Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 43 Issue 10
Oct.  2025
Turn off MathJax
Article Contents
ZHAO Yiqi, WANG Dongbin, LI Zhiyuan, CHEN Yan, DENG Jianguo, JIANG Jingkun. Current status and prospects of amine escape monitoring technology for carbon capture units[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(10): 95-102. doi: 10.13205/j.hjgc.202510011
Citation: ZHAO Yiqi, WANG Dongbin, LI Zhiyuan, CHEN Yan, DENG Jianguo, JIANG Jingkun. Current status and prospects of amine escape monitoring technology for carbon capture units[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(10): 95-102. doi: 10.13205/j.hjgc.202510011

Current status and prospects of amine escape monitoring technology for carbon capture units

doi: 10.13205/j.hjgc.202510011
  • Received Date: 2025-03-07
  • Accepted Date: 2025-04-11
  • Rev Recd Date: 2025-04-09
  • Available Online: 2025-12-03
  • Publish Date: 2025-10-01
  • Stationary sources are the major anthropogenic emitters of carbon dioxide in China, making carbon emission reduction from stationary sources a key strategy for achieving China’s Dual Carbon goals. Amine absorption-based carbon capture systems are currently the most widely used technology for CO2 emissions control from stationary sources and are gradually promoted globally. The escape of amines and their degradation products with flue gas is a concern for this technology. Studies have shown that the concentration of escaped amine can reach levels as high as several tens μg/m3, which not only increases the operating cost of carbon capture systems but also poses potential risks to environmental quality and human health. At present, the understanding of amine emissions from stationary sources is still relatively limited. One of the main reasons is the lack of amine emission limit and monitoring technology specifications, which hinders in-depth understanding and regulatory oversight of amine escape. This paper reviews the current monitoring technologies for amine escape from stationary sources, including offline sampling and analysis technology, as well as online monitoring technologies such as Fourier Transform infrared spectroscopy (FTIR) and proton transfer reaction mass spectrometry (PTR-MS), covering their basic principles and application status. We also discussed the applicability of these technologies in monitoring amine emissions in light of current monitoring needs and provided an outlook on future development of related novel technologies.
  • loading
  • [1]
    FRIEDLINGSTEIN P,O'SULLIVAN M,JONES M W,et al. Global carbon budget 2024[J]. Earth System Science Data,2024,16(4):1917-1971.
    [2]
    LAN X,TANS P,THONING K W. Trends in globally-averaged CO2 determined from NOAA Global Monitoring Laboratory measurements[EB/OL].(2025-01-06)[ 2025-04-01]. https://gml.noaa.gov/ccgg/trends/global.html.
    [3]
    XU R,TONG D,XIAO Q,et al. MEIC-global-CO2:a new global CO2 emission inventory with highly-resolved source category and sub-country information[J]. Science China Earth Sciences,2024,67(2):450-465.
    [4]
    BABU P,DARABOINA N. A systematic review of recent advances in hydrate technology for precombustion carbon capture[J]. Journal of Environmental Chemical Engineering,2024,12(5):111732.
    [5]
    DAVISON J,THAMBIMUTHU K. An overview of technologies and costs of carbon dioxide capture in power generation[J]. Proceedings of the Institution of Mechanical Engineers Part A-Journal of Power and Energy,2009,223(3):201-212.
    [6]
    LIANG Z W,FU K Y,IDEM R,et al. Review on current advances,future challenges and consideration issues for post-combustion CO2 capture using amine-based absorbents[J]. Chinese Journal of Chemical Engineering,2016,24(2):278-288.
    [7]
    WANG M,LAWAL A,STEPHENSON P,et al. Post-combustion CO2 capture with chemical absorption:a state-of-the-art review[J]. Chemical Engineering Research & Design,2011,89(9):1609-1624.
    [8]
    AKEEB O,WANG L,XIE W G,et al. Post-combustion CO2 capture via a variety of temperature ranges and material adsorption process:a review[J]. Journal of Environmental Management,2022,313:115020.
    [9]
    KHALILPOUR R,MUMFORD K,ZHAI H B,et al. Membrane-based carbon capture from flue gas:a review[J]. Journal of Cleaner Production,2015,103:286-300.
    [10]
    COUSINS A,WARDHAUGH L,COTTRELL A. Pilot plant operation for liquid absorption-based post-combustion CO2 capture[C]// Absorption-Based Post-Combustion Capture of Carbon Dioxide. Feron P H M(Ed.). Amsterdam:Elsevier,2016:649-684.
    [11]
    MENG F Z,MENG Y,JU T Y,et al. Research progress of aqueous amine solution for CO2 capture:a review[J]. Renewable & Sustainable Energy Reviews,2022,168:112732.
    [12]
    WEIR H,SANCHEZ-FERNANDEZ E,CHARALAMBOUS C,et al. Impact of high capture rates and solvent and emission management strategies on the costs of full-scale post-combustion CO2 capture plants using long-term pilot plant data[J]. International Journal of Greenhouse Gas Control,2023,126:103863.
    [13]
    GE X L,WEXLER A S,CLEGG S L. Atmospheric amines-Part I. A review. Atmospheric Environment,2011,45(3):524-546.
    [14]
    WHITE S,ANGOVE D,AZZI M,et al. An experimental investigation into the atmospheric degradation of piperazine[J]. Atmospheric Environment,2015,108:133-139.
    [15]
    MCDONALD J D,KRACKO D,DOYLE-EISELE M,et al. Carbon capture and sequestration:an exploratory inhalation toxicity assessment of amine-trapping solvents and their degradation products[J]. Environmental Science & Technology,2014,48(18):10821-10828.
    [16]
    VVELTMAN K,SINGH B,HERTWICH E G. Human and environmental impact assessment of post-combustion CO2 capture focusing on emissions from amine-based scrubbing solvents to air[J]. Environmental Science & Technology,2010,44(4):1496-1502.
    [17]
    GAO W L,LIANG S Y,WANG R J,et al. Industrial carbon dioxide capture and utilization:state of the art and future challenges[J]. Chemical Society Reviews,2020,49(23):8584-8686.
    [18]
    DUBOIS L,LARIBI S,MOUHOUBI S,et al. Study of the post-combustion CO2 capture applied to conventional and partial oxy-fuel cement plants[C]// 13th International Conference on Greenhouse Gas Control Technologies(GHGT). Lausanne:IEA GHGT,2016.
    [19]
    CHOWDHURY F A,OKABE H,YAMADA H,et al. Synthesis and selection of hindered new amine absorbents for CO2 capture[C]// 10th International Conference on Greenhouse Gas Control Technologies(GHGT). Amsterdam:IEA GHGT,2010..
    [20]
    MA'MUN S,SVENDSEN H F,HOFF K A,et al. Selection of new absorbents for carbon dioxide capture[J]. Energy Conversion and Management,2007,48(1):251-258.
    [21]
    XIAO L Y,QIU Z J,FENG S,et al. Carbon dioxide absorption and desorption experiments based on MDEA[J]. Chemical Engineering and Processing-Process Intensification,2024,203:109646.
    [22]
    HENG S Q,YU J,YANG Y L,et al. Application progress of absorbents in carbon capture process[J]. China Petroleum and Chemical Industry,2024,(10):81-83. 衡世权,喻江,杨用龙,等. 碳捕集工艺中吸收剂的应用进展[J]. 中国石油和化工,2024,(10):81-83.
    [23]
    CHAI S Y W,NGU L H,HOW B S. Review of carbon capture absorbents for CO2 utilization[J]. Greenhouse Gases-Science and Technology,2022,12(3):394-427.
    [24]
    ZHANG S,ZHI X,SHI X C,et al. Research progress of organic amine-based CO2 capture absorbents[J]. Applied Chemical Industry,2024,53(1):172-177. 张帅,郅晓,石信超,等. 有机胺类 CO2 捕集吸收剂研究进展[J]. 应用化工,2024,53(1):172-177.
    [25]
    REYNOLDS A J,VERHEYEN T V,MEULEMAN E. Degradation of amine-based solvents[C]// Absorption-Based Post-Combustion Capture of Carbon Dioxide. Feron P H M(Ed.). Amsterdam:Elsevier,2016:399-423.
    [26]
    NEERUP R,RASMUSSEN V E,VINJARAPU S H B,et al. Solvent degradation and emissions from a CO2 capture pilot at a waste-to-energy plant[J]. Journal of Environmental Chemical Engineering,2023,11(6):110918.
    [27]
    KHAKHARIA P,KVAMSDAL H M,SILVA E F DA,et al. Field study of a brownian demister unit to reduce aerosol-based emission from a post-combustion CO2 capture plant[J]. International Journal of Greenhouse Gas Control,2014,28:57-64.
    [28]
    da SILVA E F,KOLDERUP H,GOETHEER E,et al. Emission studies from a CO2 capture pilot plant[C]// International Conference on Greenhouse Gas Technologies(GHGT). Kyoto:IEA GHGT,2012.
    [29]
    THOMPSON J G,COMBS M,ABAD K,et al. Pilot testing of a heat integrated 0.7 MWe CO2 capture system with two-stage air-stripping:Emission[J]. International Journal of Greenhouse Gas Control,2017,64:267-275.
    [30]
    MOSER P,WIECHERS G,SCHMIDT S,et al. ALIGN-CCUS:Results of the 18-month test with aqueous AMP/PZ solvent at the pilot plant at Niederaussem-solvent management,emissions,and dynamic behavior[J]. International Journal of Greenhouse Gas Control,2021,109:103386.
    [31]
    KHAKHARIA P,HUIZINGA A,LOPEZ C J,et al. Acid wash scrubbing as a countermeasure for ammonia emissions from a postcombustion CO2 capture plant[J]. Industrial & Engineering Chemistry Research,2014,53(33):13195-13204.
    [32]
    MOSER P,WIECHERS G,SCHMIDT S,et al. Results of the 18-month test with MEA at the post-combustion capture pilot plant at Niederaussem-new impetus to solvent management,emissions,and dynamic behaviour[J]. International Journal of Greenhouse Gas Control,2020,95:103080.
    [33]
    ROCHELLE G T,AKINPELUMI K,GAO T Y,et al. Pilot plant results with the piperazine advanced stripper at NGCC conditions[J]. International Journal of Greenhouse Gas Control,2022,113:103660.
    [34]
    KNUDSEN J N,BADE O M,ASKESTAD I,et al. Pilot plant demonstration of CO2 capture from cement plant with advanced amine technology[C]// 12th International Conference on Greenhouse Gas Control Technologies(GHGT). Austin:IEA GHGT,2014.
    [35]
    ZHU L,SCHADE G W,NIELSEN C J. Real-time monitoring of emissions from monoethanolamine-based industrial scale carbon capture facilities[J]. Environmental Science & Technology,2013,47(24):14306-14314.
    [36]
    MORKEN A K,PEDERSEN S,KLEPPE E R,et al. Degradation and emission results of amine plant operations from MEA testing at the CO2 Technology Centre Mongstad[C]// 13th International Conference on Greenhouse Gas Control Technologies(GHGT). Lausanne:IEA GHGT,2013.
    [37]
    MERTENS J,KNUDSEN J,THIELENS M L,et al. On-line monitoring and controlling emissions in amine post-combustion carbon capture:a field test[J]. International Journal of Greenhouse Gas Control,2012,6:2-11..
    [38]
    LI Z P,WU X Y. Comparison of sampling methods for volatile organic compounds in air and waste gas[J]. Guangdong Chemical Industry,2017,44(8):167. 李作平,吴晓燕. 空气和废气中挥发性有机物采样方法比较[J]. 广东化工,2017,44(8):167.
    [39]
    XIAO M,LIU H L,GAO H X,et al. CO2 capture with hybrid absorbents of low viscosity imidazolium-based ionic liquids and amine[J]. Applied Energy,2019,235:311-319.
    [40]
    SHAO X,LI G A,REN P F,et al. Storage stability of typical volatile organic compounds in gas sampling canisters[J]. Environmental Protection of Chemical Industry,2017,37(1):116-120. 邵霞,李国傲,任培芳,等. 典型挥发性有机化合物在气体采样罐中的存储稳定性[J]. 化工环保,2017,37(1):116-120.
    [41]
    LIU J,WANG T,CHENG J,et al. Distribution of organic compounds in coal-fired power plant emissions[J]. Energy & Fuels,2019,33(6):5430-5437.
    [42]
    YOU X,GU S,ZHANG F,et al. Portable catalytic oxidation FID method for determination of non-methane hydrocarbons in exhaust gas from stationary source[J]. The Administration and Technique of Environmental Monitoring,2022,34(4):53-56.
    [43]
    KHAKHARIA P,BRACHERT L,MERTENS J,et al. Investigation of aerosol-based emission of MEA due to sulphuric acid aerosol and soot in a Post Combustion CO2 Capture process[J]. International Journal of Greenhouse Gas Control,2013,19:138-144.
    [44]
    KHAKHARIA P,BRACHERT L,MERTENS J,et al. Understanding aerosol-based emissions in a Post Combustion CO2 Capture process:Parameter testing and mechanisms[J]. International Journal of Greenhouse Gas Control,2015,34:63-74.
    [45]
    YAO L,WANG M Y,WANG X K,et al. Detection of atmospheric gaseous amines and amides by a high-resolution time-of-flight chemical ionization mass spectrometer with protonated ethanol reagent ions[J]. Atmospheric Chemistry and Physics,2016,16(22):14527-14543.
    [46]
    WANG Y W,YANG G,LU Y Q,et al. Detection of gaseous dimethylamine using vocus proton-transfer-reaction time-of-flight mass spectrometry[J]. Atmospheric Environment,2020,243:117810.
    [47]
    SIMON M,HEINRITZI M,HERZOG S,et al. Detection of dimethylamine in the low PPTV range using nitrate chemical ionization atmospheric pressure interface time-of-flight(CI-APi-TOF)mass spectrometry[J]. Atmospheric Measurement Techniques,2016,9(5):2135-2145.
    [48]
    DANG M,LIU R D,DONG F S,et al. Vacuum ultraviolet photoionization on-line mass spectrometry:Instrumentation developments and applications[J]. Trends in Analytical Chemistry,2022,149:116664.
    [49]
    MERTENS J,LEPAUMIER H,DESAGHER D,et al. Understanding ethanolamine(MEA)and ammonia emissions from amine-based post-combustion carbon capture:Lessons learned from field tests[J]. International Journal of Greenhouse Gas Control,2013,13:72-77.
    [50]
    FULK S M,ROCHELLE G T. Quantification of gas and aerosol-phase piperazine emissions by FTIR under variable bench-scale absorber conditions[C]// 12th International Conference on Greenhouse Gas Control Technologies(GHGT). Austin:IEA GHGT,2014.
    [51]
    XIE X,HAN Y,QIN C. Determination of non-methane total hydrocarbon in exhaust gas from stationary source based on portable hydrogen flame ionization detector[J]. Environmental Monitoring in China,2020,36(1):120-124.
    [52]
    AZZI M,ANGOVE D,DAVE N,et al. Emissions to the atmosphere from amine-based post combustion CO2 capture plant-regulatory aspects[J]. Oil & Gas Science and Technology-Revue de l'Ifp Energies Nouvelles,2014,69(5):793-803.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (6) PDF downloads(0) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return