ADSORPTION PERFORMANCE OF TC AND Cu<sup>2+</sup> BY METAL-ORGANIC SKELETON HYBRID FOAMS

LI Wei; HU Haoting; LIU Ning; YE Youlin; GAO Mingjie; FENG Qing

doi:10.13205/j.hjgc.202406004

Volume 42 Issue 6

Jun. 2024

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Article Navigation > ENVIRONMENTAL ENGINEERING > 2024 > 42(6): 25-34

LI Wei, HU Haoting, LIU Ning, YE Youlin, GAO Mingjie, FENG Qing. ADSORPTION PERFORMANCE OF TC AND Cu2+ BY METAL-ORGANIC SKELETON HYBRID FOAMS[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(6): 25-34. doi: 10.13205/j.hjgc.202406004

Citation:

LI Wei, HU Haoting, LIU Ning, YE Youlin, GAO Mingjie, FENG Qing. ADSORPTION PERFORMANCE OF TC AND Cu²⁺ BY METAL-ORGANIC SKELETON HYBRID FOAMS[J]. ENVIRONMENTAL ENGINEERING , 2024, 42(6): 25-34. doi: 10.13205/j.hjgc.202406004

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ADSORPTION PERFORMANCE OF TC AND Cu²⁺ BY METAL-ORGANIC SKELETON HYBRID FOAMS

doi: 10.13205/j.hjgc.202406004

1. College of Municipal and Environmental Engineering, Shenyang Jianzhu University, Shenyang 110168, China;
2. Country Garden Real Estate Development Co., Ltd., Shenyang 110013, China;
3. Liaoning Urban and Rural Construction Planning and Design Institute Co., Ltd., Shenyang 110006, China;
4. China Construction Engineering Design & Research Institute Co., Ltd., Beijing 100037, China

Received Date: 2023-01-19
Available Online: 2024-07-11

Abstract

Abstract

The removal of antibiotics and heavy metals in the medicine wastewater is a tricky problem, and the metal-organic skeleton hybrid foam MIL-100(Fe)/CMC was used to remove tetracycline (TC) and copper ions (Cu²⁺). The physicochemical properties of the MOFs hybrid foams were analyzed by X-ray diffraction, scanning electron microscopy, nitrogen adsorption and desorption, as well as thermogravimetric analysis techniques; the influencing factors, stability, and adsorption mechanisms of hybrid foams were analyzed by adsorption experiments. The results showed that MIL-100(Fe)/CMC had porous structure and high thermal stability; MIL-100(Fe)/CMC had-maximum adsorption capacity of 80.40 and 80.04 mg/g for tetracycline (TC) and Cu²⁺, respectively, in the optimal working condition of 30 mg/L contaminants, 40 mg dosage of MIL-100(Fe)/CMC, 16 hours adsorption time, pH of 6 the ionic strength (NaCl) was negatively correlated with adsorption performance. MIL-100(Fe)/CMC had excellent adsorption and cyclic regeneration performance, and the removal rates of TC and Cu²⁺ maintained above 70% after six cycles of regeneration. The adsorption of TC and Cu²⁺ by MIL-100(Fe)/CMC was a self-exothermic process, matching the Langmuir isotherm model and the proposed first-order kinetic model. In conclusion, the metal organic skeleton hybrid foam is proven to have a broad research prospect in the removal of mixed contaminants of antibiotics and heavy metals in the treatment of pharmaceutical wastewater.
- metal-organic skeletal hybrid foam,
- adsorbent,
- tetracycline,
- Cu²⁺,
- cyclic regeneration

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References(41)

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