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Volume 43 Issue 4
Apr.  2025
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Article Contents
LIU K Y,WANG J J,LING Z C,et al.Preparation of drinking water treatment residue-based functional materials and their application in pollutant adsorption[J].Environmental Engineering,2025,43(4):132-142. doi: 10.13205/j.hjgc.202504013
Citation: LIU K Y,WANG J J,LING Z C,et al.Preparation of drinking water treatment residue-based functional materials and their application in pollutant adsorption[J].Environmental Engineering,2025,43(4):132-142. doi: 10.13205/j.hjgc.202504013

Preparation of functional materials based on drinking water treatment residue and their application in pollutants adsorption

doi: 10.13205/j.hjgc.202504013
  • Received Date: 2024-10-15
  • Accepted Date: 2024-12-19
  • Rev Recd Date: 2024-11-12
  • Publish Date: 2025-04-01
  • With the rapid economic development and accelerated urbanization, the urban water consumption population in China has been continuously increasing. While traditional water treatment processes ensure the safety of drinking water, they also generate tens of millions of cubic meters of drinking water treatment residues (DWTR) annually. Compared to wastewater treatment sludge, the disposal of DWTR has received relatively less attention in research and practice. Therefore, the environmentally friendly treatment and resource utilization of DWTR deserve greater attention. This paper aims to review recent advances in preparation methods of DWTR-based functional materials, analyzes the influence of these methods on their structure and adsorption properties, identifies the sources and mechanisms of their primary adsorption active sites, and discusses the limitations and challenges faced by DWTR-based functional materials for pollutant adsorption. The findings indicated that the inherent inorganic substances, such as Al and Fe, in DWTR not only served as active sites for pollutant adsorption but also provided structural frameworks for the synthesis of composite functional materials, thereby enhancing pollutant adsorption. While techniques such as pyrolysis, activation, and compounding could improve the adsorption performance of DWTR-based functional materials, they also led to increased cost, presenting a big challenge for widespread application. Therefore, this paper proposes to provide guidance for the preparation of DWTR-based functional materials and the optimization of their adsorption properties through life cycle assessment and cost-benefit analysis, integrated with machine learning simulations. Furthermore, future research should aim to expand the scope of targeted pollutants or focus on the high-value recycling of DWTR resources, thereby achieving low-carbon recycling and sustainable utilization of DWTR-based materials in the context of the “Dual Carbon” goals.
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  • [1]
    SHUI L L,DAI T,ZHENG X G,et al. Analysis of environmental attributes of water supply plant sludge resources research on its low carbon utilization path[J]. China Municipal Engineering,2024(4):46-49,152. 水亮亮,戴腾,郑晓光,等. 给水厂污泥资源环境属性解析及其低碳利用路径研究[J]. 中国市政工程,2024(4):46-49,152.
    [2]
    LUO Z N,XU B,TANG Y L,et al. Method and strategy analysis of sludge treatment and resource utilization in urban drinking water treatment plants[J]. Energy Environmental Protection,2023,37(5):99-109. 罗振宁,徐斌,唐玉霖,等. 城市给水厂污泥处理与资源化利用途径及策略分析[J]. 能源环境保护,2023,37(5):99-109.
    [3]
    NAYERI D,MOUSAVI S A. A comprehensive review on the coagulant recovery and reuse from drinking water treatment sludge[J]. Journal of Environmental Management,2022,319:115649.
    [4]
    XU Z Y,CHEN X,MENG F K,et al. Overview of drinking water treatment residue reuse risks and environmental applications[J]. Water& Wastewater Engineering,2023,59(3):140-150. 徐舟影,陈曦,孟发科,等. 给水厂污泥再利用风险分析及其环境应用综述[J]. 给水排水,2023,59(3):140-150.
    [5]
    LIU Q L,WANG R F,MA J. Challenges of urban water supply and discussions on the strategic solution with related technology developments of urban water quality under the vision of carbon neutrality[J]. Water& Wastewater Engineering,2022,58(1):1-12. 刘晴靓,王如菲,马军. 碳中和愿景下城市供水面临的挑战、安全保障对策与技术研究进展[J]. 给水排水,2022,58(1):1-12.
    [6]
    KANG C,ZHAO Y,TANG C,et al. Use of aluminum-based water treatment sludge as coagulant for animal farm wastewater treatment[J]. Journal of Water Process Engineering,2022,46:102645.
    [7]
    ZHENG Y Y,YU Y F,LI Y,et al. Adsorption of phosphorus or ammonia nitrogen by ceramsite made from waterworks sludge[J]. Chinese Journal of Environmental Engineering,2015,9(2):756-762. 郑育毅,余育方,李妍,等. 自来水厂污泥制得陶粒对污水中磷和氨氮的吸附[J]. 环境工程学报,2015,9(2):756-762.
    [8]
    SHEN C,ZHAO Y,LI W,et al. Global profile of heavy metals and semimetals adsorption using drinking water treatment residual[J]. Chemical Engineering Journal,2019,372:1019-1027.
    [9]
    WANG C,JIANG H L,YUAN N,et al. Tuning the adsorptive properties of drinking water treatment residue via oxygen-limited heat treatment for environmental recycle[J]. Chemical Engineering Journal,2016,284:571-581.
    [10]
    ZHAO X H,ZHAO Y Q. Investigation of phosphorus desorption from P-saturated alum sludge used as a substrate in constructed wetland[J]. Separation and Purification Technology,2009,66(1):71-75.
    [11]
    FOROUGHI M,CHAVOSHI S,BAGHERI M,et al. Alum-based sludge(AbS)recycling for turbidity removal in drinking water treatment:an insight into statistical,technical,and health-related standpoints[J]. Journal of Material Cycles and Waste Management,2018,20(4):1999-2017.
    [12]
    ZHOU Z,YANG Y,LI X,et al. Optimized removal of natural organic matter by ultrasound-assisted coagulation of recycling drinking water treatment sludge[J]. Ultrasonics Sonochemistry,2018,48:171-180.
    [13]
    SHAHIDI N M H,HASANI Z M,GHASEMI M. Developing a robust indicator to evaluate circular economy through reuse strategy:a case study of using water treatment sludge as a coagulant for dewatering of iron ore tailings slurry[J]. Minerals Engineering,2024,219:109062.
    [14]
    HE C T. Sludge treatment of water purification plants[M]. 2nd Edition. Beijing:China Architecture& Building Press,2016. 何纯提. 净水厂排泥水处理[M]. 2版. 北京:中国建筑工业出版社,2016.
    [15]
    CHEN H,WU H,KHAN N S A,et al. Converting wastes to resource:preparation of NiO@γ-Al2O3 sludge composite from aluminum-containing sludge for cadmium removal from wastewater[J]. Journal of Cleaner Production,2023,392:136335.
    [16]
    CHEN A,LV L,HU R,et al. Achieving win-win outcomes with cerium-loaded porous aluminum sludge hydrogel microspheres for enhanced phosphate removal[J]. Science of the Total Environment,2023,867:161530.
    [17]
    EVERAERT M,BERGMANS J,BROOS K,et al. Granulation and calcination of alum sludge for the development of a phosphorus adsorbent:from lab scale to pilot scale[J]. Journal of Environmental Management,2021,279:111525.
    [18]
    YUAN X,DISSANAYAKE P D,GAO B,et al. Review on upgrading organic waste to value-added carbon materials for energy and environmental applications[J]. Journal of Environmental Management,2021,296:113128.
    [19]
    KUMAR M,OLAJIRE OYEDUN A,KUMAR A. A review on the current status of various hydrothermal technologies on biomass feedstock[J]. Renewable and Sustainable Energy Reviews,2018,81:1742-1770.
    [20]
    JING F,HUI B,YUDAN X,et al. Recycling of iron and aluminum from drinking water treatment sludge for synthesis of a magnetic composite material(ALCS-Fe-Al)to remove fluoride from drinking water[J]. Groundwater for Sustainable Development,2020,11:100456.
    [21]
    CHENG W,MA X,CHEN H,et al. Yttrium-modified drinking water treatment residue for efficient phosphorus removal:efficacy,mechanism,and reproducibility[J]. Environmental Science and Pollution Research,2023,30(51):111611-111626.
    [22]
    HE L,CHEN Y,SUN F,et al. Controlled release of phosphorus using lanthanum-modified hydrochar synthesized from water treatment sludge:adsorption behavior and immobilization mechanism[J]. Journal of Water Process Engineering,2022,50:103319.
    [23]
    ZHENG Z,DUAN X,TIE J. One-pot synthesis of a magnetic Zn/iron-based sludge/biochar composite for aqueous Cr(VI)adsorption[J]. Environmental Technology& Innovation,2022,28:102661.
    [24]
    TIE J,LI W,LIU H,et al. Efficient adsorption and reduction of Cr(VI)by a novel polyaniline modified magnetic iron-based waterworks sludge from aqueous solution[J]. Chemical Engineering Journal,2023,451:137673.
    [25]
    LI J,LI B,HUANG H,et al. Investigation into lanthanum-coated biochar obtained from urban dewatered sewage sludge for enhanced phosphate adsorption[J]. Science of the Total Environment,2020,714:136839.
    [26]
    SOLIMAN M F,RASHED M N,AHMD A A. Chemical activation of sludge from drinking water treatment plant for adsorption of methylene blue dye[J]. Water,Air,& Soil Pollution,2023,234(4):228.
    [27]
    NING K,CHEN H,WANG D,et al. Effective removal of fluoride and lead ions from aqueous solutions using water treatment residue and rice straw co-pyrolysis biochar composites[J]. Environmental Technology& Innovation,2024,34:103589.
    [28]
    ZHANG Y,ABASS O K,QIN J,et al. The role of freshwater sludge and its carbonaceous derivatives in the removal of lead,phosphorus and antibiotic enrofloxacin:sorption characteristics and performance[J]. Chemosphere,2022,290:133298.
    [29]
    XI J,ZHANG R,YE L,et al. Multi-step preparation of Fe and Si modified biochar derived from waterworks sludge towards methylene blue adsorption[J]. Journal of Environmental Management,2022,304:114297.
    [30]
    EL-MONAEM E M ABD,OMER A M,EL-SUBRUITI G M,et al. Zero-valent iron supported-lemon derived biochar for ultra-fast adsorption of methylene blue[J]. Biomass Conversion and Biorefinery,2024,14(2):1697-1709.
    [31]
    DU L,AHMAD S,LIU L,et al. A review of antibiotics and antibiotic resistance genes(ARGs)adsorption by biochar and modified biochar in water[J]. Science of The Total Environment,2023,858:159815.
    [32]
    ZOROUFCHI BENIS K. Transforming drinking water treatment residuals into efficient adsorbents:a review of activation and modification methods[J]. Environmental Research,2024,262:119893.
    [33]
    KIM G,RYU J,RYU T,et al. Effects of calcination temperature on the adsorption ability of polyaluminum chloride(PAC)sludge-derived granules for As(V)[J]. Journal of Water Process Engineering,2024,57:104688.
    [34]
    WANG C,LUO H,ZHANG Z,et al. Removal of As(III)and As(V)from aqueous solutions using nanoscale zero valent iron-reduced graphite oxide modified composites[J]. Journal of Hazardous Materials,2014,268:124-131.
    [35]
    DE CARVALHO G S,ZHOU J L,ZENG X,et al. Water treatment sludge conversion to biochar as cementitious material in cement composite[J]. Journal of Environmental Management,2022,306:114463.
    [36]
    MOHAMED B A,HUANG C,MOK N,et al. A comparative life-cycle assessment and cost analysis of biofilters amended with sludge-based activated carbon and commercial activated carbon for stormwater treatment[J]. Journal of Hazardous Materials,2023,445:130632.
    [37]
    LI J,PAN L,LI Z,et al. Unveiling the migration of Cr and Cd to biochar from pyrolysis of manure and sludge using machine learning[J]. Science of The Total Environment,2023,885:163895.
    [38]
    SHAHBEIK H,RAFIEE S,SHAFIZADEH A,et al. Characterizing sludge pyrolysis by machine learning:towards sustainable bioenergy production from wastes[J]. Renewable Energy,2022,199:1078-1092.
    [39]
    KIM J GON,HYUN KIM J,MOON H S,et al. Removal capacity of water plant alum sludge for phosphorus in aqueous solutions[J]. Chemical Speciation& Bioavailability,2002,14(1/2/3/4):67-73.
    [40]
    CUI J F,XU H,SHEN K L,et al. Experiment of adsorption performance of granular waterworks sludge for ammonia nitrogen removal[J]. Water Purification Technology,2017(1):22-26,32. 崔建峰,许航,申昆仑,等. 水厂颗粒污泥吸附水中氨氮的试验[J]. 净水技术,2017(1):22-26,32.
    [41]
    CHENG G,LI Q,SU Z,et al. Preparation,optimization,and application of sustainable ceramsite substrate from coal fly ash/waterworks sludge/oyster shell for phosphorus immobilization in constructed wetlands[J]. Journal of Cleaner Production,2018,175:572-581.
    [42]
    SHEN C,ZHAO Y,LIU R. Development of pellet-type adsorbent based on water treatment residual[J]. Desalination and Water Treatment,2018,112:1-9.
    [43]
    CHEN A,GUAN J,HU R,et al. Enhanced phosphate adsorption studies on several metal-modified aluminum sludge:preparation optimization,adsorption behavior,and mechanistic insight[J]. Environmental Science and Pollution Research,2023,30(19):54628-54643.
    [44]
    HUANG W Y,LI D,LIU Z Q,et al. Kinetics,isotherm,thermodynamic,and adsorption mechanism studies of La(OH)3-modified exfoliated vermiculites as highly efficient phosphate adsorbents[J]. Chemical Engineering Journal,2014,236:191-201.
    [45]
    ZHAO X,ZHANG Y,PAN S,et al. Utilization of gel-type polystyrene host for immobilization of nano-sized hydrated zirconium oxides:a new strategy for enhanced phosphate removal[J]. Chemosphere,2021,263:127938.
    [46]
    IPPOLITO J A,BARBARICK K A,HEIL D M,et al. Phosphorus retention mechanisms of a water treatment residual[J]. Journal of Environmental Quality,2003,32(5):1857-1864.
    [47]
    ADHIKARI R A,KRISHNA K BAL,SARUKKALIGE R. Evaluation of phosphorus adsorption capacity of various filter materials from aqueous solution[J]. Adsorption Science& Technology,2016,34(4/5):320-330.
    [48]
    ELLIOTT H A,O’CONNOR G A,LU P,et al. Influence of water treatment residuals on phosphorus solubility and leaching[J]. Journal of Environmental Quality,2002,31(4):1362-1369.
    [49]
    BAL K K C,NIAZ M R,SARKER D C,et al. Phosphorous removal from aqueous solution can be enhanced through the calcination of lime sludge[J]. Journal of Environmental Management,2017,200:359-365.
    [50]
    FU G,ZHAO Y,ZHOU S,et al. Efficient removal of nitrogen and phosphorus in aqueous solutions using modified water treatment residuals–sodium alginate beads[J]. Environmental Science and Pollution Research,2021,28(34):46233-46246.
    [51]
    GAO J,ZHAO J,ZHANG J,et al. Preparation of a new low-cost substrate prepared from drinking water treatment sludge(DWTS)/bentonite/zeolite/fly ash for rapid phosphorus removal in constructed wetlands[J]. Journal of Cleaner Production,2020,261:121110.
    [52]
    JO J Y,KIM J G,TSANG Y F,et al. Removal of ammonium,phosphate,and sulfonamide antibiotics using alum sludge and low-grade charcoal pellets[J]. Chemosphere,2021,281:130960.
    [53]
    LI S,YAN S,TONG Z,et al. Assessment of photocatalytic activities of layered double hydroxide@petrochemical sludge biochar for sulfamethoxazole degradation[J]. Separation and Purification Technology,2025,355:129732.
    [54]
    LIU Y,MA Y,DENG Z,et al. MoS2 coupled with ball milling co-modified sludge biochar to efficiently activate peroxymonosulfate for neonicotinoids degradation:dominant roles of SO4-·,1O2 and surface-bound radicals[J]. Environmental Research,2024,263:119983.
    [55]
    ABO-EL-ENEIN S A,SHEBL A,EL-DAHAB S A ABO. Drinking water treatment sludge as an efficient adsorbent for heavy metals removal[J]. Applied Clay Science,2017,146:343-349.
    [56]
    DU X,CUI S,FANG X,et al. Adsorption of Cd(II),Cu(II),and Zn(II)by granules prepared using sludge from a drinking water purification plant[J]. Journal of Environmental Chemical Engineering,2020,8(6):104530.
    [57]
    GAO Y,LIANG D,ZHANG Y,et al. Using waste to treat waste:clean production of erdite/zeolite composite flocculant from groundwater treatment sludge for real electroplating wastewater treatment[J]. Clean Technologies and Environmental Policy,2023,25(3):979-995.
    [58]
    BRISO A,TURRI-RIVERO A,MONTECINOS M,et al. Chemical functionalization of drinking water treatment residuals with calcium silicate hydrate to treat metal-enriched waters[J]. Journal of Water Process Engineering,2023,54:103884.
    [59]
    JEON E K,RYU S,PARK S W,et al. Enhanced adsorption of arsenic onto alum sludge modified by calcination[J]. Journal of Cleaner Production,2018,176:54-62.
    [60]
    JO J Y,CHOI J H,TSANG Y F,et al. Pelletized adsorbent of alum sludge and bentonite for removal of arsenic[J]. Environmental Pollution,2021,277:116747.
    [61]
    SHAHIN S A,MOSSAD M,FOUAD M. Evaluation of copper removal efficiency using water treatment sludge[J]. Water Science and Engineering,2019,12(1):37-44.
    [62]
    ZHANG Y P,FAN X T,PENG X S,et al. Study on methylene blue adsorption capacity by iron-rich sludge biochar[J]. Applied Chemical Industry,2022,51(9):2553-2557. 张彦平,范旭腾,彭相仕,等. 富铁污泥生物炭对亚甲基蓝吸附性能的研究[J]. 应用化工,2022,51(9):2553-2557.
    [63]
    CHENG Y L,WANG L,SHI L,et al. Adsorption of methylene blue in water by sludge-rice husk biochar[J]. Textile Auxiliaries,2023,40(4):33-41. 陈永亮,王玲,石磊,等. 污泥-稻壳生物炭对水中亚甲基蓝的吸附[J]. 印染助剂,2023,40(4):33-41.
    [64]
    NAGEEB R M,EL-DAIM EL TAHER M A,FADLALLA S M M. Adsorption of methylene blue using modified adsorbents from drinking water treatment sludge[J]. Water Science and Technology,2016,74(8):1885-1898.
    [65]
    NUANHCHAMNONG C,KOSITKANAWUTH K,WANTANEEYAKUL N. Granular waterworks sludge-biochar composites:characterization and dye removal application[J]. Results in Engineering,2022,14:100451.
    [66]
    LAIB S,REZZAZ-YAZID H,SADAOUI Z. Comparative study on removal of textile dyes in aqueous medium by adsorption using modified drinking water treatment sludge[J]. Arabian Journal for Science and Engineering,2022,47(5):6085-6098.
    [67]
    GRASSI P,FOLETTO E L,DOTTO G L,et al. Application of thermally treated water treatment sludge as a remarkable adsorbent towards emerging pollutant removal from aqueous solution[J]. Water,Air,& Soil Pollution,2021,232(10):397.
    [68]
    TONY M A. Zeolite-based adsorbent from alum sludge residue for textile wastewater treatment[J]. International Journal of Environmental Science and Technology,2020,17(5):2485-2498.
    [69]
    ZHAO C,YIN W,XU J,et al. Removal of tetracycline from water using activated carbon derived from the mixture of phragmites australis and waterworks sludge[J]. ACS Omega,2020,5(6):16045-16052.
    [70]
    WAN J. Magnetic-activated carbon composites derived from iron sludge and biological sludge for sulfonamide antibiotic removal[J]. Environmental Science And Pollution Research,2020.
    [71]
    GAO Y,LIU S,ZHOU Y,et al. Adsorption of fluoride by using sodium alginate coated poly-aluminium chloride(PAC)sludge:preparation,characterisation and mechanism[J]. International Journal of Environmental Analytical Chemistry,2024,104(11):2534-2551.
    [72]
    HE L,CHEN Y,LI Y,et al. Adsorption of Congo red and tetracycline onto water treatment sludge biochar:characterisation,kinetic,equilibrium and thermodynamic study[J]. Water Science and Technology,2022,85(6):1936-1951.
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