Source Jouranl of CSCD
Source Journal of Chinese Scientific and Technical Papers
Included as T2 Level in the High-Quality Science and Technology Journals in the Field of Environmental Science
Core Journal of RCCSE
Included in the CAS Content Collection
Included in the JST China
Indexed in World Journal Clout Index (WJCI) Report
Volume 44 Issue 5
May  2026
Turn off MathJax
Article Contents
ZHANG Shirui, LI Xianglei, SONG Huiping, FAN Zhenlian, CHENG Shuyan, JIN Dapeng, ZOU Yan. Preparation of BiOX visible-light photocatalytic materials and optimization of their NO degradation performance[J]. ENVIRONMENTAL ENGINEERING , 2026, 44(5): 161-170. doi: 10.13205/j.hjgc.202605016
Citation: ZHANG Shirui, LI Xianglei, SONG Huiping, FAN Zhenlian, CHENG Shuyan, JIN Dapeng, ZOU Yan. Preparation of BiOX visible-light photocatalytic materials and optimization of their NO degradation performance[J]. ENVIRONMENTAL ENGINEERING , 2026, 44(5): 161-170. doi: 10.13205/j.hjgc.202605016

Preparation of BiOX visible-light photocatalytic materials and optimization of their NO degradation performance

doi: 10.13205/j.hjgc.202605016
  • Received Date: 2025-04-28
    Available Online: 2026-06-06
  • BiOXX = Cl, Br, I) photocatalytic materials were prepared by a chemical precipitation method. Their structures and properties were characterized using scanning electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, nitrogen adsorption-desorption, and ultraviolet-visible diffuse reflectance spectroscopy. The results showed that BiOBr possesses a flower-like nanomicrosphere structure composed of nanosheets, which gives it a more three-dimensional morphology, a larger specific surface area, and a moderate light absorption range, resulting in superior visible light absorption. Consequently, BiOBr exhibited the best photocatalytic degradation of NO under xenon lamp irradiation. In addition, this study investigated the effects of light intensity, NO flow rate, and oxygen concentration on the NO degradation performance of BiOBr. The experimental results showed that the optimal NO removal rate of 58% was achieved under the conditions of a light source distance of 15 cm, an NO flow rate of 15 mL/min, and in the presence of oxygen. These findings provide an important experimental basis for the application of BiOBr in the photocatalytic degradation of NO.
  • loading
  • [1]
    JEFFREY S G,NANCY A M. The Impacts of combustion emissions on air quality and climate from coal to biofuels and beyond[J]. Atmospheric Environment,2009,43(1):1352- 1360.
    [2]
    GANG W,DENG J,ZHANG Y,et al. Air pollutant emissions from coal-fired power plants in China over the past two decades[J]. Science of the Total Environment,2020,741:140326.
    [3]
    PFANNERSTILL E,ARATA C,ZHU Q,et al. Temperature-dependent emissions dominate aerosol and ozone formation in los angeles[J]. Science,2024,384(6695):1324- 1329.
    [4]
    CUI W,WANG J,YAN L,et al. Photocatalytic NO removal:complete oxidation and reduction reaction for by-product inhibition and end-product recovery[J]. Environmental Science:Nano,2025,12(1):67- 97.
    [5]
    LI N,WANG C,ZHANG K,et al. Progress and prospects of photocatalytic conversion of low-concentration NO x[J]. Chinese Journal of Catalysis,2022,43(9):2363- 2387.
    [6]
    TAHIR M,MANZOOR N,SAGIR M,et al. RETRACTED:fabrication of ZnFe2O4 modified TiO2 hybrid composites for photocatalytic reduction of CO2 into methanol[J]. Fuel,2021,285:119206.
    [7]
    LIU G,XIA H,ZHANG W,et al. Improvement mechanism of NO photocatalytic degradation performance of self-cleaning synergistic photocatalytic coating under high humidity[J]. Journal of Hazardous Materials,2021,418:126337.
    [8]
    LIU G,XIA H,NIU Y,et al. Preparation and performance of photocatalytic NO degradation superhydrophobic coatings for tunnel[J]. Environmental Science Pollution Research,2022,29(35):53420- 53432.
    [9]
    HU P P,HE X Z. Study on NO removal performance of B/C3N5 photocatalytic epoxy self-cleaning coating on concrete surface[J]. Inorganic Chemicals Industry,2025,57(09):117- 124. 胡平平,何小志. 混凝土表面B/C3N5光催化环氧自清洁涂层去除NO性能研究[J]. 无机盐工业,2025,57(09):117- 124.
    [10]
    WU X,TOE C Y,SU C,et al. Preparation of bi-based photocatalysts in the form of powdered particles and thin films:a review[J]. Journal of Materials Chemistry A,2020,8(29):15302- 15308.
    [11]
    ZHAO Y. Preparation,modification and photocatalytic performance of BiOBr nanophotocatalysts[D]. Tianjin:Tianjin University,2016. 赵阳. BiOBr纳米光催化剂的制备、改性及其光催化性能研究[D]. 天津:天津大学,2016.
    [12]
    IRSHAD A,SHAZIA S,MUHAMMAD Y N,et al. Designing and modification of bismuth oxyhalides BiOXX=Cl,Br and I)photocatalysts for improved photocatalytic performance[J]. Journal of Industrial and Engineering Chemistry,2021,105:1- 33.
    [13]
    LI H,JIN C Y,ZHANG D F. Preparation of BiOCl/BiOBr heterojunction by one-step solvothermal method and its photocatalytic performance[J]. Journal of Liaocheng University(Natural Science Edition),2025,38(2):259- 267. 李红,金传玉,张大凤. 一步溶剂热法制备BiOCl/BiOBr异质结及其光催化性能研究[J]. 聊城大学学报(自然科学版),2025,38(2):259- 267.
    [14]
    GU J,LI S S,CUI T Y,et al. Preparation of biomass char doped BiOBr and its photocatalytic performance[J]. Journal of Liaocheng University(Natural Science Edition),2025,38(1):68- 75. 顾杰,李双硕,崔天伊,等. 生物质炭掺杂BiOBr的制备及其光催化性能研究[J]. 聊城大学学报(自然科学版),2025,38(1):68- 75.
    [15]
    ZHANG K,LIU C,HUANG F,et al. Study of the electronic structure and photocatalytic activity of the BiOCl photocatalyst[J]. Applied Catalysis,B:Environmental,2006,68(3/4):125- 129.
    [16]
    ZHANG S R. Construction of p-n type BiOBr/α-Fe2O3 heterojunction for photocatalytic superhydrophobic coating used in NO degradation[D]. Taiyuan:Shanxi University,2024. 张世蕊. p-n型BiOBr/α-Fe2O3异质结构建光催化超疏水涂层用于NO的降解[D]. 太原:山西大学,2024.
    [17]
    WANG X,ZHANG Y,ZHOU C,et al. Hydroxyl-regulated BiOI nanosheets with a highly positive valence band maximum for improved visible-light photocatalytic performance[J]. Applied Catalysis B:Environmental,2019,268:118390.
    [18]
    LIU C,ZHOU J,SU J,et al. Turning the unwanted surface bismuth enrichment to favourable BiVO4/BiOCl heterojunction for enhanced photoelectrochemical performance[J]. Applied Catalysis B:Environmental,2019,241:506- 513.
    [19]
    MAJHI D,DAS K,MISHRA A,et al. One pot synthesis of CdS/BiOBr/Bi2O2CO3:a novel ternary double z-scheme heterostructure photocatalyst for efficient degradation of atrazine[J]. Applied Catalysis B:Environmental,2020,260:118222.
    [20]
    WANG X,ZHANG Y,ZHOU C,et al. Hydroxyl-regulated BiOI nanosheets with a highly positive valence band maximum for improved visible-light photocatalytic performance[J]. Applied Catalysis B:Environmental,2020,268:118390.
    [21]
    LI H,LONG B,YE K,et al. A recyclable photocatalytic tea-bag-like device model based on ultrathin Bi/C/BiOXX=Cl,Br)nanosheets[J]. Applied Surface Science,2020,515:145967.
    [22]
    WU P,FENG L,LIANG Y,et al. Large-scale synthesis of 2D bismuth-enriched bismuth oxyiodides at low temperatures for high-performance supercapacitor and photocatalytic applications[J]. Journal of Materials Science:Materials in Electronics,2020,31(6):5385- 5401.
    [23]
    SI H,MAO C,XIE Y,et al. P-n depleted bulk BiOBr/α-Fe2O3 heterojunctions applied for unbiased solar water splitting[J]. Dalton Transactions,2017,46(1):200- 206.
    [24]
    CEN S,LV X,LIU Q,et al. Direct z-scheme Ag2WO4/BiOCl composite photocatalyst for efficient photocatalytic degradations of dissolved organic impurities[J]. Optik,2021,243:166847.
    [25]
    XIA J,DI J,YIN S,et al. Fabrication of the visible-light-driven Bi2WO6/BiOBr composite with enhanced photocatalytic activity[J]. RSC Advances,2014,4(45):82- 90.
    [26]
    WANG Y,ZHANG A,ZHANG D,et al. Ultra-low loading of Ag2CrO4 on BiOI/CoFe2O4 microsphere with p-n heterojunction:highly improved photocatalytic performance for Hg0 removal and mechanism insight[J]. Journal of Photochemistry and Photobiology A:Chemistry,2020,396:112543.
    [27]
    QIN X,CHENG H,WANG W,et al. Three dimensional BiOXX=Cl,Br and I)hierarchical architectures:facile ionic liquid-assisted solvothermal synthesis and photocatalysis towards organic dye degradation[J]. Materials Letters,2013,100:285- 288.
    [28]
    SONG H,ZHANG S,CHENG S,et al. A photo catalytic superhydrophobic coating with p-n type BiOBr/α-Fe2O3 heterojunctions applied in NO degradation[J]. RSC Advances,2025,15(5):832- 843.
    [29]
    LIU G,XIA H,NIU Y,et al. Preparation and performance of photocatalytic NO degradation superhydrophobic coatings for tunnel[J]. Environmental Science Pollution Research,2022,29(35):53420- 53432.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article views (44) PDF downloads(0) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return