Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 43 Issue 10
Oct.  2025
Turn off MathJax
Article Contents
YI Tianli, TIAN Juntai, LIU Yue, NIE Zimeng, WANG Ziwei, ZHAO Xiaoya, QIAO Feiyang, YE Daiqi. Review of catalytic oxidation technology of volatile organic compounds from the perspective of energy consumption[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(10): 112-120. doi: 10.13205/j.hjgc.202510013
Citation: YI Tianli, TIAN Juntai, LIU Yue, NIE Zimeng, WANG Ziwei, ZHAO Xiaoya, QIAO Feiyang, YE Daiqi. Review of catalytic oxidation technology of volatile organic compounds from the perspective of energy consumption[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(10): 112-120. doi: 10.13205/j.hjgc.202510013

Review of catalytic oxidation technology of volatile organic compounds from the perspective of energy consumption

doi: 10.13205/j.hjgc.202510013
  • Received Date: 2024-12-23
  • Accepted Date: 2025-02-06
  • Rev Recd Date: 2025-01-21
  • Available Online: 2025-12-03
  • Publish Date: 2025-10-01
  • Under the background of the Dual-Carbon Goals, the catalytic oxidation of volatile organic compounds (VOCs) with high efficiency, economy, and low-energy-consumption is a big demand in China. This review focuses on the energy consumption of thermal and non-thermal catalytic oxidation technologies of VOCs, summarizes the energy consumption characteristics of thermal catalytic oxidation of aromatic hydrocarbons, aliphatic hydrocarbons, oxygenated VOCs, and chlorine-containing, nitrogen-containing, and sulfur-containing VOCs, and provides an overview of the energy consumption of non-thermal catalytic oxidation technologies, such as plasma-catalytic oxidation, photocatalytic oxidation, photothermal catalytic oxidation, and ozone-catalytic oxidation. The results show that it is difficult to achieve room temperature catalytic combustion for chlorine-containing, nitrogen-containing, and sulfur-containing VOCs, and researchers should focus on improving product selectivity and avoiding the generation of toxic by-products. The catalytic combustion temperature of aromatic hydrocarbons is still far beyond the room temperature, and the catalytic combustion of oxygenated VOCs and aliphatic hydrocarbons are expected to achieve low temperature or near room temperature catalytic combustion in the future. Thermal catalytic oxidations have the lowest average specific molar energy consumption, compared with different non-thermal catalytic oxidations. Thermal catalytic oxidation technology is still the mainstream technology for the industrial destruction of VOCs in the future, and non-thermal catalytic oxidation technology will occupy a place, because of its unique advantages in specific scenarios.
  • loading
  • [1]
    MCFIGGANS G,MENTEL T F,WILDT J,et al. Secondary organic aerosol reduced by mixture of atmospheric vapours[J]. Nature,2019,565(7741):587-593.
    [2]
    REN Y,DONG C,SONG C,et al. Spinel-based catalysts that enable catalytic oxidation of volatile organic compounds[J]. Environmental Science & Technology,2024,58(47):20785-20811.
    [3]
    LU T,ZHANG C,Du F,et al. Mutual inhibition effects on the synchronous conversion of benzene,toluene,and xylene over MnOx catalysts[J]. Journal of Colloid and Interface Science,2023,641:791-802.
    [4]
    LI M,ZHANG W,ZHANG X,et al. Influences of different surface oxygen species on oxidation of toluene and/or benzene and their reaction pathways over Cu-Mn metal oxides[J]. Journal of Colloid and Interface Science,2023,630:301-316.
    [5]
    YUAN J,LI G,LIU X,et al. Catalytic oxidation of BTX(benzene,toluene,and xylene)using metal oxide perovskites[J]. Advanced Functional Materials,2024,34(36):2401281.
    [6]
    GUO Y,WEN M,LI G,et al. Recent advances in VOC elimination by catalytic oxidation technology onto various nanoparticles catalysts:a critical review[J]. Applied Catalysis B:Environmental,2021,281:119447.
    [7]
    TANG W,XIAO W,WANG S,et al. Boosting catalytic propane oxidation over PGM-free Co3O4 nanocrystal aggregates through chemical leaching:A comparative study with Pt and Pd based catalysts[J]. Applied Catalysis B:Environmental,2018,226:585-595.
    [8]
    HARTIKAINEN A,YLI-PIRILÄ P,TIITTA P,et al. Volatile organic compounds from logwood combustion:emissions and transformation under dark and photochemical aging conditions in a smog chamber[J]. Environmental Science & Technology,2018,52(8):4979-4988.
    [9]
    FANG Y,LI L,YANG J,et al. Engineering the nucleophilic active oxygen species in CuTiO x for efficient low-temperature propene combustion[J]. Environmental Science & Technology,2020,54(23):15476-15488.
    [10]
    LIU G,MA X,LI W,et al. Pollution characteristics,source appointment and environmental effect of oxygenated volatile organic compounds in Guangdong-Hong Kong-Macao Greater Bay Area:implication for air quality management[J]. Science of the Total Environment,2024,919:170836.
    [11]
    MO Z,HUANG S,YUAN B,et al. Tower-based measurements of NMHCs and OVOCs in the Pearl River delta:vertical distribution,source analysis and chemical reactivity[J]. Environmental Pollution,2022,292:118454.
    [12]
    LI J,XIE X,LI L,et al. Fate of oxygenated volatile organic compounds in the Yangtze River delta region:source contributions and impacts on the atmospheric oxidation capacity[J]. Environmental Science & Technology,2022,56(16):11212-11224.
    [13]
    ZHANG K,DING H,PAN W,et al. Research progress of a composite metal oxide catalyst for VOC degradation[J]. Environmental Science & Technology,2022,56(13):9220-9236.
    [14]
    HE D,HAO H,CHEN D,et al. Effects of rare-earth(Nd,Er and Y)doping on catalytic performance of HZSM-5 zeolite catalysts for methyl mercaptan(CH3SH)decomposition[J]. Applied Catalysis A:General,2017,533:66-74.
    [15]
    YANY C,MIAO G,PI Y,et al. Abatement of various types of VOCs by adsorption/catalytic oxidation:A review[J]. Chemical Engineering Journal,2019,370:1128-1153.
    [16]
    WANG S H. Petrochemical engineering design handbook. Volume 1:Basic data for petrochemical engineering[M]. Beijing:Chemical Industry Press,2002. 王松汉,石油化工设计手册. 第1卷,石油化工基础数据[M]. 北京:化学工业出版社,2002.
    [17]
    SU Z,LI X,SI W,et al. Probing the actual role and activity of oxygen vacancies in toluene catalytic oxidation:evidence from in situ XPS/NEXAFS and DFT + U calculation[J]. ACS Catalysis,2023,13(6):3444-3455.
    [18]
    LU A,SUN H,ZHANG N,et al. Surface partial-charge-tuned enhancement of catalytic activity of platinum nanocatalysts for toluene oxidation[J]. ACS Catalysis,2019,9(8):7431-7442.
    [19]
    SU Z,YANG W,WANG C,et al. Roles of oxygen vacancies in the bulk and surface of CeO2 for toluene catalytic combustion[J]. Environmental Science & Technology,2020,54(19):12684-12692.
    [20]
    SHEN Y,DENG J,IMPENG S,et al. Boosting toluene combustion by engineering Co-O strength in cobalt oxide catalysts[J]. Environmental Science & Technology,2020,54(16):10342-10350.
    [21]
    HAN W,DONG F,HAN W,et al. A new strategy for designing highly efficient Co3O4 catalyst with the molecular space configurations for toluene catalytic combustion[J]. Chemical Engineering Journal,2022,435:134953.
    [22]
    DENG H,KANG S,MA J,et al. Silver incorporated into cryptomelane-type manganese oxide boosts the catalytic oxidation of benzene[J]. Applied Catalysis B:Environmental,2018,239:214-222.
    [23]
    ZHANG X,LI M,CUI X,et al. Enhancing catalytic activity for toluene and acetone oxidation over Zr a Co1- a O x catalysts by doping Zr to improve the oxygen activation capacity due to formation of Zr-O-Co bonds[J]. Chemical Engineering Journal,2023,465:142857.
    [24]
    LUO M,CHENG Y,PENG X,et al. Copper modified manganese oxide with tunnel structure as efficient catalyst for low-temperature catalytic combustion of toluene[J]. Chemical Engineering Journal,2019,369:758-765.
    [25]
    PEI W,LIU Y,DENG J,et al. Partially embedding Pt nanoparticles in the skeleton of 3DOM Mn2O3:an effective strategy for enhancing catalytic stability in toluene combustion[J]. Applied Catalysis B:Environmental,2019,256:117814.
    [26]
    CHEN X,CHEN X,CAI S,et al. Catalytic combustion of toluene over mesoporous Cr2O3-supported platinum catalysts prepared by in situ pyrolysis of MOFs[J]. Chemical Engineering Journal,2018,334:768-779.
    [27]
    DONG F,MENG Y,LING W,et al. Single atomic Pt confined into lattice defect sites for low-temperature catalytic oxidation of VOCs[J]. Applied Catalysis B:Environment and Energy,2024,346:123779.
    [28]
    LIU X,LÜ X,WANG Y,et al. Effect of calcination process on performance of 3DOM CeMnO3 catalysts[J]. Journal of Rare Earths,2021,39(9):1073-1081.
    [29]
    LIU Y,DAI H,DENG J,et al. Au/3DOM La0.6Sr0.4MnO3:highly active nanocatalysts for the oxidation of carbon monoxide and toluene[J]. Journal of Catalysis,2013,305:146-153.
    [30]
    TARJOMANNEJAD A,FARZI A,NIARI A,et al. An experimental and kinetic study of toluene oxidation over LaMn1- xBx O3 and La0.8 A0.2Mn0.3 B0.7O3A=Sr,Ce and B=Cu,Fe)nano-perovskite catalysts[J]. Korean Journal of Chemical Engineering,2016,33(9):2628-2637.
    [31]
    LI X,CHEN D,LI N,et al. Highly efficient Pd catalysts loaded on La1-xSrxMnO3 perovskite nanotube support for low-temperature toluene oxidation[J]. Journal of Alloys and Compounds,2021,871:159575.
    [32]
    LOSCH P,HUANG W,VOZNIUK O,et al. Modular Pd/zeolite composites demonstrating the key role of support hydrophobic/hydrophilic character in methane catalytic combustion[J]. ACS Catalysis,2019,9(6):4742-4753.
    [33]
    FARRAUTO R J. Low-temperature oxidation of methane[J]. Science,2012,337(6095):659-660.
    [34]
    YU X,GENZ N S,MENDES R G,et al. Anchoring PdO x clusters on defective alumina for improved catalytic methane oxidation[J]. Nature Communications,2024,15(1):6494.
    [35]
    ZHANG T,LANG X,DONG A,et al. Difference of oxidation mechanism between light C3–C4 alkane and alkene over mullite YMn2O5 oxides’ catalyst[J]. ACS Catalysis,2020,10(13):7269-7282.
    [36]
    FANG Y,LI H,ZHANG Q,et al. Oxygen vacancy-governed opposite catalytic performance for C3H6 and C3H8 combustion:the effect of the Pt electronic structure and chemisorbed oxygen species[J]. Environmental Science & Technology,2022,56(5):3245-3257.
    [37]
    HUANG Z,DING J,YANG X,et al. Highly efficient oxidation of propane at low temperature over a Pt-based catalyst by optimization support[J]. Environmental Science & Technology,2022,56(23):17278-17287.
    [38]
    THRANE J,KULD S,NIELSEN N D,et al. Methanol-assisted autocatalysis in catalytic methanol synthesis[J]. Angewandte Chemie International Edition,2020,59(41):18189-18193.
    [39]
    YANG J,LIU Y,DENG J,et al. AgAuPd/meso-Co3O4:high-performance catalysts for methanol oxidation[J]. Chinese Journal of Catalysis,2019,40(6):837-848.
    [40]
    JIA H,XING Y,ZHANG L,et al. Progress of catalytic oxidation of typical chlorinated volatile organic compounds(CVOCs):a review[J]. Science of the Total Environment,2023,865:161063.
    [41]
    SU Y,FU K,PANG C,et al. Recent advances of chlorinated volatile organic compounds’ oxidation catalyzed by multiple catalysts:reasonable adjustment of acidity and redox properties[J]. Environmental Science & Technology,2022,56(14):9854-9871.
    [42]
    DAI Q,WANG W,WANG X,et al. Sandwich-structured CeO2@ZSM-5 hybrid composites for catalytic oxidation of 1,2-dichloroethane:an integrated solution to coking and chlorine poisoning deactivation[J]. Applied Catalysis B:Environmental,2017,203:31-42.
    [43]
    LIU H,MA Y,CHEN J,et al. Highly efficient visible-light-driven photocatalytic degradation of VOCs by CO2-assisted synthesized mesoporous carbon confined mixed-phase TiO2 nanocomposites derived from MOFs[J]. Applied Catalysis B:Environmental,2019,250:337-346.
    [44]
    CHEN G,WANG Z,LIN F,et al. Comparative investigation on catalytic ozonation of VOCs in different types over supported MnO x catalysts[J]. Journal of Hazardous Materials,2020,391:122218.
    [45]
    VAN D J,DEWULF J,LEYS C,et al. Combining non-thermal plasma with heterogeneous catalysis in waste gas treatment:a review[J]. Applied Catalysis B:Environmental,2008,78(3):324-333.
    [46]
    QU M,CHENG Z,SUN Z,et al. Non-thermal plasma coupled with catalysis for VOCs abatement:a review[J]. Process Safety and Environmental Protection,2021,153:139-158.
    [47]
    DEBONO O,HEQUET V,LE C L,et al. VOC ternary mixture effect on ppb level photocatalytic oxidation:removal kinetic,reaction intermediates and mineralization[J]. Applied Catalysis B:Environmental,2017,218:359-369.
    [48]
    LI J,CUI W,CHEN P,et al. Unraveling the mechanism of binary channel reactions in photocatalytic formaldehyde decomposition for promoted mineralization[J]. Applied Catalysis B:Environmental,2020,260:118130.
    [49]
    LU Y,WANG D,MA C,et al. The effect of activated carbon adsorption on the photocatalytic removal of formaldehyde[J]. Building and Environment,2010,45(3):615-621.
    [50]
    SHAN A Y,GHAZI T I M,Rashid S A. Immobilisation of titanium dioxide onto supporting materials in heterogeneous photocatalysis:a review[J]. Applied Catalysis A:General,2010,389(1):1-8.
    [51]
    LI J,LÜ X,WENG B,et al. Engineering light propagation for synergetic photo-and thermocatalysis toward volatile organic compounds elimination[J]. Chemical Engineering Journal,2023,461:142022.
    [52]
    KONG J,JIANG C,RUI Z,et al. Photothermocatalytic synergistic oxidation:An effective way to overcome the negative water effect on supported noble metal catalysts for VOCs oxidation[J]. Chemical Engineering Journal,2020,397:125485.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (7) PDF downloads(0) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return