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Volume 43 Issue 11
Nov.  2025
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Article Contents
YANG Yifan, YI Yuanrong, ABUDUPUL Asguri, GAO Xiang, MA Shuo, LIU Yitong. Separation of non-ferrous iron from copper smelting slag and preparation of iron oxide yellow pigment[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(11): 179-186. doi: 10.13205/j.hjgc.202511020
Citation: YANG Yifan, YI Yuanrong, ABUDUPUL Asguri, GAO Xiang, MA Shuo, LIU Yitong. Separation of non-ferrous iron from copper smelting slag and preparation of iron oxide yellow pigment[J]. ENVIRONMENTAL ENGINEERING , 2025, 43(11): 179-186. doi: 10.13205/j.hjgc.202511020

Separation of non-ferrous iron from copper smelting slag and preparation of iron oxide yellow pigment

doi: 10.13205/j.hjgc.202511020
  • Received Date: 2024-12-26
  • Accepted Date: 2025-02-26
  • Rev Recd Date: 2025-02-01
  • Available Online: 2026-01-09
  • The annual output of copper smelting slag in the world exceeds 50 million tons, and stacking is the current mainstream copper smelting slag treatment method, which causes the risk of heavy metal overflow and potential environmental pollution. In this paper, non-ferrous iron was extracted from copper smelting slag by sulfuric acid leaching to prepare ferrous sulfate solution, and then iron oxide yellow pigment was prepared by air oxidation. The influence of key parameters, such as leaching liquid concentration, air flow, temperature, treating time, raw material particle size and crystal seed addition was investigated by the experiments. The results showed that when the leaching temperature was set at 95 ℃, the leaching time was 2 hours, and the liquid-solid ratio was 5∶1, the leaching efficiency of iron in copper smelting slag was as high as 96.5%. When the ratio of crystal to seed was 33%, the oxidation time was 50 h, the air volume was 0.8 m3/h, and the terminal pH value was adjusted to 3.5, the content of Fe2O3 in the prepared iron oxide yellow pigment reached 86.4%. This process has the advantages of wide availability of raw materials and simple experimental operation, and provides a new utilization path for copper smelting slag.
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