strong BPA degradation performance, and the removal rate reached 85.3% within 120 min. In addition, the effects of inorganic anions on BPA removal were in a sequence as follows: Cl^-2PO^-₄2-₄-₃≈NO^-₃. The removal rate of BPA remained 70.1% after 4 cycles. The results of the radical quenching experiment showed that SO^-₄· was the main active radical. Combined with LC-MS, the possible degradation pathway of BPA was proposed. The above experimental results indicated that the prepared BM-NS catalyst had a good application prospect in activating PMS to degrade BPA.
- Bi₂WO₆,
- MXenes-NS,
- permonosulfate,
- sulfate radical SO^-₄·,

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References(24)

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