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Volume 43 Issue 5
May  2025
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Article Contents
XIANG Xiaofeng, SHAO Yaru, GAO Rongze, WANG Zhichao, JIN Zhonghua, WANG Limin, CHE Defu. Research progress of direct air capture technology for CO2[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(5): 178-191. doi: 10.13205/j.hjgc.202505020
Citation: XIANG Xiaofeng, SHAO Yaru, GAO Rongze, WANG Zhichao, JIN Zhonghua, WANG Limin, CHE Defu. Research progress of direct air capture technology for CO2[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(5): 178-191. doi: 10.13205/j.hjgc.202505020

Research progress of direct air capture technology for CO2

doi: 10.13205/j.hjgc.202505020
  • Received Date: 2024-02-01
  • Accepted Date: 2024-07-09
  • Rev Recd Date: 2024-03-07
  • Available Online: 2025-09-11
  • Direct air capture (DAC) technology has attracted extensive attention in recent years due to its flexible layout, simple operation, and suitability for distributed and point-type carbon emission source capture processes. In order to clarify the DAC technology's application potential in engineering, this paper systematically reviewed the principles and development route of different DAC technologies, summarized the advantages and disadvantages of liquid-based, solid-based, and emerging DAC technologies, analyzed the challenges in their development, and put forward solutions tailored to each technology. The capture materials used in various DAC technologies were briefly reviewed, and the characteristics of these materials in terms of regeneration temperature, renewable energy consumption, and capacity were compared and analyzed. The results showed that the emerging direct air capture technology reduced costs to some extent and was successfully verified in the laboratory. Before large-scale industrial application, issues such as the development of highly selective membrane materials,electrolyzer stability, and the development of efficient electrolyte systems should be solved first.
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  • [1]
    METZ B,DAVIDSON O,CONINCK H,et al. IPCC special report on carbon dioxide capture and storage[M]. Cambridge:Cambridge University Press,2005.
    [2]
    Ministry of Education. The ministry of education issued the"carbon neutral" scientific and technological innovation action plan for higher education[J]. New Energy Science and Technology,2021(9):32-34. 教育部. 教育部发布《高等学校“碳中和”科技创新行动计划》[J]. 新能源科技,2021(9):32-34.
    [3]
    LACKNER K,GRIMES P,ZIOCK H. Capturing carbon dioxide from air[J]. Carbon Capture and Storage:CO2 Management Technologies,1999:364-376.
    [4]
    KEITH D W,HA-DUONG M,STOLAROFF J K. Climate strategy with CO2 capture from the air[J]. Climatic Change,2005,74(1-3):17-45.
    [5]
    SONG Kechen,CUI Xili,XING Huabin. Progress on direct air capture of carbon dioxide[J]. Chemical Industry and Engineering Progress,2022,41(3):1152-1162. 宋珂琛,崔希利,邢华斌. 二氧化碳直接空气捕集材料与技术研究进展[J]. 化工进展,2022,41(3):1152-1162.
    [6]
    DUAN X,SONG G,LU G,et al. Chemisorption and regeneration of amine-based CO2 sorbents in direct air capture[J]. Materials Today Sustainability,2023,23:100453.
    [7]
    HAN S,YOO M,KIM D,et al. Carbon dioxide capture using calcium hydroxide aqueous solution as the absorbent[J]. Energy& Fuels,2011,25(8):3825-3834.
    [8]
    ZEMAN F. Energy and material balance of CO2 capture from ambient air[J]. Environmental Science and Ecotechnology,2007,41:7558-7563.
    [9]
    MAHMOUDKHANI M,HEIDEL K,FERREIRA J,et al. Low energy packed tower and caustic recovery for direct capture of CO2 from air[J]. Energy Procedia,2009,1(1):1535-1542.
    [10]
    SHU Q,LEGRAND L,KUNTKE P,et al. Electrochemical regeneration of spent alkaline absorbent from direct air capture[J]. Environ Sci Technol,2020,54(14):8990-8998.
    [11]
    SABATINO F,MEHTA M,GRIMM A,et al. Evaluation of a direct air capture process combining wet scrubbing and bipolar membrane electrodialysis[J]. Industrial& Engineering Chemistry Research,2020,59(15):7007-7020.
    [12]
    RINBERG A,BERGMAN A,SCHRAG D,et al. Alkalinity concentration swing for direct air capture of carbon dioxide[J]. ChemSusChem,2021,14(20):4439-4453.
    [13]
    ELIMELECH M,PHILLIP W. The future of seawater desalination:energy,technology,and the environment[J]. SCIENCE,2011,333:712-717.
    [14]
    LIU X,LU G,YAN Z. Nanocrystalline zirconia as catalyst support in methanol synthesis[J]. Applied Catalysis A:General,2005,279(1/2):241-245.
    [15]
    Guo X M. Research on Copper-based catalyst for hydrogenation of methanol from carbon dioxide[D]. Shanghai:East China University of Science and Technology,2011. 郭晓明. 二氧化碳加氢合成甲醇铜基催化剂的研究[D]. 上海:华东理工大学,2011.
    [16]
    ALIYU A,AKRAM M,HUGHES K,et al. Investigation into simulating selective exhaust gas recirculation and varying pressurized hot water temperature on the performance of the pilot-scale advanced CO2 capture plant with 40 wt(%)MEA[J]. International Journal of Greenhouse Gas Control,2021,107:103287.
    [17]
    HANUSCH J,KERSCHGENS I,HUBER F,et al. Pyrrolizidines for direct air capture and CO2 conversion[J]. Chemical Communications,2019,55(7):949-952.
    [18]
    BARZAGLI F,GIORGI C,MANI F,et al. Screening study of different amine-based solutions as sorbents for direct CO2 capture from air[J]. ACS Sustainable Chemistry& Engineering,2020,8(37):14013-14021.
    [19]
    LIN Y,MADAN T,ROCHELLE G. Regeneration with rich bypass of aqueous piperazine and monoethanolamine for CO2 capture[J]. Industrial& Engineering Chemistry Research,2014,53(10):4067-7074.
    [20]
    ZHANG S,SHEN Y,WANG L,et al. Phase change solvents for post-combustion CO2 capture:principle,advances,and challenges[J]. Applied Energy,2019,239:876-897.
    [21]
    CUSTELCEAN R,WILLIAMS N,GARRABRANT K,et al. Direct air capture of CO2 with aqueous amino acids and solid Bis-Iminoguanidines(BIGs)[J]. Chem-archive,2019:23338-23346.
    [22]
    CAI H,ZHANG X,LEI L,et al. Direct CO2 capture from air via crystallization with a trichelating iminoguanidine ligand[J]. ACS Omega,2020,5(32):20428-20437.
    [23]
    SANCHEZ-FERNANDEZ E,HEFFERNAN K,VAN DER HAM L,et al. Precipitating amino acid solvents for CO2 capture. opportunities to reduce costs in post combustion capture[J]. Energy Procedia,2014,63:727-738.
    [24]
    WELTON T. Room-temperature ionic liquids. solvents for synthesis and catalysis[J]. Chemical Society Reviews,1999,99:2071-2083.
    [25]
    WILKES J,ZAWOROTKO M. Air and water stable 1-ethyl-3-methylimidazolium based ionic liquids[J]. Journal of the Chemical Society,1992:965-967.
    [26]
    SONG Z,HU X,ZHOU Y,et al. Rational design of double salt ionic liquids as extraction solvents:separation of thiophene/n-octane as example[J]. American Institute of Chemical Engineers,2019,65(8):e16625.
    [27]
    CAPLOW M. Kinetics of carbamate formation and breakdown[J]. Journal of the American Chemical Society,1968(24):6795-6803.
    [28]
    DANCKWERTS P. The reaction of CO2 with ethanolamines[J]. Chemical Engineering Science,1979,34:443-446.
    [29]
    KUMEŁAN J,KAMPS Á,TUMA D,et al. Solubility of CO2 in the ionic liquid[bmim][PF6][J]. Fluid Phase Equilibria,2005,228/229:207-211.
    [30]
    AKI S,MELLEIN B,SAURER E,et al. High-pressure phase behavior of carbon dioxide with imidazolium-based ionic liquids[J]. Journal Of Physical Chemistry B,2004,108:20355-20365.
    [31]
    SHARIATI A,PETERS C. High-pressure phase equilibria of systems with ionic liquids[J]. The Journal of Supercritical Fluids,2005,34(2):171-176.
    [32]
    OLIVIER-BOURBIGOU H,MAGNA L. Ionic liquids:perspectives for organic and catalytic reactions[J]. Journal of Molecular Catalysis A:Chemical,2002,182/ 183:419– 437.
    [33]
    LUO X,GUO Y,DING F,et al. Significant improvements in CO2 capture by pyridine-containing anion-functionalized ionic liquids through multiple-site cooperative interactions[J]. Angewandte Chemie,2014,126(27):7173-7177.
    [34]
    BATES E,MAYTON R,NTAI I,et al. CO2 capture by a task-specific ionic liquid[J]. Journal of the American Chemical Society,2002,124:924-726.
    [35]
    GURKAN B,FUENTE J,MINDRUP E,et al. Equimolar CO2 absorption by anion-functionalized ionic liquids[J]. Journal of the American Chemical Society,2010,132:2116– 2117.
    [36]
    SISTLA Y,KHANNA A. CO2 absorption studies in amino acid-anion based ionic liquids[J]. Chemical Engineering Journal,2015,273:268-276.
    [37]
    GURKAN B,GOODRICH B,MINDRUP E,et al. Molecular design of high capacity,low viscosity,chemically tunable ioonic liquids for CO2 capture[J]. The Journal of Physical Chemistry Letters,2010,1(24):3494-3499.
    [38]
    LI S,ZHAO C,SUN C,et al. Reaction mechanism and kinetics study of CO2 absorption into[C2OHmim][Lys][J]. Energy& Fuels,2016,30(10):8535-8544.
    [39]
    CHEN Y,JIA G,GUOA S,et al. Visible-light-driven conversion of CO2 from air to CO using an ionic liquid and a conjugated polymer[J]. Green Chemistry,2017,19:5777-5781.
    [40]
    MCQUEEN N,GOMES K,MCCORMICK C,et al. A review of direct air capture(DAC):scaling up commercial technologies and innovating for the future[J]. Progress in Energy,2021,3(3):032001.
    [41]
    SABATINO F,GRIMM A,GALLUCCI F,et al. A comparative energy and costs assessment and optimization for direct air capture technologies[J]. Joule,2021,5(8):2047-2076.
    [42]
    BACIOCCHI R,STORTI G,MAZZOTTI M. Process design and energy requirements for the capture of carbon dioxide from air[J]. Chemical Engineering and Processing:Process Intensification,2006,45(12):1047-1058.
    [43]
    CUSTELCEAN R. Direct air capture of CO2 using solvents[J]. Annual Review of Chemical and Biomolecular Engineering,2022,13(1):217-234.
    [44]
    KIANI A,JIANG K,FERON P. Techno-economic assessment for CO2 capture from air using a conventional liquid-based absorption process[J]. Frontiers in Energy Research,2020,8:92.
    [45]
    KIANI A,LEJEUNE M,LI C,et al. Liquefied synthetic methane from ambient CO2 and renewable H2-a technoeconomic study[J]. Journal of Natural Gas Science and Engineering,2021,94:104079.
    [46]
    HOSPITAL-BENITO D,MOYA C,GAZZANI M,et al. Direct air capture based on ionic liquids:from molecular design to process assessment[J]. Chemical Engineering Journal,2023,468:143630.
    [47]
    RANJANI V,SHEN M,FISHER E,et al. Adsorption of CO2 on molecular sieves and activated carbon[J]. Energy& Fuels,2001,15:279-284.
    [48]
    KARIMI M C,SILVA J,GONÇALVES C,et al. CO2 capture in chemically and thermally modified activated carbons using breakthrough measurements:experimental and modeling study[J]. Industrial& Engineering Chemistry Research,2018,57(32):11154-11166.
    [49]
    ABD A,OTHMAN M,KIM J. A review on application of activated carbons for carbon dioxide capture:present performance,preparation,and surface modification for further improvement[J]. Environmental Science and Pollution Research,2021,28(32):43329-43364.
    [50]
    SETHIA G,SAYARI A. Comprehensive study of ultra-microporous nitrogen-doped activated carbon for CO2 capture[J]. Carbon,2015,93:68-80.
    [51]
    KUMAR S,SRIVASTAVA R,KOH J. Utilization of zeolites as CO2 capturing agents:advances and future perspectives[J]. Journal of CO2 Utilization,2020,41(1). DOI: 10.1016/j.jcou.2020.101251.
    [52]
    TOMOYUKI I,OKUGAWA Y,YASUDA M. Relationship between properties of various zeolites and their CO2-adsorption behaviors in pressure swing adsorption operation[J]. Industrial& Engineering Chemistry Research,1988,27:1103-1109.
    [53]
    LI G,XIAO P,WEBLEY P,et al. Competition of CO2/H2O in adsorption based CO2 capture[J]. Energy Procedia,2009,1(1):1123-1130.
    [54]
    MADDEN D,SCOTT H,KUMAR A,et al. Flue-gas and direct-air capture of CO2 by porous metal-organic materials[J]. Philosophical Transactions of the Royal Society A:Mathematical,Physical and Engineering Sciences,2017,375(2084):20160025.
    [55]
    XU X,SONG C,ANDRESEN J,et al. Novel polyethylenimine-modified mesoporous molecular sieve of MCM-41 type as high-capacity adsorbent for CO2 capture[J]. Energy& Fuels,2002,16:1463-1469.
    [56]
    WEN J,GU F,WEI F,et al. One-pot synthesis of the amine-modified meso-structured monolith CO2 adsorbent[J]. Journal of Materials Chemistry,2010,20(14):2840-2846.
    [57]
    GOEPPERT A,METH S,PRAKASH G,et al. Nanostructured silica as a support for regenerable high-capacity organoamine-based CO2 sorbents[J]. Energy& Environmental Science,2010,3(12):1949-1960.
    [58]
    TSUDA T,FUJIWARA T. Polyethyleneimine and macrocyclic polyamine silica gels acting as carbon dioxide absorbents[J]. ChemInform,1993,24(7). DOI: 10.1002/chin.199307296.
    [59]
    BELMABKHOUT Y,SERNA-GUERRERO R,SAYARI A. Amine-bearing mesoporous silica for CO2 removal from dry and humid air[J]. Chemical Engineering Science,2010,65(11):3695-3698.
    [60]
    WURZBACHER J,GEBALD C,STEINFELD A. Separation of CO2 from air by temperature-vacuum swing adsorption using diamine-functionalized silica gel[J]. Energy& Environmental Science,2011,4(9):3584-3592.
    [61]
    AL-ABSI A,DOMIN A,MOHAMEDALI M,et al. CO2 capture using in-situ polymerized amines into pore-expanded-SBA-15:performance evaluation,kinetics,and adsorption isotherms[J]. Fuel,2023,333:126401.
    [62]
    CHAIKITTISILP W,LUNN J,SHANTZ D,et al. Poly(L-lysine)brush-mesoporous silica hybrid material as a biomolecule-based adsorbent for CO2 capture from simulated flue gas and air[J]. Chemistry A European Journal,2011,17(38):10556-10561.
    [63]
    WILFONG W,KAIL B,JONES C,et al. Spectroscopic investigation of the mechanisms responsible for the superior stability of hybrid class 1/class 2 CO2 sorbents:a new class 4 category[J]. ACS Applied Materials& Interfaces,2016,8(20):12780-12791.
    [64]
    KUMAR R,BANDYOPADHYAY M,PANDEY M,et al. Amine-impregnated nanoarchitectonics of mesoporous silica for capturing dry and humid 400 ppm carbon dioxide:a comparative study[J]. Microporous and Mesoporous Materials,2022,338:111956.
    [65]
    ZHU X,GE T,WU J,et al. Modified layered double hydroxides for efficient and reversible carbon dioxide capture from air[J]. Cell Reports Physical Science,2021,2(7).
    [66]
    CHOI S,WATANABE T,BAE T,et al. Modification of the Mg/DOBDC MOF with amines to enhance CO2 adsorption from ultradilute gases[J]. The Journal of Physical Chemistry Letters,2012,3(9):1136-1141.
    [67]
    SKARSTROM C W. Method and apparatus for fractionating gaseous mixtures by adsorption:US71478058A[P]. US 2944627.[ 1960-12-07].
    [68]
    ZHU X,GE T,YANG F,et al. Design of steam-assisted temperature vacuum-swing adsorption processes for efficient CO2 capture from ambient air[J]. Renewable and Sustainable Energy Reviews,2021,137:110651.
    [69]
    LIVELY R,REALFF M. On thermodynamic separation efficiency:adsorption processes[J]. AIChE Journal,2016,62(10):3699-3705.
    [70]
    ELFVING J,BAJAMUNDI C,KAUPPINEN J. Characterization and performance of direct air capture sorbent[J]. Energy Procedia,2017,114:6087-6101.
    [71]
    YU Q,BRILMAN W. A radial flow contactor for ambient air CO2 capture[J]. Applied Sciences,2020,10(3):1080.
    [72]
    DRECHSLER C,AGAR D. Simulation and optimization of a novel moving belt adsorber concept for the direct air capture of carbon dioxide[J]. Computers& Chemical Engineering,2019,126:520-534.
    [73]
    ZHANG Z,XU H,HUA W,et al. Thermodynamics analysis of multi-stage temperature swing adsorption cycle for dilute CO2 capture,enrichment and purification[J]. Energy Conversion and Management,2022,265:115794.
    [74]
    WURZBACHER J,GEBALD C,BRUNNER S,et al. Heat and mass transfer of temperature-vacuum swing desorption for CO2 capture from air[J]. Chemical Engineering Journal,2016,283:1329-1338.
    [75]
    STAMPI-BOMBELLI V,VAN D,MAZZOTTI M. Analysis of direct capture of CO2 from ambient air via steam-assisted temperature–vacuum swing adsorption[J]. Adsorption,2020,26(7):1183-1197.
    [76]
    WANG T,LACKNER K,WRIGHT A. Moisture swing sorbent for carbon dioxide capture from ambient air[J]. Environmental Science& Technology,2011,45(15):6670-6675.
    [77]
    YANG H,SINGH M,SCHAEFER J. Humidity-swing mechanism for CO2 capture from ambient air[J]. Chemical Communications,2018,54(39):4915-4918.
    [78]
    HOU C,WU Y,WANG T,et al. Preparation of quaternized bamboo cellulose and its implication in direct air capture of CO2[J]. Energy& Fuels,2018,33(3):1745-1752.
    [79]
    WANG T,WANG X,HOU C,et al. Quaternary functionalized mesoporous adsorbents for ultra-high kinetics of CO2 capture from air[J]. Scientific Reports,2020,10(1):21429.
    [80]
    VÁZQUEZ F,KOPONEN J,RUUSKANEN V,et al. Power-to-X technology using renewable electricity and carbon dioxide from ambient air:soletair proof-of-concept and improved process concept[J]. Journal of CO2 Utilization,2018,28:235-246.
    [81]
    FASIHI M,EFIMOVA O,BREYER C. Techno-economic assessment of CO2 direct air capture plants[J]. J Clean Prod,2019,224:957-980.
    [82]
    WANG T,DONG H,HOU C L,et al. Review on CO2 adsorbents for direct air capture[J]. Journal of Zhejiang University(Engineering and Technology),2022,56(3):462-475. 王涛,董昊,侯成龙,等. 直接空气捕集CO2吸附剂综述[J]. 浙江大学学报(工学版),2022,56(3):462-475.
    [83]
    LACKNER K. Capture of carbon dioxide from ambient air[J]. The European Physical Journal Special Topics,2009,176(1):93-106.
    [84]
    AGENCY I. Direct air capture a key technology for net zero[M]. OECD Publishing,2022.
    [85]
    FUJIKAWA S,SELYANCHYN R,KUNITAKE T. A new strategy for membrane-based direct air capture[J]. Polymer Journal,2020,53(1):111-119.
    [86]
    SODIQ A,ABDULLATIF Y,AISSA B,et al. A review on progress made in direct air capture of CO2[J]. Environmental Technology& Innovation,2023,29:102991.
    [87]
    CASTEL C,BOUNACEUR R,FAVRE E. Membrane processes for direct carbon dioxide capture from air:possibilities and limitations[J]. Frontiers in Chemical Engineering,2021,3:668867.
    [88]
    CASTRO-MUÑOZ R,ZAMIDI AHMAD M,MALANKOWSKA M,et al. A new relevant membrane application:CO2 direct air capture(DAC)[J]. Chemical Engineering Journal,2022,446:137047:2-13.
    [89]
    MOON S,SHIM J. A novel process for CO2/CH4 gas separation on activated carbon fibers-electric swing adsorption[J]. Journal of Colloid and Interface Science,2006,298(2):523-528.
    [90]
    LEE T,CHO J,CHI S. Carbon dioxide removal using carbon monolith as electric swing adsorption to improve indoor air quality[J]. Building and Environment,2015,92:209-221.
    [91]
    ERBEN J,HEUßNER A,THIELE S,et al. Activation of electrospun carbon fibers:the effect of fiber diameter on CO2 and steam reaction kinetics[J]. Journal of Polymer Research,2021,28(4):1-14.
    [92]
    SEVANTHI R,IRIN F,PARVIZ D,et al. Electrical current stimulated desorption of carbon dioxide adsorbed on graphene based structures[J]. RSC Advances,2016,6(49):43401-43407.
    [93]
    ZHAO Q,WU F,HE Y,et al. Impact of operating parameters on CO2 capture using carbon monolith by electrical swing adsorption technology(ESA)[J]. Chemical Engineering Journal,2017,327:441-453.
    [94]
    ZHAO Q,WU F,MEN Y,et al. CO2 capture using a novel hybrid monolith(H-ZSM5/activated carbon)as adsorbent by combined vacuum and electric swing adsorption(VESA)[J]. Chemical Engineering Journal,2019,358:707-717.
    [95]
    GRANDE C,RIBEIRO R,RODRIGUES A. CO2 capture from NGCC power stations using electric swing adsorption(ESA)[J]. Energy& Fuels,2009,23:2797-2803.
    [96]
    BIEL-NIELSEN T,HATTON T,VILLADSEN S,et al. Electrochemistry-based CO2 removal technologies[J]. Chem Sus Chem,2023,16(11):e202202345.
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