PERFORMANCE OF SCHWERTMANNITE IN FENTON-LIKE OXIDATION OF PHENOL IN LIQUID PHASE AND SOIL

MA Qingpeng; YANG Kai; ZENG Yongqin; BI Xue; ZHOU Yan; ZHANG Zhuo

doi:10.13205/j.hjgc.202306016

Volume 41 Issue 6

Jun. 2023

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MA Qingpeng, YANG Kai, ZENG Yongqin, BI Xue, ZHOU Yan, ZHANG Zhuo. PERFORMANCE OF SCHWERTMANNITE IN FENTON-LIKE OXIDATION OF PHENOL IN LIQUID PHASE AND SOIL[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(6): 117-123,150. doi: 10.13205/j.hjgc.202306016

Citation:

MA Qingpeng, YANG Kai, ZENG Yongqin, BI Xue, ZHOU Yan, ZHANG Zhuo. PERFORMANCE OF SCHWERTMANNITE IN FENTON-LIKE OXIDATION OF PHENOL IN LIQUID PHASE AND SOIL[J]. ENVIRONMENTAL ENGINEERING , 2023, 41(6): 117-123,150. doi: 10.13205/j.hjgc.202306016

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PERFORMANCE OF SCHWERTMANNITE IN FENTON-LIKE OXIDATION OF PHENOL IN LIQUID PHASE AND SOIL

doi: 10.13205/j.hjgc.202306016

1. Power China Eco-Environment Group Co., Ltd., Shenzhen 515833, China;
2. Beijing Junmei Environmental Technology Co., Ltd., Beijing 102627, China;
3. School of Land Science and Technology, China University of Geosciences (Beijing), Beijing 100083, China

Received Date: 2022-05-12
Available Online: 2023-09-02

Abstract

Abstract

Schwertmannite (Sch) presents high catalytic properties potential for phenol oxidation in a Fenton-like mechanism, because of its unique combination of Fe composition and structure characteristics. In this study, Sch was fabricated as a heterogeneous Fenton-like catalyst through chemical oxidation, for phenol degradation in polluted water and soil. The synthetic minerals have a typical sea-urchin-like structure and ordered morphology with unique channels of a specific size range. The catalytic performance of Sch for phenol oxidation in water and alcohol with various pH values was investigated. Under an acidic pH, nearly 98% of phenol was successfully removed. When Sch material was added to neutral or nearly acidic C₆H₅OH contaminated soil at a mass ratio of 1.25% or 2.5%, the concentration of C₆H₅OH could be reduced from 6.052 mg/kg to less than 0.2 mg/kg. The material had great potential application prospect in actual remediation projects of phenol polluted soil.
- Schwertmannite,
- Fenton,
- phenol,
- oxidation,
- water,
- soil

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References(29)

References

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